Novel suberin-based biopolyesters: From synthesis to properties
This article reports the successful synthesis and characterization of two types of completely biobased polymers prepared by the polycondensation or polytransesterification of suberin fragments, isolated by different procedures and from two different vegetable sources. These polymerizations were cond...
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Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2011-05, Vol.49 (10), p.2281-2291 |
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container_title | Journal of polymer science. Part A, Polymer chemistry |
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creator | Sousa, Andreia F Gandini, Alessandro Silvestre, Armando J.D Neto, Carlos Pascoal Cruz Pinto, José J.C Eckerman, Christer Holmbom, Bjarne |
description | This article reports the successful synthesis and characterization of two types of completely biobased polymers prepared by the polycondensation or polytransesterification of suberin fragments, isolated by different procedures and from two different vegetable sources. These polymerizations were conducted with different experimental conditions in terms of the type of catalyst, the reaction medium and temperature, as well as the molar ratio between the reactive moieties. The ensuing linear or partly crosslinked polyesters were characterized by conventional spectroscopic techniques, SEC, DSC, XRD, DMA, and TGA. These hydrophobic materials represent an original contribution to the growing field of polymers from renewable resources. |
doi_str_mv | 10.1002/pola.24661 |
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These polymerizations were conducted with different experimental conditions in terms of the type of catalyst, the reaction medium and temperature, as well as the molar ratio between the reactive moieties. The ensuing linear or partly crosslinked polyesters were characterized by conventional spectroscopic techniques, SEC, DSC, XRD, DMA, and TGA. These hydrophobic materials represent an original contribution to the growing field of polymers from renewable resources.</description><identifier>ISSN: 0887-624X</identifier><identifier>ISSN: 1099-0518</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.24661</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; biopolyesters ; biopolymers ; birch ; catalysts ; cork ; Crosslinking ; Differential scanning calorimetry ; Exact sciences and technology ; hydrophobicity ; Organic polymers ; Physicochemistry of polymers ; Polycondensation ; Polyester resins ; polyesters ; Polymer chemistry ; polymerization ; Polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Renewable resources ; Reproduction ; Spectroscopy ; suberin ; Synthesis ; temperature ; Vegetables ; X-ray diffraction</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2011-05, Vol.49 (10), p.2281-2291</ispartof><rights>Copyright © 2011 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright Wiley Subscription Services, Inc. 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Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>This article reports the successful synthesis and characterization of two types of completely biobased polymers prepared by the polycondensation or polytransesterification of suberin fragments, isolated by different procedures and from two different vegetable sources. These polymerizations were conducted with different experimental conditions in terms of the type of catalyst, the reaction medium and temperature, as well as the molar ratio between the reactive moieties. The ensuing linear or partly crosslinked polyesters were characterized by conventional spectroscopic techniques, SEC, DSC, XRD, DMA, and TGA. These hydrophobic materials represent an original contribution to the growing field of polymers from renewable resources.</description><subject>Applied sciences</subject><subject>biopolyesters</subject><subject>biopolymers</subject><subject>birch</subject><subject>catalysts</subject><subject>cork</subject><subject>Crosslinking</subject><subject>Differential scanning calorimetry</subject><subject>Exact sciences and technology</subject><subject>hydrophobicity</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polycondensation</subject><subject>Polyester resins</subject><subject>polyesters</subject><subject>Polymer chemistry</subject><subject>polymerization</subject><subject>Polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Renewable resources</subject><subject>Reproduction</subject><subject>Spectroscopy</subject><subject>suberin</subject><subject>Synthesis</subject><subject>temperature</subject><subject>Vegetables</subject><subject>X-ray diffraction</subject><issn>0887-624X</issn><issn>1099-0518</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kUFv1DAQhS0EEkvhwh8gEkJISCkzTuzYXFCp2IK0apFoYW-WN5mASzZePLvA_nu8pPTAgdMc_L03b56FeIxwjADy5SYO_ljWWuMdMUOwtgSF5q6YgTFNqWW9vC8eMF8D5DdlZuL1efxBQ8G7FaUwlivP1BWrELPRnnhLiV8V8xTXBe_H7VfiwMU2FpsUN5S2gfihuNf7genRzTwSV_O3l6fvysXF2fvTk0XZHsKUtvMt2r6qgQiwt6RQogerUfeSsOusN3XXgZIAaDuLlpB6RZ3XUJsVVEfi-eSbV3_f5WRuHbilYfAjxR07C6gbiZXK5NN_yOu4S2MO56QCK5U1IDP1YqLaFJkT9W6TwtqnvUNwhyrdoUr3p8oMP7ux9Nz6oU9-bAPfKmQNRml1CIkT9zMMtP-Po_twsTj5611OmpDb_nWr8emb003VKPf5_MwtLxdzWL5p3KfMP5n43kfnv6Sc4-qjzNfnL60kGlP9BuEMmtw</recordid><startdate>20110515</startdate><enddate>20110515</enddate><creator>Sousa, Andreia F</creator><creator>Gandini, Alessandro</creator><creator>Silvestre, Armando J.D</creator><creator>Neto, Carlos Pascoal</creator><creator>Cruz Pinto, José J.C</creator><creator>Eckerman, Christer</creator><creator>Holmbom, Bjarne</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20110515</creationdate><title>Novel suberin-based biopolyesters: From synthesis to properties</title><author>Sousa, Andreia F ; Gandini, Alessandro ; Silvestre, Armando J.D ; Neto, Carlos Pascoal ; Cruz Pinto, José J.C ; Eckerman, Christer ; Holmbom, Bjarne</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4661-9dac19f340ee01f9e5121a09616f2e1dd9a84dd0520019d919e1ef5eda6048b03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>biopolyesters</topic><topic>biopolymers</topic><topic>birch</topic><topic>catalysts</topic><topic>cork</topic><topic>Crosslinking</topic><topic>Differential scanning calorimetry</topic><topic>Exact sciences and technology</topic><topic>hydrophobicity</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polycondensation</topic><topic>Polyester resins</topic><topic>polyesters</topic><topic>Polymer chemistry</topic><topic>polymerization</topic><topic>Polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Renewable resources</topic><topic>Reproduction</topic><topic>Spectroscopy</topic><topic>suberin</topic><topic>Synthesis</topic><topic>temperature</topic><topic>Vegetables</topic><topic>X-ray diffraction</topic><toplevel>online_resources</toplevel><creatorcontrib>Sousa, Andreia F</creatorcontrib><creatorcontrib>Gandini, Alessandro</creatorcontrib><creatorcontrib>Silvestre, Armando J.D</creatorcontrib><creatorcontrib>Neto, Carlos Pascoal</creatorcontrib><creatorcontrib>Cruz Pinto, José J.C</creatorcontrib><creatorcontrib>Eckerman, Christer</creatorcontrib><creatorcontrib>Holmbom, Bjarne</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. 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subjects | Applied sciences biopolyesters biopolymers birch catalysts cork Crosslinking Differential scanning calorimetry Exact sciences and technology hydrophobicity Organic polymers Physicochemistry of polymers Polycondensation Polyester resins polyesters Polymer chemistry polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts Renewable resources Reproduction Spectroscopy suberin Synthesis temperature Vegetables X-ray diffraction |
title | Novel suberin-based biopolyesters: From synthesis to properties |
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