An analysis of temperature dependent current―voltage characteristics of Cu2O―ZnO heterojunction solar cells

Carrier transport and recombination mechanisms in Cu2O-ZnO heterojunction thin film solar cells were investigated through an analysis of their current-voltage characteristics in the dark and under various illumination intensities, as a function of temperature between 100K and 295K. The Cu2O-ZnO hete...

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Veröffentlicht in:Thin solid films 2011-07, Vol.519 (19), p.6613-6619
Hauptverfasser: JEONG, Seongho, SANG HO SONG, NAGAICH, Kushagra, CAMPBELL, Stephen A, AYDIL, Eray S
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container_end_page 6619
container_issue 19
container_start_page 6613
container_title Thin solid films
container_volume 519
creator JEONG, Seongho
SANG HO SONG
NAGAICH, Kushagra
CAMPBELL, Stephen A
AYDIL, Eray S
description Carrier transport and recombination mechanisms in Cu2O-ZnO heterojunction thin film solar cells were investigated through an analysis of their current-voltage characteristics in the dark and under various illumination intensities, as a function of temperature between 100K and 295K. The Cu2O-ZnO heterojunction solar cells were prepared by metal organic chemical vapor deposition of Cu2O on ZnO films sputtered on transparent conducting oxide coated glass substrates. Activation energies extracted from the temperature dependence of the J-V characteristics reveals that interface recombination is the dominant carrier transport mechanism. Tunneling across an interfacial barrier also plays an important role in current flow and a thin TiO2 buffer layer reduces tunneling. A high open circuit voltage at low temperature (~0.9V at around 100K) indicates that Cu2O-ZnO heterojunction solar cells have high potential as solar cells if the recombination and tunneling at the interface can be suppressed at room temperature.
doi_str_mv 10.1016/j.tsf.2011.04.241
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source Elsevier ScienceDirect Journals Complete
subjects Applied sciences
Carrier transport
CHEMICAL VAPOR DEPOSITION
Chemical vapor deposition (including plasma-enhanced cvd, mocvd, etc.)
Condensed matter: electronic structure, electrical, magnetic, and optical properties
COPPER OXIDE
Cross-disciplinary physics: materials science
rheology
CUPROUS OXIDE
Deposition by sputtering
Electrical properties of specific thin films
Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures
Energy
Exact sciences and technology
Heterojunctions
INTERFACES
Materials science
Methods of deposition of films and coatings
film growth and epitaxy
Natural energy
Open circuit voltage
Photovoltaic cells
Photovoltaic conversion
Physics
SOLAR CELLS
Solar cells. Photoelectrochemical cells
Solar energy
THIN FILMS
TITANIUM DIOXIDE
Tunneling
VOLTAGE
ZINC OXIDE
title An analysis of temperature dependent current―voltage characteristics of Cu2O―ZnO heterojunction solar cells
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