effect of different catalytic chain transfer agents on particle nucleation and the course of the polymerization in ab initio batch emulsion polymerization of methyl methacrylate
The effect a Co(II) based catalytic chain transfer agent (CCTA) has on the course of the polymerization and the product properties of an emulsion polymerization is governed by the intrinsic activity and the partitioning behavior of the catalyst. The effect on the conversion time history, the molecul...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2010-03, Vol.48 (5), p.1038-1048 |
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| container_end_page | 1048 |
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| container_issue | 5 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
| container_volume | 48 |
| creator | Smeets, Niels M.B Jansen, Tom G.T Sciarone, Timo J.J Heuts, Johan P.A Meuldijk, Jan Van Herk, Alex M |
| description | The effect a Co(II) based catalytic chain transfer agent (CCTA) has on the course of the polymerization and the product properties of an emulsion polymerization is governed by the intrinsic activity and the partitioning behavior of the catalyst. The effect on the conversion time history, the molecular weight distribution and the particle size distribution is evaluated in batch emulsion polymerization of methyl methacrylate for three different CCTAs, which cover a range of intrinsic activities and partitioning behaviors. It was demonstrated that radical desorption from the particle phase to the aqueous phase preceded by chain transfer is the main kinetic event controlling the course of the polymerization and the product properties in terms of the particle size distribution. The experimental results show that the aqueous phase solubility of the CCTA is the key parameter controlling the course of the polymerization and the particle size distribution. |
| doi_str_mv | 10.1002/pola.23858 |
| format | Article |
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The effect on the conversion time history, the molecular weight distribution and the particle size distribution is evaluated in batch emulsion polymerization of methyl methacrylate for three different CCTAs, which cover a range of intrinsic activities and partitioning behaviors. It was demonstrated that radical desorption from the particle phase to the aqueous phase preceded by chain transfer is the main kinetic event controlling the course of the polymerization and the product properties in terms of the particle size distribution. The experimental results show that the aqueous phase solubility of the CCTA is the key parameter controlling the course of the polymerization and the particle size distribution.</description><identifier>ISSN: 0887-624X</identifier><identifier>ISSN: 1099-0518</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.23858</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Catalysis ; Catalysts ; catalytic chain transfer ; Chain transfer ; Emulsion polymerization ; Exact sciences and technology ; molecular weight distribution/molar mass distribution ; Organic polymers ; Particle size distribution ; Partitioning ; Physicochemistry of polymers ; Polymerization ; polymerization kinetics ; Polymethyl methacrylates ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2010-03, Vol.48 (5), p.1038-1048</ispartof><rights>Copyright © 2010 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4298-29c1d566c4e21e38d2d27cbabec257ecae2d01cb6bf5a54193877f8f1a4b3c033</citedby><cites>FETCH-LOGICAL-c4298-29c1d566c4e21e38d2d27cbabec257ecae2d01cb6bf5a54193877f8f1a4b3c033</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.23858$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.23858$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22389275$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Smeets, Niels M.B</creatorcontrib><creatorcontrib>Jansen, Tom G.T</creatorcontrib><creatorcontrib>Sciarone, Timo J.J</creatorcontrib><creatorcontrib>Heuts, Johan P.A</creatorcontrib><creatorcontrib>Meuldijk, Jan</creatorcontrib><creatorcontrib>Van Herk, Alex M</creatorcontrib><title>effect of different catalytic chain transfer agents on particle nucleation and the course of the polymerization in ab initio batch emulsion polymerization of methyl methacrylate</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>The effect a Co(II) based catalytic chain transfer agent (CCTA) has on the course of the polymerization and the product properties of an emulsion polymerization is governed by the intrinsic activity and the partitioning behavior of the catalyst. The effect on the conversion time history, the molecular weight distribution and the particle size distribution is evaluated in batch emulsion polymerization of methyl methacrylate for three different CCTAs, which cover a range of intrinsic activities and partitioning behaviors. It was demonstrated that radical desorption from the particle phase to the aqueous phase preceded by chain transfer is the main kinetic event controlling the course of the polymerization and the product properties in terms of the particle size distribution. The experimental results show that the aqueous phase solubility of the CCTA is the key parameter controlling the course of the polymerization and the particle size distribution.</description><subject>Applied sciences</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>catalytic chain transfer</subject><subject>Chain transfer</subject><subject>Emulsion polymerization</subject><subject>Exact sciences and technology</subject><subject>molecular weight distribution/molar mass distribution</subject><subject>Organic polymers</subject><subject>Particle size distribution</subject><subject>Partitioning</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>polymerization kinetics</subject><subject>Polymethyl methacrylates</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0887-624X</issn><issn>1099-0518</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkcFu1DAQhiMEEkvhwgvgC0JCSrGdOHaOVcW2oFVbAVW5WRNn0jU4ydb2CtK34g1xmtIDB7jMePx_889Ik2UvGT1klPJ3u9HBIS-UUI-yFaN1nVPB1ONsRZWSecXLr0-zZyF8ozRpQq2yX9h1aCIZO9La9PQ4RGIggpuiNcRswQ4kehhC0ghcJzmQcSA78El3SIZ9ihBt-oOhJXGLxIx7H3C2nKu00tSjt7cLlOygSdGmijQQzZZgv3dh1v5Ck0GPcTu5uwTGTw4iPs-edOACvrjPB9nl-v2X49N8c37y4fhok5uS1yrntWGtqCpTImdYqJa3XJoGGjRcSDSAvKXMNFXTCRAlqwslZac6BmVTGFoUB9mbxXfnx5s9hqh7Gww6BwOO-6BryirJqkr8l1R1xRlLMxL5diGNH0Pw2Omdtz34STOq5wPq-YD67oAJfn1vC8GA69IRjA0PHTxRNZfzeLZwP6zD6R-O-uJ8c_THO196bIj486EH_HddyUIKfXV2os_WHz9trtYXel781cJ3MGq49mmPy8-csoIyRZkUsvgNSa_I3w</recordid><startdate>20100301</startdate><enddate>20100301</enddate><creator>Smeets, Niels M.B</creator><creator>Jansen, Tom G.T</creator><creator>Sciarone, Timo J.J</creator><creator>Heuts, Johan P.A</creator><creator>Meuldijk, Jan</creator><creator>Van Herk, Alex M</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20100301</creationdate><title>effect of different catalytic chain transfer agents on particle nucleation and the course of the polymerization in ab initio batch emulsion polymerization of methyl methacrylate</title><author>Smeets, Niels M.B ; Jansen, Tom G.T ; Sciarone, Timo J.J ; Heuts, Johan P.A ; Meuldijk, Jan ; Van Herk, Alex M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4298-29c1d566c4e21e38d2d27cbabec257ecae2d01cb6bf5a54193877f8f1a4b3c033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>catalytic chain transfer</topic><topic>Chain transfer</topic><topic>Emulsion polymerization</topic><topic>Exact sciences and technology</topic><topic>molecular weight distribution/molar mass distribution</topic><topic>Organic polymers</topic><topic>Particle size distribution</topic><topic>Partitioning</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>polymerization kinetics</topic><topic>Polymethyl methacrylates</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>online_resources</toplevel><creatorcontrib>Smeets, Niels M.B</creatorcontrib><creatorcontrib>Jansen, Tom G.T</creatorcontrib><creatorcontrib>Sciarone, Timo J.J</creatorcontrib><creatorcontrib>Heuts, Johan P.A</creatorcontrib><creatorcontrib>Meuldijk, Jan</creatorcontrib><creatorcontrib>Van Herk, Alex M</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Smeets, Niels M.B</au><au>Jansen, Tom G.T</au><au>Sciarone, Timo J.J</au><au>Heuts, Johan P.A</au><au>Meuldijk, Jan</au><au>Van Herk, Alex M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>effect of different catalytic chain transfer agents on particle nucleation and the course of the polymerization in ab initio batch emulsion polymerization of methyl methacrylate</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>2010-03-01</date><risdate>2010</risdate><volume>48</volume><issue>5</issue><spage>1038</spage><epage>1048</epage><pages>1038-1048</pages><issn>0887-624X</issn><issn>1099-0518</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>The effect a Co(II) based catalytic chain transfer agent (CCTA) has on the course of the polymerization and the product properties of an emulsion polymerization is governed by the intrinsic activity and the partitioning behavior of the catalyst. The effect on the conversion time history, the molecular weight distribution and the particle size distribution is evaluated in batch emulsion polymerization of methyl methacrylate for three different CCTAs, which cover a range of intrinsic activities and partitioning behaviors. It was demonstrated that radical desorption from the particle phase to the aqueous phase preceded by chain transfer is the main kinetic event controlling the course of the polymerization and the product properties in terms of the particle size distribution. The experimental results show that the aqueous phase solubility of the CCTA is the key parameter controlling the course of the polymerization and the particle size distribution.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pola.23858</doi><tpages>11</tpages></addata></record> |
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| subjects | Applied sciences Catalysis Catalysts catalytic chain transfer Chain transfer Emulsion polymerization Exact sciences and technology molecular weight distribution/molar mass distribution Organic polymers Particle size distribution Partitioning Physicochemistry of polymers Polymerization polymerization kinetics Polymethyl methacrylates Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | effect of different catalytic chain transfer agents on particle nucleation and the course of the polymerization in ab initio batch emulsion polymerization of methyl methacrylate |
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