Surface functionalization of electro-deposited nickel

A new in situ electrochemical method of functionalizing an oxide-free Ni surface is demonstrated using octanethiol. Initial adsorption results in a multilayer molecular film, which blocks both the hydrogen evolution reaction (HER) and re-oxidation of the Ni by ambient oxygen. However, excess octanet...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2011-10, Vol.13 (40), p.17987-17993
Hauptverfasser:	SADLER, James E, SZUMSKI, Doug S, SCHWARZACHER, Walther, KIERZKOWSKA, Agnieska, CATARELLI, Samantha R, STELLA, Kevin, NICHOLS, Richard J, FONTICELLI, Mariano H, BENITEZ, Guillermo, BLUM, Bárbara, SALVAREZZA, Roberto C
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Ethanol Ethyl alcohol Exact sciences and technology General and physical chemistry Monolayers Multilayers Nickel Oxidation Spectroscopy Surface chemistry Surface physical chemistry
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