The important role of additives for improved lithium ion battery safety
1,3-Propane sultone (PS) additive for graphite electrodes was studied for propylene carbonate (PC) and ethylene carbonate (EC)-based electrolytes in lithium batteries. Decomposition of solvents with graphite electrodes could be remarkably suppressed by addition of the PS additive in the PC-based ele...
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Veröffentlicht in: | Journal of power sources 2009-04, Vol.189 (1), p.602-606 |
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creator | Park, Gumjae Nakamura, Hiroyoshi Lee, Yunsung Yoshio, Masaki |
description | 1,3-Propane sultone (PS) additive for graphite electrodes was studied for propylene carbonate (PC) and ethylene carbonate (EC)-based electrolytes in lithium batteries. Decomposition of solvents with graphite electrodes could be remarkably suppressed by addition of the PS additive in the PC-based electrolyte, leading to improvement of electrochemical performances of the cells. The 1,3-propane sultone additive showed very interesting properties for the graphite electrode. It is predicted to give a solid electrolyte interphase (SEI) on the surface of the graphite prior to solvent decomposition and bring about effects that not only suppress lithium deposition on the graphite electrode surface, but also accelerate lithium intercalation, leading to formation of LiC
6 onto graphite electrode. |
doi_str_mv | 10.1016/j.jpowsour.2008.09.088 |
format | Article |
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6 onto graphite electrode.</description><subject>1,3-Propane sultone</subject><subject>Additive</subject><subject>Applied sciences</subject><subject>Carbonates</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Exact sciences and technology</subject><subject>Graphite</subject><subject>Li deposition</subject><subject>Li intercalation</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Polystyrene resins</subject><subject>Solvents</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkE1vEzEQhi0EEqHwF5AvCC67zHg_bN9AVWkrVeJSzpbXnlUdbdbBdoLy73GUwhFOc5jnnXf0MPYeoUXA8fO23e7jrxwPqRUAqgXdglIv2AaV7Bohh-El20AnVSPl0L1mb3LeAgCihA27fXwiHnb7mIpdC09xIR5nbr0PJRwp8zmm8z7FI3m-hPIUDjse4sonWwqlE892pnJ6y17Ndsn07nlesR_fbh6v75qH77f3118fGteDLM0IXmuyVo-jApiEGBzYeVZOYjd5cHpC3YPvXD9NSqAH9L2fBqEH75VQ2F2xj5e79aOfB8rF7EJ2tCx2pXjIRukR1SCwq-Snf5IopcReVYMVHS-oSzHnRLPZp7Cz6WQQzNmx2Zo_js3ZsQFtquMa_PDcYbOzy5zs6kL-mxY46q6-XbkvF46qmmOgZLILtDryIZErxsfwv6rfoaeWMQ</recordid><startdate>20090401</startdate><enddate>20090401</enddate><creator>Park, Gumjae</creator><creator>Nakamura, Hiroyoshi</creator><creator>Lee, Yunsung</creator><creator>Yoshio, Masaki</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>7ST</scope><scope>SOI</scope></search><sort><creationdate>20090401</creationdate><title>The important role of additives for improved lithium ion battery safety</title><author>Park, Gumjae ; Nakamura, Hiroyoshi ; Lee, Yunsung ; Yoshio, Masaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c407t-60d99eaa966800b225c0aff8c713bd0c9b1940d3c4bb821d01d4db5295dd82813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>1,3-Propane sultone</topic><topic>Additive</topic><topic>Applied sciences</topic><topic>Carbonates</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Exact sciences and technology</topic><topic>Graphite</topic><topic>Li deposition</topic><topic>Li intercalation</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Polystyrene resins</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Park, Gumjae</creatorcontrib><creatorcontrib>Nakamura, Hiroyoshi</creatorcontrib><creatorcontrib>Lee, Yunsung</creatorcontrib><creatorcontrib>Yoshio, Masaki</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Park, Gumjae</au><au>Nakamura, Hiroyoshi</au><au>Lee, Yunsung</au><au>Yoshio, Masaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The important role of additives for improved lithium ion battery safety</atitle><jtitle>Journal of power sources</jtitle><date>2009-04-01</date><risdate>2009</risdate><volume>189</volume><issue>1</issue><spage>602</spage><epage>606</epage><pages>602-606</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>1,3-Propane sultone (PS) additive for graphite electrodes was studied for propylene carbonate (PC) and ethylene carbonate (EC)-based electrolytes in lithium batteries. Decomposition of solvents with graphite electrodes could be remarkably suppressed by addition of the PS additive in the PC-based electrolyte, leading to improvement of electrochemical performances of the cells. The 1,3-propane sultone additive showed very interesting properties for the graphite electrode. It is predicted to give a solid electrolyte interphase (SEI) on the surface of the graphite prior to solvent decomposition and bring about effects that not only suppress lithium deposition on the graphite electrode surface, but also accelerate lithium intercalation, leading to formation of LiC
6 onto graphite electrode.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2008.09.088</doi><tpages>5</tpages></addata></record> |
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subjects | 1,3-Propane sultone Additive Applied sciences Carbonates Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrodes Electrolytes Exact sciences and technology Graphite Li deposition Li intercalation Lithium Lithium-ion batteries Polystyrene resins Solvents |
title | The important role of additives for improved lithium ion battery safety |
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