Synthesis of new boron complexes: application to transfer hydrogenation of acetophenone derivatives

Two new boron complexes were synthesized from N‐[3‐(methylmercapto)aniline]‐3,5‐di‐tert‐butylsalicylaldimine (LH) with boron reagent BPh3 or BF3.Et2O. These boron complexes are stable and easily soluble in protic solvents such as ethanol (C2H5OH) but hardly soluble in nonprotic solvents such as chlo...

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Veröffentlicht in:	Applied organometallic chemistry 2011-05, Vol.25 (5), p.390-394
Hauptverfasser:	Kilic, Ahmet, Kayan, Cezmi, Aydemir, Murat, Durap, Feyyaz, Durgun, Mustaf1, Baysal, Akın, Tas, Esref, Gümgüm, Bahattin
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetophenone BF3.Et2O Boron boron complexes BPh3 Catalysts Derivatives Ethanol Ethyl alcohol Hydrogenation Solvents synthesis transfer hydrogenation
Online-Zugang:	Volltext
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