Effects of post-treatments on microstructure and hydrogen storage performance of the carbon nano-tubes prepared via a metal dusting process

Preparation of multi-wall carbon nano-tubes (CNTs) is successfully demonstrated via a metal dusting (MD) process, in which a steel coupon and CO–CO 2 mixed gas are the only reactants needed. During the process, fresh Fe–Ni nano-particles are produced spontaneously and continuously from the steel, an...

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Veröffentlicht in:Journal of power sources 2008-07, Vol.182 (1), p.317-322
Hauptverfasser: Chang, Jeng-Kuei, Tsai, Heng-Yi, Tsai, Wen-Ta
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container_title Journal of power sources
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creator Chang, Jeng-Kuei
Tsai, Heng-Yi
Tsai, Wen-Ta
description Preparation of multi-wall carbon nano-tubes (CNTs) is successfully demonstrated via a metal dusting (MD) process, in which a steel coupon and CO–CO 2 mixed gas are the only reactants needed. During the process, fresh Fe–Ni nano-particles are produced spontaneously and continuously from the steel, and consequently catalyze the growth of the CNTs. Post-treatments, including heating in air at 550 °C and etching in boiling nitric acid, are used to purify the as-prepared multi-wall CNTs. The microstructure modification due to the post-treatments are examined with a transmission electron microscopy. The possibility of utilizing the MD-produced CNTs as a hydrogen storage material is also explored in this study.
doi_str_mv 10.1016/j.jpowsour.2008.03.063
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subjects Alternative fuels. Production and utilization
Applied sciences
Carbon
Carbon nano-tubes
Energy
Exact sciences and technology
Fuels
Hydrogen
Hydrogen storage
Hydrogen storage materials
Metal dusting
Microstructure
Nanocomposites
Nanomaterials
Nanostructure
Post-treatment
Steels
title Effects of post-treatments on microstructure and hydrogen storage performance of the carbon nano-tubes prepared via a metal dusting process
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