Sensitive and Selective Chromogenic Sensing of Carbon Monoxide via Reversible Axial CO Coordination in Binuclear Rhodium Complexes

The study of probes for CO sensing of a family of binuclear rhodium(II) compounds of general formula [Rh2{(XC6H3)P(XC6H4)} n (O2CR)4–n ]·L2 containing one or two metalated phosphines (in a head-to-tail arrangement) and different axial ligands has been conducted. Chloroform solutions of these complex...

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Veröffentlicht in:	Journal of the American Chemical Society 2011-10, Vol.133 (39), p.15762-15772
Hauptverfasser:	Moragues, María E, Esteban, Julio, Ros-Lis, José Vicente, Martínez-Máñez, Ramón, Marcos, M. Dolores, Martínez, Manuel, Soto, Juan, Sancenón, Félix
Format:	Artikel
Sprache:	eng
Schlagworte:	Air Carbon Monoxide - analysis Carbon Monoxide - chemistry Chemistry Techniques, Analytical - instrumentation Color Colorimetry Drug Design Organometallic Compounds - chemistry Rhodium - chemistry
Online-Zugang:	Volltext
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