Ethynyl aromatic siliconhybridized resin: Synthesis, characterizations, and thermal properties
A novel silicon-containing resin (ESA resin) was successfully synthesized by the condensation reaction of lithium arylacetylide with chlorosilane in high yields. The resin was characterized by the techniques of FTIR, ¹H-NMR, ²⁹Si-NMR, and gel permeation chromatography. Thermal cure process was monit...
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| Veröffentlicht in: | Journal of applied polymer science 2010-07, Vol.117 (2), p.714-719 |
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| container_title | Journal of applied polymer science |
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| creator | Yang, Ming Shi, Song Wang, Mingcun Wang, Yuhui Luo, Zhenhua Feng, Zhihai Zhao, Tong |
| description | A novel silicon-containing resin (ESA resin) was successfully synthesized by the condensation reaction of lithium arylacetylide with chlorosilane in high yields. The resin was characterized by the techniques of FTIR, ¹H-NMR, ²⁹Si-NMR, and gel permeation chromatography. Thermal cure process was monitored by DSC and FTIR methods. This resin could melt at around 100°C and thermally cured at 200-250°C with low exothermal enthalpy. Owing to the high aryl groups containing and the complete crosslinking of ethynyl groups, the cured ESA resin exhibited excellent thermal stability and high char yield. The decomposition temperature $T_{d_5}$ of the cured resin was at 510°C, and the residue yield at 900°C was 82.9% in N₂. |
| doi_str_mv | 10.1002/app.31237 |
| format | Article |
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The resin was characterized by the techniques of FTIR, ¹H-NMR, ²⁹Si-NMR, and gel permeation chromatography. Thermal cure process was monitored by DSC and FTIR methods. This resin could melt at around 100°C and thermally cured at 200-250°C with low exothermal enthalpy. Owing to the high aryl groups containing and the complete crosslinking of ethynyl groups, the cured ESA resin exhibited excellent thermal stability and high char yield. The decomposition temperature $T_{d_5}$ of the cured resin was at 510°C, and the residue yield at 900°C was 82.9% in N₂.</description><identifier>ISSN: 0021-8995</identifier><identifier>ISSN: 1097-4628</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.31237</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; aromatic ; Aromatic compounds ; Combustion ; Condensation resins ; Crosslinking ; ethynyl ; Exact sciences and technology ; Inorganic and organomineral polymers ; Lithium ; Physicochemistry of polymers ; Polymers ; Preparation ; Reproduction ; Resins ; silicones ; Thermal properties ; thermosets</subject><ispartof>Journal of applied polymer science, 2010-07, Vol.117 (2), p.714-719</ispartof><rights>Copyright © 2010 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4617-dbbd1b34e3ba4103859dbe4fd8d54635aefbda2a3bb55540b48e5175c0e15c2e3</citedby><cites>FETCH-LOGICAL-c4617-dbbd1b34e3ba4103859dbe4fd8d54635aefbda2a3bb55540b48e5175c0e15c2e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.31237$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.31237$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22847726$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Ming</creatorcontrib><creatorcontrib>Shi, Song</creatorcontrib><creatorcontrib>Wang, Mingcun</creatorcontrib><creatorcontrib>Wang, Yuhui</creatorcontrib><creatorcontrib>Luo, Zhenhua</creatorcontrib><creatorcontrib>Feng, Zhihai</creatorcontrib><creatorcontrib>Zhao, Tong</creatorcontrib><title>Ethynyl aromatic siliconhybridized resin: Synthesis, characterizations, and thermal properties</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>A novel silicon-containing resin (ESA resin) was successfully synthesized by the condensation reaction of lithium arylacetylide with chlorosilane in high yields. The resin was characterized by the techniques of FTIR, ¹H-NMR, ²⁹Si-NMR, and gel permeation chromatography. Thermal cure process was monitored by DSC and FTIR methods. This resin could melt at around 100°C and thermally cured at 200-250°C with low exothermal enthalpy. Owing to the high aryl groups containing and the complete crosslinking of ethynyl groups, the cured ESA resin exhibited excellent thermal stability and high char yield. The decomposition temperature $T_{d_5}$ of the cured resin was at 510°C, and the residue yield at 900°C was 82.9% in N₂.</description><subject>Applied sciences</subject><subject>aromatic</subject><subject>Aromatic compounds</subject><subject>Combustion</subject><subject>Condensation resins</subject><subject>Crosslinking</subject><subject>ethynyl</subject><subject>Exact sciences and technology</subject><subject>Inorganic and organomineral polymers</subject><subject>Lithium</subject><subject>Physicochemistry of polymers</subject><subject>Polymers</subject><subject>Preparation</subject><subject>Reproduction</subject><subject>Resins</subject><subject>silicones</subject><subject>Thermal properties</subject><subject>thermosets</subject><issn>0021-8995</issn><issn>1097-4628</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kE1v1DAQhi0EEsvCgV9ALgiQSOvxR5xwq6puQSqlqFTcsMYfYQ3ZJNipIP31eEnpDU4zmnned0YvIU-BHgCl7BDH8YAD4-oeWQFtVCkqVt8nq7yDsm4a-ZA8SukbpQCSVivy5WTazv3cFRiHHU7BFil0wQ79djYxuHDjXRF9Cv2b4nLup21u0-vCbjGinXwMN1kz9HmEvSvyOu6wK8Y4jD5OwafH5EGLXfJPbuuaXG1OPh2_Lc8-nL47PjorrahAlc4YB4YLzw0KoLyWjTNetK52UlRcom-NQ4bcGCmloEbUXoKSlnqQlnm-Ji8W33z6x7VPk96FZH3XYe-H66QbCpXkInutycv_klApEEw0vM7oqwW1cUgp-laPMewwzhqo3qetc9r6T9qZfX5ri8li10bsbUh3AsZqoRTbnz9cuJ-h8_O_DfXRxcVf53JRhDT5X3cKjN91pbiS-vP5qf4Izea8eb_R-6-fLXyLg8avMX9xdckocAo1lw2n_DebZ6fm</recordid><startdate>20100715</startdate><enddate>20100715</enddate><creator>Yang, Ming</creator><creator>Shi, Song</creator><creator>Wang, Mingcun</creator><creator>Wang, Yuhui</creator><creator>Luo, Zhenhua</creator><creator>Feng, Zhihai</creator><creator>Zhao, Tong</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20100715</creationdate><title>Ethynyl aromatic siliconhybridized resin: Synthesis, characterizations, and thermal properties</title><author>Yang, Ming ; Shi, Song ; Wang, Mingcun ; Wang, Yuhui ; Luo, Zhenhua ; Feng, Zhihai ; Zhao, Tong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4617-dbbd1b34e3ba4103859dbe4fd8d54635aefbda2a3bb55540b48e5175c0e15c2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>aromatic</topic><topic>Aromatic compounds</topic><topic>Combustion</topic><topic>Condensation resins</topic><topic>Crosslinking</topic><topic>ethynyl</topic><topic>Exact sciences and technology</topic><topic>Inorganic and organomineral polymers</topic><topic>Lithium</topic><topic>Physicochemistry of polymers</topic><topic>Polymers</topic><topic>Preparation</topic><topic>Reproduction</topic><topic>Resins</topic><topic>silicones</topic><topic>Thermal properties</topic><topic>thermosets</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Ming</creatorcontrib><creatorcontrib>Shi, Song</creatorcontrib><creatorcontrib>Wang, Mingcun</creatorcontrib><creatorcontrib>Wang, Yuhui</creatorcontrib><creatorcontrib>Luo, Zhenhua</creatorcontrib><creatorcontrib>Feng, Zhihai</creatorcontrib><creatorcontrib>Zhao, Tong</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Ming</au><au>Shi, Song</au><au>Wang, Mingcun</au><au>Wang, Yuhui</au><au>Luo, Zhenhua</au><au>Feng, Zhihai</au><au>Zhao, Tong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ethynyl aromatic siliconhybridized resin: Synthesis, characterizations, and thermal properties</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2010-07-15</date><risdate>2010</risdate><volume>117</volume><issue>2</issue><spage>714</spage><epage>719</epage><pages>714-719</pages><issn>0021-8995</issn><issn>1097-4628</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>A novel silicon-containing resin (ESA resin) was successfully synthesized by the condensation reaction of lithium arylacetylide with chlorosilane in high yields. The resin was characterized by the techniques of FTIR, ¹H-NMR, ²⁹Si-NMR, and gel permeation chromatography. Thermal cure process was monitored by DSC and FTIR methods. This resin could melt at around 100°C and thermally cured at 200-250°C with low exothermal enthalpy. Owing to the high aryl groups containing and the complete crosslinking of ethynyl groups, the cured ESA resin exhibited excellent thermal stability and high char yield. The decomposition temperature $T_{d_5}$ of the cured resin was at 510°C, and the residue yield at 900°C was 82.9% in N₂.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.31237</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
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| source | Wiley Journals |
| subjects | Applied sciences aromatic Aromatic compounds Combustion Condensation resins Crosslinking ethynyl Exact sciences and technology Inorganic and organomineral polymers Lithium Physicochemistry of polymers Polymers Preparation Reproduction Resins silicones Thermal properties thermosets |
| title | Ethynyl aromatic siliconhybridized resin: Synthesis, characterizations, and thermal properties |
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