Ionic conductivity studies of gel polyelectrolyte based on ionic liquid
Novel lithium polyelectrolyte-ionic liquids have been prepared and characterized of their properties. Poly(lithium 2-acrylamido-2-methyl propanesulfonate) (PAMPSLi) and its copolymer with N-vinyl formamide (VF) also has been prepared as a copolymer. 1-Ethyl-3-methylimidazolium tricyanomethanide (emI...
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| Veröffentlicht in: | Journal of power sources 2008-04, Vol.178 (2), p.779-782 |
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| container_title | Journal of power sources |
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| creator | Cha, E.H. Lim, S.A. Park, J.H. Kim, D.W. Macfarlane, D.R. |
| description | Novel lithium polyelectrolyte-ionic liquids have been prepared and characterized of their properties. Poly(lithium 2-acrylamido-2-methyl propanesulfonate) (PAMPSLi) and its copolymer with
N-vinyl formamide (VF) also has been prepared as a copolymer. 1-Ethyl-3-methylimidazolium tricyanomethanide (emImTCM) and
N,
N-dimethyl-
N-propyl-
N-butyl ammonium tricyanomethanide (N
1134TCM) which are chosen because of the same with the anion of ionic liquid were prepared. The ionic conductivity of copolymer system (PAMPSLi/PVF/emImTCM: 5.43
×
10
−3
S
cm
−1 at 25
°C) exhibits about over four times higher than that of homopolymer system (PAMPSLi/emImTCM: 1.28
×
10
−3
S
cm
−1 at 25
°C). Introduction of vinyl formamide into the copolymer type can increase the dissociation of the lithium cations from the polymer backbone. The ionic conductivity of copolymer with emImTCM (PAMPSLi/PVF/emImTCM) exhibits the higher conductivity than that of PAMPSLi/PVF/N
1134TCM (2.48
×
10
−3
S
cm
−1). Because of using the polymerizable anion it is seen to maintain high flexibility of imidazolium cation effectively to exhibit the higher conductivity. And also the viscosity of emImTCM (19.56
cP) is lower than that of N
1134TCM (28.61
cP). Low viscosity leads to a fast rate of diffusion of redox species. |
| doi_str_mv | 10.1016/j.jpowsour.2007.10.033 |
| format | Article |
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N-vinyl formamide (VF) also has been prepared as a copolymer. 1-Ethyl-3-methylimidazolium tricyanomethanide (emImTCM) and
N,
N-dimethyl-
N-propyl-
N-butyl ammonium tricyanomethanide (N
1134TCM) which are chosen because of the same with the anion of ionic liquid were prepared. The ionic conductivity of copolymer system (PAMPSLi/PVF/emImTCM: 5.43
×
10
−3
S
cm
−1 at 25
°C) exhibits about over four times higher than that of homopolymer system (PAMPSLi/emImTCM: 1.28
×
10
−3
S
cm
−1 at 25
°C). Introduction of vinyl formamide into the copolymer type can increase the dissociation of the lithium cations from the polymer backbone. The ionic conductivity of copolymer with emImTCM (PAMPSLi/PVF/emImTCM) exhibits the higher conductivity than that of PAMPSLi/PVF/N
1134TCM (2.48
×
10
−3
S
cm
−1). Because of using the polymerizable anion it is seen to maintain high flexibility of imidazolium cation effectively to exhibit the higher conductivity. And also the viscosity of emImTCM (19.56
cP) is lower than that of N
1134TCM (28.61
cP). Low viscosity leads to a fast rate of diffusion of redox species.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2007.10.033</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Anions ; Applied sciences ; Cationic polymerization ; Copolymer ; Copolymers ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Exact sciences and technology ; Imidazolium cation ; Ionic conductivity ; Ionic liquid ; Ionic liquids ; Lithium ; Polyvinyl fluorides ; Quaternary ammonium cation ; Tricyanomethanide ; Viscosity</subject><ispartof>Journal of power sources, 2008-04, Vol.178 (2), p.779-782</ispartof><rights>2007 Elsevier B.V.</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c374t-391657fc4f3d0235eeb5e586d7344c20e90a53a91e9074d6d0287cc5e6672c183</citedby><cites>FETCH-LOGICAL-c374t-391657fc4f3d0235eeb5e586d7344c20e90a53a91e9074d6d0287cc5e6672c183</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jpowsour.2007.10.033$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,3550,23930,23931,25140,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20344564$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Cha, E.H.</creatorcontrib><creatorcontrib>Lim, S.A.</creatorcontrib><creatorcontrib>Park, J.H.</creatorcontrib><creatorcontrib>Kim, D.W.</creatorcontrib><creatorcontrib>Macfarlane, D.R.</creatorcontrib><title>Ionic conductivity studies of gel polyelectrolyte based on ionic liquid</title><title>Journal of power sources</title><description>Novel lithium polyelectrolyte-ionic liquids have been prepared and characterized of their properties. Poly(lithium 2-acrylamido-2-methyl propanesulfonate) (PAMPSLi) and its copolymer with
N-vinyl formamide (VF) also has been prepared as a copolymer. 1-Ethyl-3-methylimidazolium tricyanomethanide (emImTCM) and
N,
N-dimethyl-
N-propyl-
N-butyl ammonium tricyanomethanide (N
1134TCM) which are chosen because of the same with the anion of ionic liquid were prepared. The ionic conductivity of copolymer system (PAMPSLi/PVF/emImTCM: 5.43
×
10
−3
S
cm
−1 at 25
°C) exhibits about over four times higher than that of homopolymer system (PAMPSLi/emImTCM: 1.28
×
10
−3
S
cm
−1 at 25
°C). Introduction of vinyl formamide into the copolymer type can increase the dissociation of the lithium cations from the polymer backbone. The ionic conductivity of copolymer with emImTCM (PAMPSLi/PVF/emImTCM) exhibits the higher conductivity than that of PAMPSLi/PVF/N
1134TCM (2.48
×
10
−3
S
cm
−1). Because of using the polymerizable anion it is seen to maintain high flexibility of imidazolium cation effectively to exhibit the higher conductivity. And also the viscosity of emImTCM (19.56
cP) is lower than that of N
1134TCM (28.61
cP). Low viscosity leads to a fast rate of diffusion of redox species.</description><subject>Anions</subject><subject>Applied sciences</subject><subject>Cationic polymerization</subject><subject>Copolymer</subject><subject>Copolymers</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Exact sciences and technology</subject><subject>Imidazolium cation</subject><subject>Ionic conductivity</subject><subject>Ionic liquid</subject><subject>Ionic liquids</subject><subject>Lithium</subject><subject>Polyvinyl fluorides</subject><subject>Quaternary ammonium cation</subject><subject>Tricyanomethanide</subject><subject>Viscosity</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkEFPwyAUx4nRxDn9CqYX46kVSoH2pll0LlniRc-EwauhYWWDdmbfXuamV0_v5eX3fw9-CN0SXBBM-ENXdBv_Ff0YihJjkYYFpvQMTUgtaF4Kxs7RBFNR50IweomuYuwwxoQIPEHzhe-tzrTvzagHu7PDPovDaCzEzLfZJ7hs490eHOghpGaAbKUimMz3mf2JOrsdrblGF61yEW5OdYo-Xp7fZ6_58m2-mD0tc01FNeS0IZyJVlctNbikDGDFgNXcCFpVusTQYMWoakhqRGV4gmqhNQPORalJTafo_rh3E_x2hDjItY0anFM9-DHKuuFEsJI1ieRHUgcfY4BWboJdq7CXBMuDONnJX3HyIO4wT-JS8O50QkWtXBtUr238S5c4PZXxKnGPRw7Sf3cWgozaQq_B2JBsSePtf6e-AUYCh84</recordid><startdate>20080401</startdate><enddate>20080401</enddate><creator>Cha, E.H.</creator><creator>Lim, S.A.</creator><creator>Park, J.H.</creator><creator>Kim, D.W.</creator><creator>Macfarlane, D.R.</creator><general>Elsevier B.V</general><general>Elsevier Sequoia</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20080401</creationdate><title>Ionic conductivity studies of gel polyelectrolyte based on ionic liquid</title><author>Cha, E.H. ; Lim, S.A. ; Park, J.H. ; Kim, D.W. ; Macfarlane, D.R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c374t-391657fc4f3d0235eeb5e586d7344c20e90a53a91e9074d6d0287cc5e6672c183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Anions</topic><topic>Applied sciences</topic><topic>Cationic polymerization</topic><topic>Copolymer</topic><topic>Copolymers</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Exact sciences and technology</topic><topic>Imidazolium cation</topic><topic>Ionic conductivity</topic><topic>Ionic liquid</topic><topic>Ionic liquids</topic><topic>Lithium</topic><topic>Polyvinyl fluorides</topic><topic>Quaternary ammonium cation</topic><topic>Tricyanomethanide</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cha, E.H.</creatorcontrib><creatorcontrib>Lim, S.A.</creatorcontrib><creatorcontrib>Park, J.H.</creatorcontrib><creatorcontrib>Kim, D.W.</creatorcontrib><creatorcontrib>Macfarlane, D.R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cha, E.H.</au><au>Lim, S.A.</au><au>Park, J.H.</au><au>Kim, D.W.</au><au>Macfarlane, D.R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic conductivity studies of gel polyelectrolyte based on ionic liquid</atitle><jtitle>Journal of power sources</jtitle><date>2008-04-01</date><risdate>2008</risdate><volume>178</volume><issue>2</issue><spage>779</spage><epage>782</epage><pages>779-782</pages><issn>0378-7753</issn><eissn>1873-2755</eissn><coden>JPSODZ</coden><abstract>Novel lithium polyelectrolyte-ionic liquids have been prepared and characterized of their properties. Poly(lithium 2-acrylamido-2-methyl propanesulfonate) (PAMPSLi) and its copolymer with
N-vinyl formamide (VF) also has been prepared as a copolymer. 1-Ethyl-3-methylimidazolium tricyanomethanide (emImTCM) and
N,
N-dimethyl-
N-propyl-
N-butyl ammonium tricyanomethanide (N
1134TCM) which are chosen because of the same with the anion of ionic liquid were prepared. The ionic conductivity of copolymer system (PAMPSLi/PVF/emImTCM: 5.43
×
10
−3
S
cm
−1 at 25
°C) exhibits about over four times higher than that of homopolymer system (PAMPSLi/emImTCM: 1.28
×
10
−3
S
cm
−1 at 25
°C). Introduction of vinyl formamide into the copolymer type can increase the dissociation of the lithium cations from the polymer backbone. The ionic conductivity of copolymer with emImTCM (PAMPSLi/PVF/emImTCM) exhibits the higher conductivity than that of PAMPSLi/PVF/N
1134TCM (2.48
×
10
−3
S
cm
−1). Because of using the polymerizable anion it is seen to maintain high flexibility of imidazolium cation effectively to exhibit the higher conductivity. And also the viscosity of emImTCM (19.56
cP) is lower than that of N
1134TCM (28.61
cP). Low viscosity leads to a fast rate of diffusion of redox species.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2007.10.033</doi><tpages>4</tpages></addata></record> |
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| subjects | Anions Applied sciences Cationic polymerization Copolymer Copolymers Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology Imidazolium cation Ionic conductivity Ionic liquid Ionic liquids Lithium Polyvinyl fluorides Quaternary ammonium cation Tricyanomethanide Viscosity |
| title | Ionic conductivity studies of gel polyelectrolyte based on ionic liquid |
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