Transferable and Flexible Nanorod-Assembled TiO2 Cloths for Dye-Sensitized Solar Cells, Photodetectors, and Photocatalysts

Flexible and transferable TiO2 nanorods cloths (TNRCs) were synthesized from a fast and catalyst-free microwave heating route by using carbon cloth as an efficiently sacrificial template. The as-synthesized TNRCs were assembled by numerous aligned TiO2 nanorods with diameters of about 100 nm. The go...

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Veröffentlicht in:ACS nano 2011-10, Vol.5 (10), p.8412-8419
Hauptverfasser: Wang, Zhuoran, Wang, Heng, Liu, Bin, Qiu, Wenzhe, Zhang, Jun, Ran, Sihan, Huang, Hongtao, Xu, Jing, Han, Hongwei, Chen, Di, Shen, Guozhen
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container_end_page 8419
container_issue 10
container_start_page 8412
container_title ACS nano
container_volume 5
creator Wang, Zhuoran
Wang, Heng
Liu, Bin
Qiu, Wenzhe
Zhang, Jun
Ran, Sihan
Huang, Hongtao
Xu, Jing
Han, Hongwei
Chen, Di
Shen, Guozhen
description Flexible and transferable TiO2 nanorods cloths (TNRCs) were synthesized from a fast and catalyst-free microwave heating route by using carbon cloth as an efficiently sacrificial template. The as-synthesized TNRCs were assembled by numerous aligned TiO2 nanorods with diameters of about 100 nm. The good transferability and flexibility make it possible to be transferred to any substrate for further device applications. As an example, we transferred the TNRCs to a FTO substrate to make dye-sensitized solar cells, which exhibited an improved efficiency of around 2.21% assisted by TiCl4 treatment. The transferable TNRCs were also configured as high-performance photodetectors. Illuminated by UV light with a wavelength of 365 nm, the current was found significantly enhanced, and an I UV/I dark of about 60, a rise time of nearly 1.4 s, and a decay time of 6.1 s were obtained. Moreover, they were also configured as flexible and recyclable photocatalysts with good photocatalytic performance for the degradation of methylene blue solution under UV light irradiation.
doi_str_mv 10.1021/nn203315k
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