Liquid-liquid equilibria of polymer solutions: Flory-huggins with specific interaction
We have developed a new Flory-Huggins model by adding a specific interaction parameter derived from a modified double-lattice model for the Helmholtz energy of mixing for binary liquid mixtures. This model is very simple and could be easily integrated into engineering applications. Using this revise...
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Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 2010-01, Vol.48 (2), p.162-167 |
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container_title | Journal of polymer science. Part B, Polymer physics |
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creator | Jung, Jae Gyeong Bae, Young Chan |
description | We have developed a new Flory-Huggins model by adding a specific interaction parameter derived from a modified double-lattice model for the Helmholtz energy of mixing for binary liquid mixtures. This model is very simple and could be easily integrated into engineering applications. Using this revised model, we can successfully describe the phase behavior of polymer solutions with an upper critical solution temperature (UCST), a lower critical solution temperature (LCST), both UCST and LCST, and a closed miscibility loop. |
doi_str_mv | 10.1002/polb.21883 |
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This model is very simple and could be easily integrated into engineering applications. 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Part B, Polymer physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jung, Jae Gyeong</au><au>Bae, Young Chan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Liquid-liquid equilibria of polymer solutions: Flory-huggins with specific interaction</atitle><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle><addtitle>J. Polym. Sci. B Polym. Phys</addtitle><date>2010-01-15</date><risdate>2010</risdate><volume>48</volume><issue>2</issue><spage>162</spage><epage>167</epage><pages>162-167</pages><issn>0887-6266</issn><issn>1099-0488</issn><eissn>1099-0488</eissn><coden>JPLPAY</coden><abstract>We have developed a new Flory-Huggins model by adding a specific interaction parameter derived from a modified double-lattice model for the Helmholtz energy of mixing for binary liquid mixtures. This model is very simple and could be easily integrated into engineering applications. Using this revised model, we can successfully describe the phase behavior of polymer solutions with an upper critical solution temperature (UCST), a lower critical solution temperature (LCST), both UCST and LCST, and a closed miscibility loop.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/polb.21883</doi><tpages>6</tpages></addata></record> |
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subjects | Applied sciences computer modeling Exact sciences and technology Interaction parameters lattice models Liquid-liquid equilibria Liquids Mathematical models Miscibility mixing Organic polymers phase behavior phase diagrams Physicochemistry of polymers Polymer physics Properties and characterization Reproduction Solution and gel properties theory thermodynamics |
title | Liquid-liquid equilibria of polymer solutions: Flory-huggins with specific interaction |
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