Novel N-ethyl-2-styrylquinolinium iodides as sensitizers in the photoinitiated free-radical polymerization of trimethylolopropane triacrylate. II
Results of kinetic studies of two-component photoinitiator systems used in the visible-light photoinduced polymerization of 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate are presented. Nine different styrylquinolinum dyes coupled with n-butyltriphenylborate as a coinitiator have been used as...
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Veröffentlicht in: | Journal of applied polymer science 2010-10, Vol.118 (1), p.165-172 |
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creator | Kabatc, Janina Krzyżanowska, Edyta Jędrzejewska, Beata Pietrzak, Marek Pączkowski, Jerzy |
description | Results of kinetic studies of two-component photoinitiator systems used in the visible-light photoinduced polymerization of 2-ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate are presented. Nine different styrylquinolinum dyes coupled with n-butyltriphenylborate as a coinitiator have been used as photoinitiating systems. Reactive radicals that initiate the polymerization are formed by the well-known mechanism of photoinduced electron transfer between dye cations acting as electron acceptors and borate anions acting as electron donors. |
doi_str_mv | 10.1002/app.30125 |
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subjects | Anions Applied sciences Borates Dyes dyes/pigments Exact sciences and technology initiators Iodides kinetics (polym.) Photoinitiators photopolymerization Physicochemistry of polymers Polymerization Polymers and radiations Radicals Reproduction |
title | Novel N-ethyl-2-styrylquinolinium iodides as sensitizers in the photoinitiated free-radical polymerization of trimethylolopropane triacrylate. II |
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