Rheological Behavior and Morphologies of Reactively Compatibilized PVDF/TPU Blends
Using the comb copolymer PVDF‐g‐AAc as a compatibilizer, five reactively compatibilized PVDF/TPU blends with different compositions were prepared. During melt blending, the carboxylic acid groups of PVDF‐g‐AAc react with the urethane linkages of TPU to generate the graft copolymers PVDF‐g‐AAc‐g‐TPU,...
Gespeichert in:
| Veröffentlicht in: | Macromolecular chemistry and physics 2011-02, Vol.212 (3), p.252-258 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 258 |
|---|---|
| container_issue | 3 |
| container_start_page | 252 |
| container_title | Macromolecular chemistry and physics |
| container_volume | 212 |
| creator | Ma, Haiying Xiong, Zhengrong Lv, Fengxian Li, Chan Yang, Yuming |
| description | Using the comb copolymer PVDF‐g‐AAc as a compatibilizer, five reactively compatibilized PVDF/TPU blends with different compositions were prepared. During melt blending, the carboxylic acid groups of PVDF‐g‐AAc react with the urethane linkages of TPU to generate the graft copolymers PVDF‐g‐AAc‐g‐TPU, which lead to compatibilization of the PVDF/TPU blends. The rheological behavior of the compatibilized PVDF/TPU blends can be described by a generalized Zener model. PVDF/TPU 50/50 and PVDF/TPU 30/70 blends show a particle network structure, indicating elastic interactions between the grafted shells of compatibilized PVDF domains. SEM shows that almost all compatibilized PVDF/TPU blends exhibit a dispersion‐type morphology.
Reactively compatibilized PVDF/TPU blends with different compositions are prepared using the comb copolymer PVDF ‐g‐AAc as the compatibilizer. The rheological behavior of the compatibilized PVDF/TPU blends can be described well by the generalized Zener model. The PVDF/TPU 50/50 and PVDF/TPU 30/70 blend exhibit a particle network structure, indicating elastic interactions between the grafted shells of compatibilized PVDF domains. |
| doi_str_mv | 10.1002/macp.201000503 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_901660745</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>901660745</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4263-ddd46f7a6f3b84dd2719cd07e849bba44a11e62645e42d6683e65d80d40817273</originalsourceid><addsrcrecordid>eNqFkEtPAjEUhSdGE_GxdT0b42qw784sBURNfBCCumzK9I5UCx1bRPHXOwgh7lzdk9zvnHtzkuQEozZGiJxPdVm3CWo04ojuJC3MCc5oQfluoxEhGaac7CcHMb42TI4K2UqGwwl4519sqV3agYleWB9SPTPpnQ_15HcFMfVVOgRdzu0C3DLt-mmt53Zsnf0Gkw6eev3z0eAx7TiYmXiU7FXaRTjezMPksX856l5ntw9XN92L26xkRNDMGMNEJbWo6DhnxhCJi9IgCTkrxmPNmMYYBBGMAyNGiJyC4CZHhqEcSyLpYXK2zq2Df_-AOFdTG0twTs_Af0RVICwEkow3ZHtNlsHHGKBSdbBTHZYKI7XqTq26U9vuGsPpJlrHppgq6Flp49ZFGCfNE3nDFWvu0zpY_pOq7i66g783srXXxjl8bb06vCkhqeTq-f5KPQ9EZ9Tr9NQ9_QEppo4Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>901660745</pqid></control><display><type>article</type><title>Rheological Behavior and Morphologies of Reactively Compatibilized PVDF/TPU Blends</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Ma, Haiying ; Xiong, Zhengrong ; Lv, Fengxian ; Li, Chan ; Yang, Yuming</creator><creatorcontrib>Ma, Haiying ; Xiong, Zhengrong ; Lv, Fengxian ; Li, Chan ; Yang, Yuming</creatorcontrib><description>Using the comb copolymer PVDF‐g‐AAc as a compatibilizer, five reactively compatibilized PVDF/TPU blends with different compositions were prepared. During melt blending, the carboxylic acid groups of PVDF‐g‐AAc react with the urethane linkages of TPU to generate the graft copolymers PVDF‐g‐AAc‐g‐TPU, which lead to compatibilization of the PVDF/TPU blends. The rheological behavior of the compatibilized PVDF/TPU blends can be described by a generalized Zener model. PVDF/TPU 50/50 and PVDF/TPU 30/70 blends show a particle network structure, indicating elastic interactions between the grafted shells of compatibilized PVDF domains. SEM shows that almost all compatibilized PVDF/TPU blends exhibit a dispersion‐type morphology.
Reactively compatibilized PVDF/TPU blends with different compositions are prepared using the comb copolymer PVDF ‐g‐AAc as the compatibilizer. The rheological behavior of the compatibilized PVDF/TPU blends can be described well by the generalized Zener model. The PVDF/TPU 50/50 and PVDF/TPU 30/70 blend exhibit a particle network structure, indicating elastic interactions between the grafted shells of compatibilized PVDF domains.</description><identifier>ISSN: 1022-1352</identifier><identifier>ISSN: 1521-3935</identifier><identifier>EISSN: 1521-3935</identifier><identifier>DOI: 10.1002/macp.201000503</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; Blends ; Compatibility ; compatibilization ; Exact sciences and technology ; graft copolymers ; Mathematical models ; Morphology ; networks ; Organic polymers ; Physicochemistry of polymers ; Polymer blends ; Polyvinylidene fluorides ; Properties and characterization ; Rheological properties ; rheology ; Rheology and viscoelasticity ; Urethane thermoplastic elastomers</subject><ispartof>Macromolecular chemistry and physics, 2011-02, Vol.212 (3), p.252-258</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4263-ddd46f7a6f3b84dd2719cd07e849bba44a11e62645e42d6683e65d80d40817273</citedby><cites>FETCH-LOGICAL-c4263-ddd46f7a6f3b84dd2719cd07e849bba44a11e62645e42d6683e65d80d40817273</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmacp.201000503$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmacp.201000503$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24520818$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ma, Haiying</creatorcontrib><creatorcontrib>Xiong, Zhengrong</creatorcontrib><creatorcontrib>Lv, Fengxian</creatorcontrib><creatorcontrib>Li, Chan</creatorcontrib><creatorcontrib>Yang, Yuming</creatorcontrib><title>Rheological Behavior and Morphologies of Reactively Compatibilized PVDF/TPU Blends</title><title>Macromolecular chemistry and physics</title><addtitle>Macromol. Chem. Phys</addtitle><description>Using the comb copolymer PVDF‐g‐AAc as a compatibilizer, five reactively compatibilized PVDF/TPU blends with different compositions were prepared. During melt blending, the carboxylic acid groups of PVDF‐g‐AAc react with the urethane linkages of TPU to generate the graft copolymers PVDF‐g‐AAc‐g‐TPU, which lead to compatibilization of the PVDF/TPU blends. The rheological behavior of the compatibilized PVDF/TPU blends can be described by a generalized Zener model. PVDF/TPU 50/50 and PVDF/TPU 30/70 blends show a particle network structure, indicating elastic interactions between the grafted shells of compatibilized PVDF domains. SEM shows that almost all compatibilized PVDF/TPU blends exhibit a dispersion‐type morphology.
Reactively compatibilized PVDF/TPU blends with different compositions are prepared using the comb copolymer PVDF ‐g‐AAc as the compatibilizer. The rheological behavior of the compatibilized PVDF/TPU blends can be described well by the generalized Zener model. The PVDF/TPU 50/50 and PVDF/TPU 30/70 blend exhibit a particle network structure, indicating elastic interactions between the grafted shells of compatibilized PVDF domains.</description><subject>Applied sciences</subject><subject>Blends</subject><subject>Compatibility</subject><subject>compatibilization</subject><subject>Exact sciences and technology</subject><subject>graft copolymers</subject><subject>Mathematical models</subject><subject>Morphology</subject><subject>networks</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer blends</subject><subject>Polyvinylidene fluorides</subject><subject>Properties and characterization</subject><subject>Rheological properties</subject><subject>rheology</subject><subject>Rheology and viscoelasticity</subject><subject>Urethane thermoplastic elastomers</subject><issn>1022-1352</issn><issn>1521-3935</issn><issn>1521-3935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPAjEUhSdGE_GxdT0b42qw784sBURNfBCCumzK9I5UCx1bRPHXOwgh7lzdk9zvnHtzkuQEozZGiJxPdVm3CWo04ojuJC3MCc5oQfluoxEhGaac7CcHMb42TI4K2UqGwwl4519sqV3agYleWB9SPTPpnQ_15HcFMfVVOgRdzu0C3DLt-mmt53Zsnf0Gkw6eev3z0eAx7TiYmXiU7FXaRTjezMPksX856l5ntw9XN92L26xkRNDMGMNEJbWo6DhnxhCJi9IgCTkrxmPNmMYYBBGMAyNGiJyC4CZHhqEcSyLpYXK2zq2Df_-AOFdTG0twTs_Af0RVICwEkow3ZHtNlsHHGKBSdbBTHZYKI7XqTq26U9vuGsPpJlrHppgq6Flp49ZFGCfNE3nDFWvu0zpY_pOq7i66g783srXXxjl8bb06vCkhqeTq-f5KPQ9EZ9Tr9NQ9_QEppo4Y</recordid><startdate>20110201</startdate><enddate>20110201</enddate><creator>Ma, Haiying</creator><creator>Xiong, Zhengrong</creator><creator>Lv, Fengxian</creator><creator>Li, Chan</creator><creator>Yang, Yuming</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110201</creationdate><title>Rheological Behavior and Morphologies of Reactively Compatibilized PVDF/TPU Blends</title><author>Ma, Haiying ; Xiong, Zhengrong ; Lv, Fengxian ; Li, Chan ; Yang, Yuming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4263-ddd46f7a6f3b84dd2719cd07e849bba44a11e62645e42d6683e65d80d40817273</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Blends</topic><topic>Compatibility</topic><topic>compatibilization</topic><topic>Exact sciences and technology</topic><topic>graft copolymers</topic><topic>Mathematical models</topic><topic>Morphology</topic><topic>networks</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymer blends</topic><topic>Polyvinylidene fluorides</topic><topic>Properties and characterization</topic><topic>Rheological properties</topic><topic>rheology</topic><topic>Rheology and viscoelasticity</topic><topic>Urethane thermoplastic elastomers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Haiying</creatorcontrib><creatorcontrib>Xiong, Zhengrong</creatorcontrib><creatorcontrib>Lv, Fengxian</creatorcontrib><creatorcontrib>Li, Chan</creatorcontrib><creatorcontrib>Yang, Yuming</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Macromolecular chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Haiying</au><au>Xiong, Zhengrong</au><au>Lv, Fengxian</au><au>Li, Chan</au><au>Yang, Yuming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rheological Behavior and Morphologies of Reactively Compatibilized PVDF/TPU Blends</atitle><jtitle>Macromolecular chemistry and physics</jtitle><addtitle>Macromol. Chem. Phys</addtitle><date>2011-02-01</date><risdate>2011</risdate><volume>212</volume><issue>3</issue><spage>252</spage><epage>258</epage><pages>252-258</pages><issn>1022-1352</issn><issn>1521-3935</issn><eissn>1521-3935</eissn><abstract>Using the comb copolymer PVDF‐g‐AAc as a compatibilizer, five reactively compatibilized PVDF/TPU blends with different compositions were prepared. During melt blending, the carboxylic acid groups of PVDF‐g‐AAc react with the urethane linkages of TPU to generate the graft copolymers PVDF‐g‐AAc‐g‐TPU, which lead to compatibilization of the PVDF/TPU blends. The rheological behavior of the compatibilized PVDF/TPU blends can be described by a generalized Zener model. PVDF/TPU 50/50 and PVDF/TPU 30/70 blends show a particle network structure, indicating elastic interactions between the grafted shells of compatibilized PVDF domains. SEM shows that almost all compatibilized PVDF/TPU blends exhibit a dispersion‐type morphology.
Reactively compatibilized PVDF/TPU blends with different compositions are prepared using the comb copolymer PVDF ‐g‐AAc as the compatibilizer. The rheological behavior of the compatibilized PVDF/TPU blends can be described well by the generalized Zener model. The PVDF/TPU 50/50 and PVDF/TPU 30/70 blend exhibit a particle network structure, indicating elastic interactions between the grafted shells of compatibilized PVDF domains.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/macp.201000503</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1022-1352 |
| ispartof | Macromolecular chemistry and physics, 2011-02, Vol.212 (3), p.252-258 |
| issn | 1022-1352 1521-3935 1521-3935 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_901660745 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Blends Compatibility compatibilization Exact sciences and technology graft copolymers Mathematical models Morphology networks Organic polymers Physicochemistry of polymers Polymer blends Polyvinylidene fluorides Properties and characterization Rheological properties rheology Rheology and viscoelasticity Urethane thermoplastic elastomers |
| title | Rheological Behavior and Morphologies of Reactively Compatibilized PVDF/TPU Blends |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-09T19%3A20%3A28IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rheological%20Behavior%20and%20Morphologies%20of%20Reactively%20Compatibilized%20PVDF/TPU%20Blends&rft.jtitle=Macromolecular%20chemistry%20and%20physics&rft.au=Ma,%20Haiying&rft.date=2011-02-01&rft.volume=212&rft.issue=3&rft.spage=252&rft.epage=258&rft.pages=252-258&rft.issn=1022-1352&rft.eissn=1521-3935&rft_id=info:doi/10.1002/macp.201000503&rft_dat=%3Cproquest_cross%3E901660745%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=901660745&rft_id=info:pmid/&rfr_iscdi=true |