Crystal chemistry of the monazite structure

The AXO 4 monazite-type compounds form an extended family that is described in this review in terms of field of stability versus composition. All the substitution possibilities on the cationic and anionic sites leading to the monazite structure are reported. The phosphate, vanadate, chromate, arseni...

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Veröffentlicht in:Journal of the European Ceramic Society 2011-06, Vol.31 (6), p.941-976
Hauptverfasser: Clavier, Nicolas, Podor, Renaud, Dacheux, Nicolas
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Podor, Renaud
Dacheux, Nicolas
description The AXO 4 monazite-type compounds form an extended family that is described in this review in terms of field of stability versus composition. All the substitution possibilities on the cationic and anionic sites leading to the monazite structure are reported. The phosphate, vanadate, chromate, arseniate, sulphate and silicate families are described and the unit-cell parameters of pure compounds and solid solutions are gathered. The stability limits of the monazite-type structure are discussed versus several models generally correlated with geometric criteria. The effects of physico-chemical parameters such as pressure, temperature and irradiation on the monazite-type structure stability are also discussed. The structural relationships between the monazite structure and the related structures (zircon, anhydrite, barite, AgMnO 4, scheelite and monoclinic BiPO 4, CaSeO 3, rhabdophane and SrNp(PO 4) 2) are described.
doi_str_mv 10.1016/j.jeurceramsoc.2010.12.019
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subjects Cationic
Chromates
Functional applications
Mathematical models
Monazite
Phosphate
Phosphates
Stability
Structure
Sulfates
Vanadates
title Crystal chemistry of the monazite structure
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