Direct and Simple Electrochemical Determination of Morphine at PEDOT Modified Pt Electrode
A simple and rapid method for morphine detection is described based on PEDOT electrode in the presence of SDS. The electrochemistry of morphine is investigated by CV, LSV and SWV. The effect of common interferences on the current response of morphine namely AA and UA is studied. The electrode is app...
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Veröffentlicht in: | Electroanalysis (New York, N.Y.) N.Y.), 2011-03, Vol.23 (3), p.737-746 |
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description | A simple and rapid method for morphine detection is described based on PEDOT electrode in the presence of SDS. The electrochemistry of morphine is investigated by CV, LSV and SWV. The effect of common interferences on the current response of morphine namely AA and UA is studied. The electrode is applied to the selective determination of morphine in urine samples in the linear ranges 0.3–8 µmol L−1 and 10–60 µmol L−1, with low detection limits of 50 and 68 nmol L−1, respectively and recovery of 96.4 %. The application of PEDOT is realized in determination of morphine in tablets successfully. |
doi_str_mv | 10.1002/elan.201000600 |
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The electrochemistry of morphine is investigated by CV, LSV and SWV. The effect of common interferences on the current response of morphine namely AA and UA is studied. The electrode is applied to the selective determination of morphine in urine samples in the linear ranges 0.3–8 µmol L−1 and 10–60 µmol L−1, with low detection limits of 50 and 68 nmol L−1, respectively and recovery of 96.4 %. The application of PEDOT is realized in determination of morphine in tablets successfully.</description><identifier>ISSN: 1040-0397</identifier><identifier>ISSN: 1521-4109</identifier><identifier>EISSN: 1521-4109</identifier><identifier>DOI: 10.1002/elan.201000600</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>4-ethylenedioxythiophene ; Codeine ; Electrochemistry ; Electrodes ; Electrolytic analysis ; Morphine ; Narcotics ; Platinum ; Poly ; Poly(3,4‐ethylenedioxythiophene) ; Recovery ; Surfactants ; Tablets ; Urine</subject><ispartof>Electroanalysis (New York, N.Y.), 2011-03, Vol.23 (3), p.737-746</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. 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The electrochemistry of morphine is investigated by CV, LSV and SWV. The effect of common interferences on the current response of morphine namely AA and UA is studied. The electrode is applied to the selective determination of morphine in urine samples in the linear ranges 0.3–8 µmol L−1 and 10–60 µmol L−1, with low detection limits of 50 and 68 nmol L−1, respectively and recovery of 96.4 %. The application of PEDOT is realized in determination of morphine in tablets successfully.</description><subject>4-ethylenedioxythiophene</subject><subject>Codeine</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Electrolytic analysis</subject><subject>Morphine</subject><subject>Narcotics</subject><subject>Platinum</subject><subject>Poly</subject><subject>Poly(3,4‐ethylenedioxythiophene)</subject><subject>Recovery</subject><subject>Surfactants</subject><subject>Tablets</subject><subject>Urine</subject><issn>1040-0397</issn><issn>1521-4109</issn><issn>1521-4109</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqNkDtPwzAQgCMEEuWxMntjSjnHTmKPVVteKrSCAhKL5ToX1ZBHsYOAf4-rAmKDyafT952sL4qOKPQpQHKClW76CYQZMoCtqEfThMacgtwOM3CIgcl8N9rz_ikwMuOyFz2OrEPTEd0U5NbWqwrJuAoL15ol1tboioywQ1fbRne2bUhbkqvWrZa2QaI7MhuPpvOwKWxpsSCz7lsv8CDaKXXl8fDr3Y_uTsfz4Xk8mZ5dDAeT2DBJIS7DTwpASReZhgVPOC-FzpgEIbQotUTJhUx4qhENh0XBOKdaGGYoNTxlgu1Hx5u7K9e-vKLvVG29wSrkwPbVKyGzhIlc8v-QNAtd1mR_QxrXeu-wVCtna-0-FAW1rq3WtdVP7SDIjfBmK_z4g1bjyeD6txtvXOs7fP9xtXtWWc7yVD1cn6n7Gz7jeZaqS_YJMGmRRA</recordid><startdate>201103</startdate><enddate>201103</enddate><creator>Atta, Nada F.</creator><creator>Galal, Ahmed</creator><creator>Ahmed, Rasha A.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>201103</creationdate><title>Direct and Simple Electrochemical Determination of Morphine at PEDOT Modified Pt Electrode</title><author>Atta, Nada F. ; Galal, Ahmed ; Ahmed, Rasha A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3910-f096d0e91b6a0b4244f8a639088a8fa9e9489245aeec40bd3441a8c3c11c45383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>4-ethylenedioxythiophene</topic><topic>Codeine</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Electrolytic analysis</topic><topic>Morphine</topic><topic>Narcotics</topic><topic>Platinum</topic><topic>Poly</topic><topic>Poly(3,4‐ethylenedioxythiophene)</topic><topic>Recovery</topic><topic>Surfactants</topic><topic>Tablets</topic><topic>Urine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Atta, Nada F.</creatorcontrib><creatorcontrib>Galal, Ahmed</creatorcontrib><creatorcontrib>Ahmed, Rasha A.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electroanalysis (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Atta, Nada F.</au><au>Galal, Ahmed</au><au>Ahmed, Rasha A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct and Simple Electrochemical Determination of Morphine at PEDOT Modified Pt Electrode</atitle><jtitle>Electroanalysis (New York, N.Y.)</jtitle><addtitle>Electroanalysis</addtitle><date>2011-03</date><risdate>2011</risdate><volume>23</volume><issue>3</issue><spage>737</spage><epage>746</epage><pages>737-746</pages><issn>1040-0397</issn><issn>1521-4109</issn><eissn>1521-4109</eissn><abstract>A simple and rapid method for morphine detection is described based on PEDOT electrode in the presence of SDS. The electrochemistry of morphine is investigated by CV, LSV and SWV. The effect of common interferences on the current response of morphine namely AA and UA is studied. The electrode is applied to the selective determination of morphine in urine samples in the linear ranges 0.3–8 µmol L−1 and 10–60 µmol L−1, with low detection limits of 50 and 68 nmol L−1, respectively and recovery of 96.4 %. The application of PEDOT is realized in determination of morphine in tablets successfully.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/elan.201000600</doi><tpages>10</tpages></addata></record> |
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subjects | 4-ethylenedioxythiophene Codeine Electrochemistry Electrodes Electrolytic analysis Morphine Narcotics Platinum Poly Poly(3,4‐ethylenedioxythiophene) Recovery Surfactants Tablets Urine |
title | Direct and Simple Electrochemical Determination of Morphine at PEDOT Modified Pt Electrode |
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