Simultaneous determination of a pyridine-triphenylborane anti-fouling agent and its estimated degradation products using capillary zone electrophoresis
A commercial organoborane compound, pyridine-triphenylborane (PTPB), is often applied to ship hulls as an anti-fouling agent. We developed capillary zone electrophoresis (CZE) with direct UV detection for the simultaneous determination of PTPB and its estimated degradation products: diphenylborinic...
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| Veröffentlicht in: | Journal of Chromatography A 2010-04, Vol.1217 (14), p.2187-2190 |
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| creator | Fukushi, Keiichi Yakushiji, Yuki Okamura, Hideo Hashimoto, Youichi Saito, Keiitsu |
| description | A commercial organoborane compound, pyridine-triphenylborane (PTPB), is often applied to ship hulls as an anti-fouling agent. We developed capillary zone electrophoresis (CZE) with direct UV detection for the simultaneous determination of PTPB and its estimated degradation products: diphenylborinic acid (DPB), phenylboronic acid (MPB), and phenol. The limits of detection (LODs) for PTPB, DPB, MPB, and phenol were, respectively, 25, 30, 50, and 29
μg/l at a signal-to-noise ratio of three. At concentrations of 0.5
mg/l, values of the relative standard deviation (RSD,
n
=
6, intra-day) of peak area were obtained, respectively, for PTPB, DPB, MPB, and phenol, as 4.1, 4.1, 4.7, and 3.4% for peak heights 3.6, 3.2, 1.7, and 1.4%, and for migration times 1.1, 1.1, 1.0, and 0.73%. The analytes were detected within 14
min. Simple photodegradation experiments were conducted to verify the usefulness of the proposed method for additional PTPB degradation investigations. |
| doi_str_mv | 10.1016/j.chroma.2010.01.087 |
| format | Article |
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μg/l at a signal-to-noise ratio of three. At concentrations of 0.5
mg/l, values of the relative standard deviation (RSD,
n
=
6, intra-day) of peak area were obtained, respectively, for PTPB, DPB, MPB, and phenol, as 4.1, 4.1, 4.7, and 3.4% for peak heights 3.6, 3.2, 1.7, and 1.4%, and for migration times 1.1, 1.1, 1.0, and 0.73%. The analytes were detected within 14
min. Simple photodegradation experiments were conducted to verify the usefulness of the proposed method for additional PTPB degradation investigations.</description><identifier>ISSN: 0021-9673</identifier><identifier>EISSN: 1873-3778</identifier><identifier>DOI: 10.1016/j.chroma.2010.01.087</identifier><identifier>PMID: 20189577</identifier><identifier>CODEN: JOCRAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Acetonitriles - chemistry ; Analytical chemistry ; Boranes - analysis ; Boranes - chemistry ; Boron Compounds - analysis ; Boron Compounds - chemistry ; Boronic Acids - analysis ; Boronic Acids - chemistry ; Capillarity ; Capillary zone electrophoresis ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Chromatography ; Degradation ; Diphenylborinic acid ; Electrophoresis ; Electrophoresis, Capillary - methods ; Exact sciences and technology ; Hydrogen-Ion Concentration ; Migration ; Other chromatographic methods ; Pesticides - analysis ; Pesticides - chemistry ; Phenol ; Phenol - analysis ; Phenol - chemistry ; Phenylboronic acid ; Photolysis ; Pyridine-triphenylborane ; Pyridines - analysis ; Pyridines - chemistry ; Reproducibility of Results ; Sensitivity and Specificity ; Signal to noise ratio ; Sodium Hydroxide - chemistry ; Standard deviation</subject><ispartof>Journal of Chromatography A, 2010-04, Vol.1217 (14), p.2187-2190</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright (c) 2010 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c636t-722d18286973b3cdb8ebebe8cc8d8804d8a3d9ab67e7a5117d7144c19576b0153</citedby><cites>FETCH-LOGICAL-c636t-722d18286973b3cdb8ebebe8cc8d8804d8a3d9ab67e7a5117d7144c19576b0153</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0021967310001640$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22525470$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20189577$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fukushi, Keiichi</creatorcontrib><creatorcontrib>Yakushiji, Yuki</creatorcontrib><creatorcontrib>Okamura, Hideo</creatorcontrib><creatorcontrib>Hashimoto, Youichi</creatorcontrib><creatorcontrib>Saito, Keiitsu</creatorcontrib><title>Simultaneous determination of a pyridine-triphenylborane anti-fouling agent and its estimated degradation products using capillary zone electrophoresis</title><title>Journal of Chromatography A</title><addtitle>J Chromatogr A</addtitle><description>A commercial organoborane compound, pyridine-triphenylborane (PTPB), is often applied to ship hulls as an anti-fouling agent. We developed capillary zone electrophoresis (CZE) with direct UV detection for the simultaneous determination of PTPB and its estimated degradation products: diphenylborinic acid (DPB), phenylboronic acid (MPB), and phenol. The limits of detection (LODs) for PTPB, DPB, MPB, and phenol were, respectively, 25, 30, 50, and 29
μg/l at a signal-to-noise ratio of three. At concentrations of 0.5
mg/l, values of the relative standard deviation (RSD,
n
=
6, intra-day) of peak area were obtained, respectively, for PTPB, DPB, MPB, and phenol, as 4.1, 4.1, 4.7, and 3.4% for peak heights 3.6, 3.2, 1.7, and 1.4%, and for migration times 1.1, 1.1, 1.0, and 0.73%. The analytes were detected within 14
min. Simple photodegradation experiments were conducted to verify the usefulness of the proposed method for additional PTPB degradation investigations.</description><subject>Acetonitriles - chemistry</subject><subject>Analytical chemistry</subject><subject>Boranes - analysis</subject><subject>Boranes - chemistry</subject><subject>Boron Compounds - analysis</subject><subject>Boron Compounds - chemistry</subject><subject>Boronic Acids - analysis</subject><subject>Boronic Acids - chemistry</subject><subject>Capillarity</subject><subject>Capillary zone electrophoresis</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Chromatography</subject><subject>Degradation</subject><subject>Diphenylborinic acid</subject><subject>Electrophoresis</subject><subject>Electrophoresis, Capillary - methods</subject><subject>Exact sciences and technology</subject><subject>Hydrogen-Ion Concentration</subject><subject>Migration</subject><subject>Other chromatographic methods</subject><subject>Pesticides - analysis</subject><subject>Pesticides - chemistry</subject><subject>Phenol</subject><subject>Phenol - analysis</subject><subject>Phenol - chemistry</subject><subject>Phenylboronic acid</subject><subject>Photolysis</subject><subject>Pyridine-triphenylborane</subject><subject>Pyridines - analysis</subject><subject>Pyridines - chemistry</subject><subject>Reproducibility of Results</subject><subject>Sensitivity and Specificity</subject><subject>Signal to noise ratio</subject><subject>Sodium Hydroxide - chemistry</subject><subject>Standard deviation</subject><issn>0021-9673</issn><issn>1873-3778</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kc1u1DAUhS0EokPhDRBkg8omg3-S2Nkgoar8SJVYlK4tx76Z8SiJg-0gDS_C63KHDLCrvLBkf_f4-BxCXjK6ZZQ17w5bu49hNFtO8YiyLVXyEdkwJUUppFSPyYZSzsq2keKCPEvpQCmTVPKn5AJHVFtLuSG_7vy4DNlMEJZUOMgQRz-Z7MNUhL4wxXyM3vkJyhz9vIfpOHQhIl6YKfuyD8vgp11hdjBlPHKFz6mAlP1oMjgU3EXjVrk5BrdYvF7SacSa2Q-DicfiZ0A5GMDmGOZ9iJB8ek6e9GZI8OK8X5L7jzffrj-Xt18_fbn-cFvaRjS5lJw7prhqWik6YV2noMOlrFVOKVo5ZYRrTddIkKZmTDrJqsoy_HzTUVaLS3K16qK77wsa16NPFtDYn0S0ahvOeS0Fkm8fJFlTca4YExLRakVtDClF6PUcMZB41IzqU3n6oNfy9Kk8TZnG8nDs1fmFpRvB_Rv62xYCb86ASdYMPfZgffrP8ZrXlaTIvV653gRtdhGZ-ztUESjEMLeT0vuVAMz2h4eok_UwWXA-Yg_aBf-w199bfscy</recordid><startdate>20100402</startdate><enddate>20100402</enddate><creator>Fukushi, Keiichi</creator><creator>Yakushiji, Yuki</creator><creator>Okamura, Hideo</creator><creator>Hashimoto, Youichi</creator><creator>Saito, Keiitsu</creator><general>Elsevier B.V</general><general>Amsterdam; New York: Elsevier</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>7QH</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>H97</scope><scope>L.G</scope></search><sort><creationdate>20100402</creationdate><title>Simultaneous determination of a pyridine-triphenylborane anti-fouling agent and its estimated degradation products using capillary zone electrophoresis</title><author>Fukushi, Keiichi ; Yakushiji, Yuki ; Okamura, Hideo ; Hashimoto, Youichi ; Saito, Keiitsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c636t-722d18286973b3cdb8ebebe8cc8d8804d8a3d9ab67e7a5117d7144c19576b0153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Acetonitriles - chemistry</topic><topic>Analytical chemistry</topic><topic>Boranes - analysis</topic><topic>Boranes - chemistry</topic><topic>Boron Compounds - analysis</topic><topic>Boron Compounds - chemistry</topic><topic>Boronic Acids - analysis</topic><topic>Boronic Acids - chemistry</topic><topic>Capillarity</topic><topic>Capillary zone electrophoresis</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Chromatography</topic><topic>Degradation</topic><topic>Diphenylborinic acid</topic><topic>Electrophoresis</topic><topic>Electrophoresis, Capillary - methods</topic><topic>Exact sciences and technology</topic><topic>Hydrogen-Ion Concentration</topic><topic>Migration</topic><topic>Other chromatographic methods</topic><topic>Pesticides - analysis</topic><topic>Pesticides - chemistry</topic><topic>Phenol</topic><topic>Phenol - analysis</topic><topic>Phenol - chemistry</topic><topic>Phenylboronic acid</topic><topic>Photolysis</topic><topic>Pyridine-triphenylborane</topic><topic>Pyridines - analysis</topic><topic>Pyridines - chemistry</topic><topic>Reproducibility of Results</topic><topic>Sensitivity and Specificity</topic><topic>Signal to noise ratio</topic><topic>Sodium Hydroxide - chemistry</topic><topic>Standard deviation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fukushi, Keiichi</creatorcontrib><creatorcontrib>Yakushiji, Yuki</creatorcontrib><creatorcontrib>Okamura, Hideo</creatorcontrib><creatorcontrib>Hashimoto, Youichi</creatorcontrib><creatorcontrib>Saito, Keiitsu</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Aqualine</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fukushi, Keiichi</au><au>Yakushiji, Yuki</au><au>Okamura, Hideo</au><au>Hashimoto, Youichi</au><au>Saito, Keiitsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Simultaneous determination of a pyridine-triphenylborane anti-fouling agent and its estimated degradation products using capillary zone electrophoresis</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>2010-04-02</date><risdate>2010</risdate><volume>1217</volume><issue>14</issue><spage>2187</spage><epage>2190</epage><pages>2187-2190</pages><issn>0021-9673</issn><eissn>1873-3778</eissn><coden>JOCRAM</coden><abstract>A commercial organoborane compound, pyridine-triphenylborane (PTPB), is often applied to ship hulls as an anti-fouling agent. We developed capillary zone electrophoresis (CZE) with direct UV detection for the simultaneous determination of PTPB and its estimated degradation products: diphenylborinic acid (DPB), phenylboronic acid (MPB), and phenol. The limits of detection (LODs) for PTPB, DPB, MPB, and phenol were, respectively, 25, 30, 50, and 29
μg/l at a signal-to-noise ratio of three. At concentrations of 0.5
mg/l, values of the relative standard deviation (RSD,
n
=
6, intra-day) of peak area were obtained, respectively, for PTPB, DPB, MPB, and phenol, as 4.1, 4.1, 4.7, and 3.4% for peak heights 3.6, 3.2, 1.7, and 1.4%, and for migration times 1.1, 1.1, 1.0, and 0.73%. The analytes were detected within 14
min. Simple photodegradation experiments were conducted to verify the usefulness of the proposed method for additional PTPB degradation investigations.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>20189577</pmid><doi>10.1016/j.chroma.2010.01.087</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Acetonitriles - chemistry Analytical chemistry Boranes - analysis Boranes - chemistry Boron Compounds - analysis Boron Compounds - chemistry Boronic Acids - analysis Boronic Acids - chemistry Capillarity Capillary zone electrophoresis Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography Degradation Diphenylborinic acid Electrophoresis Electrophoresis, Capillary - methods Exact sciences and technology Hydrogen-Ion Concentration Migration Other chromatographic methods Pesticides - analysis Pesticides - chemistry Phenol Phenol - analysis Phenol - chemistry Phenylboronic acid Photolysis Pyridine-triphenylborane Pyridines - analysis Pyridines - chemistry Reproducibility of Results Sensitivity and Specificity Signal to noise ratio Sodium Hydroxide - chemistry Standard deviation |
| title | Simultaneous determination of a pyridine-triphenylborane anti-fouling agent and its estimated degradation products using capillary zone electrophoresis |
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