The important role of additives for improved lithium ion battery safety

1,3-Propane sultone (PS) additive for graphite electrodes was studied for propylene carbonate (PC) and ethylene carbonate (EC)-based electrolytes in lithium batteries. Decomposition of solvents with graphite electrodes could be remarkably suppressed by addition of the PS additive in the PC-based ele...

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Veröffentlicht in:Journal of power sources 2009-04, Vol.189 (1), p.602-606
Hauptverfasser: Park, Gumjae, Nakamura, Hiroyoshi, Lee, Yunsung, Yoshio, Masaki
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container_end_page 606
container_issue 1
container_start_page 602
container_title Journal of power sources
container_volume 189
creator Park, Gumjae
Nakamura, Hiroyoshi
Lee, Yunsung
Yoshio, Masaki
description 1,3-Propane sultone (PS) additive for graphite electrodes was studied for propylene carbonate (PC) and ethylene carbonate (EC)-based electrolytes in lithium batteries. Decomposition of solvents with graphite electrodes could be remarkably suppressed by addition of the PS additive in the PC-based electrolyte, leading to improvement of electrochemical performances of the cells. The 1,3-propane sultone additive showed very interesting properties for the graphite electrode. It is predicted to give a solid electrolyte interphase (SEI) on the surface of the graphite prior to solvent decomposition and bring about effects that not only suppress lithium deposition on the graphite electrode surface, but also accelerate lithium intercalation, leading to formation of LiC 6 onto graphite electrode.
doi_str_mv 10.1016/j.jpowsour.2008.09.088
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subjects 1,3-Propane sultone
Additive
Applied sciences
Carbonates
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Electrodes
Electrolytes
Exact sciences and technology
Graphite
Li deposition
Li intercalation
Lithium
Lithium-ion batteries
Polystyrene resins
Solvents
title The important role of additives for improved lithium ion battery safety
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