Stereospecific radical polymerization of N‐tert‐butoxycarbonylacrylamide in the presence of fluorinated alcohols

Radical polymerization of N‐tert‐butoxycarbonylacrylamide (NBocAAm) in toluene at low temperatures in the presence of the fluorinated alcohols, 2,2,2‐trifluoroethanol, 1,1,1,3,3,3‐hexafluoro‐2‐propanol, and nonafluoro‐tert‐butanol, afforded atactic, heterotactic, and syndiotactic polymers, respectiv...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2010-12, Vol.48 (24), p.5718-5726
Hauptverfasser:	Hirano, Tomohiro, Yamaoka, Ryosuke, Miyazaki, Takamasa, Ute, Koichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Applied sciences Bonding Exact sciences and technology Fluorination heterotactic hydrogen bonding N-tert-butoxycarbonylacrylamide Organic polymers Physicochemistry of polymers Polymer chemistry Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts radical polymerization Radicals Reproduction stereospecific polymers syndiotactic Toluene
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