Novel suberin-based biopolyesters: From synthesis to properties

This article reports the successful synthesis and characterization of two types of completely biobased polymers prepared by the polycondensation or polytransesterification of suberin fragments, isolated by different procedures and from two different vegetable sources. These polymerizations were cond...

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Veröffentlicht in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2011-05, Vol.49 (10), p.2281-2291
Hauptverfasser: Sousa, Andreia F, Gandini, Alessandro, Silvestre, Armando J.D, Neto, Carlos Pascoal, Cruz Pinto, José J.C, Eckerman, Christer, Holmbom, Bjarne
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container_end_page 2291
container_issue 10
container_start_page 2281
container_title Journal of polymer science. Part A, Polymer chemistry
container_volume 49
creator Sousa, Andreia F
Gandini, Alessandro
Silvestre, Armando J.D
Neto, Carlos Pascoal
Cruz Pinto, José J.C
Eckerman, Christer
Holmbom, Bjarne
description This article reports the successful synthesis and characterization of two types of completely biobased polymers prepared by the polycondensation or polytransesterification of suberin fragments, isolated by different procedures and from two different vegetable sources. These polymerizations were conducted with different experimental conditions in terms of the type of catalyst, the reaction medium and temperature, as well as the molar ratio between the reactive moieties. The ensuing linear or partly crosslinked polyesters were characterized by conventional spectroscopic techniques, SEC, DSC, XRD, DMA, and TGA. These hydrophobic materials represent an original contribution to the growing field of polymers from renewable resources.
doi_str_mv 10.1002/pola.24661
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source Wiley Online Library Journals Frontfile Complete
subjects Applied sciences
biopolyesters
biopolymers
birch
catalysts
cork
Crosslinking
Differential scanning calorimetry
Exact sciences and technology
hydrophobicity
Organic polymers
Physicochemistry of polymers
Polycondensation
Polyester resins
polyesters
Polymer chemistry
polymerization
Polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
Renewable resources
Reproduction
Spectroscopy
suberin
Synthesis
temperature
Vegetables
X-ray diffraction
title Novel suberin-based biopolyesters: From synthesis to properties
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