Novel N-ethyl-2-styrylquinolinium iodides as sensitizers in the photoinitiated free-radical polymerization of trimethylolopropane triacrylate. II

Results of kinetic studies of two-component photoinitiator systems used in the visible-light photoinduced polymerization of 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate are presented. Nine different styrylquinolinum dyes coupled with n-butyltriphenylborate as a coinitiator have been used as...

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Veröffentlicht in:Journal of applied polymer science 2010-10, Vol.118 (1), p.165-172
Hauptverfasser: Kabatc, Janina, Krzyżanowska, Edyta, Jędrzejewska, Beata, Pietrzak, Marek, Pączkowski, Jerzy
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container_issue 1
container_start_page 165
container_title Journal of applied polymer science
container_volume 118
creator Kabatc, Janina
Krzyżanowska, Edyta
Jędrzejewska, Beata
Pietrzak, Marek
Pączkowski, Jerzy
description Results of kinetic studies of two-component photoinitiator systems used in the visible-light photoinduced polymerization of 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate are presented. Nine different styrylquinolinum dyes coupled with n-butyltriphenylborate as a coinitiator have been used as photoinitiating systems. Reactive radicals that initiate the polymerization are formed by the well-known mechanism of photoinduced electron transfer between dye cations acting as electron acceptors and borate anions acting as electron donors.
doi_str_mv 10.1002/app.30125
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subjects Anions
Applied sciences
Borates
Dyes
dyes/pigments
Exact sciences and technology
initiators
Iodides
kinetics (polym.)
Photoinitiators
photopolymerization
Physicochemistry of polymers
Polymerization
Polymers and radiations
Radicals
Reproduction
title Novel N-ethyl-2-styrylquinolinium iodides as sensitizers in the photoinitiated free-radical polymerization of trimethylolopropane triacrylate. II
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