Liquid-liquid equilibria of polymer solutions: Flory-huggins with specific interaction

We have developed a new Flory-Huggins model by adding a specific interaction parameter derived from a modified double-lattice model for the Helmholtz energy of mixing for binary liquid mixtures. This model is very simple and could be easily integrated into engineering applications. Using this revise...

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Veröffentlicht in:Journal of polymer science. Part B, Polymer physics Polymer physics, 2010-01, Vol.48 (2), p.162-167
Hauptverfasser: Jung, Jae Gyeong, Bae, Young Chan
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creator Jung, Jae Gyeong
Bae, Young Chan
description We have developed a new Flory-Huggins model by adding a specific interaction parameter derived from a modified double-lattice model for the Helmholtz energy of mixing for binary liquid mixtures. This model is very simple and could be easily integrated into engineering applications. Using this revised model, we can successfully describe the phase behavior of polymer solutions with an upper critical solution temperature (UCST), a lower critical solution temperature (LCST), both UCST and LCST, and a closed miscibility loop.
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1099-0488
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source Wiley Online Library Journals Frontfile Complete
subjects Applied sciences
computer modeling
Exact sciences and technology
Interaction parameters
lattice models
Liquid-liquid equilibria
Liquids
Mathematical models
Miscibility
mixing
Organic polymers
phase behavior
phase diagrams
Physicochemistry of polymers
Polymer physics
Properties and characterization
Reproduction
Solution and gel properties
theory
thermodynamics
title Liquid-liquid equilibria of polymer solutions: Flory-huggins with specific interaction
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