Enthalpic interaction coefficients of N, N-dimethylformamide in aqueous ethylene glycol and glycerol solutions at 298.15 K
The dilution enthalpies of N, N-dimethylformamide (DMF) in aqueous ethylene glycol and glycerol solutions have been determined using a CSC-4400 isothermal calorimeter at 298.15 K. The experimental data have been analyzed in terms of McMillan–Mayer formalism to obtain the enthalpic virial coefficient...
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| Veröffentlicht in: | Thermochimica acta 2011-06, Vol.520 (1), p.61-66 |
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| container_issue | 1 |
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| container_title | Thermochimica acta |
| container_volume | 520 |
| creator | Wang, Xu Shao, Shuang Guo, Yuhua Lin, Ruisen |
| description | The dilution enthalpies of
N,
N-dimethylformamide (DMF) in aqueous ethylene glycol and glycerol solutions have been determined using a CSC-4400 isothermal calorimeter at 298.15
K. The experimental data have been analyzed in terms of McMillan–Mayer formalism to obtain the enthalpic virial coefficients for heterotactic interaction. The results have been interpreted from the point of view of solute–solute interactions and solute–solvent interactions. |
| doi_str_mv | 10.1016/j.tca.2011.03.016 |
| format | Article |
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N,
N-dimethylformamide (DMF) in aqueous ethylene glycol and glycerol solutions have been determined using a CSC-4400 isothermal calorimeter at 298.15
K. The experimental data have been analyzed in terms of McMillan–Mayer formalism to obtain the enthalpic virial coefficients for heterotactic interaction. The results have been interpreted from the point of view of solute–solute interactions and solute–solvent interactions.</description><identifier>ISSN: 0040-6031</identifier><identifier>EISSN: 1872-762X</identifier><identifier>DOI: 10.1016/j.tca.2011.03.016</identifier><identifier>CODEN: THACAS</identifier><language>eng</language><publisher>Oxford: Elsevier B.V</publisher><subject>Chemical thermodynamics ; Chemistry ; Dilution enthalpy ; Enthalpic pair interaction coefficients ; Enthalpy ; Ethylene Glycol ; Exact sciences and technology ; Formalism ; General and physical chemistry ; Glycerol ; Glycerols ; Mixtures ; N, N-Dimethylformamide ; Thermodynamic properties ; Virial coefficients</subject><ispartof>Thermochimica acta, 2011-06, Vol.520 (1), p.61-66</ispartof><rights>2011</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.tca.2011.03.016$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3549,27923,27924,45994</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24285833$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Xu</creatorcontrib><creatorcontrib>Shao, Shuang</creatorcontrib><creatorcontrib>Guo, Yuhua</creatorcontrib><creatorcontrib>Lin, Ruisen</creatorcontrib><title>Enthalpic interaction coefficients of N, N-dimethylformamide in aqueous ethylene glycol and glycerol solutions at 298.15 K</title><title>Thermochimica acta</title><description>The dilution enthalpies of
N,
N-dimethylformamide (DMF) in aqueous ethylene glycol and glycerol solutions have been determined using a CSC-4400 isothermal calorimeter at 298.15
K. The experimental data have been analyzed in terms of McMillan–Mayer formalism to obtain the enthalpic virial coefficients for heterotactic interaction. The results have been interpreted from the point of view of solute–solute interactions and solute–solvent interactions.</description><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Dilution enthalpy</subject><subject>Enthalpic pair interaction coefficients</subject><subject>Enthalpy</subject><subject>Ethylene Glycol</subject><subject>Exact sciences and technology</subject><subject>Formalism</subject><subject>General and physical chemistry</subject><subject>Glycerol</subject><subject>Glycerols</subject><subject>Mixtures</subject><subject>N, N-Dimethylformamide</subject><subject>Thermodynamic properties</subject><subject>Virial coefficients</subject><issn>0040-6031</issn><issn>1872-762X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNotkU1v1DAQhi0EUpfCD-jNF8SFBH9sHEecUNVC1apcQOJmzdpj6pUTL7YXafn1ddqe5uuZ0at5CbngrOeMq8_7vlroBeO8Z7JvnVdkw_UoulGJ36_JhrEt6xST_Iy8LWXPGONCsw35f7XUB4iHYGlYKmawNaSF2oTeBxtwqYUmT-8_0fvOhRnrwyn6lGeYg8O2QuHvEdOx0KcJLkj_xJNNkcLinlLMrSgpHte7hUKlYtI9H-jtO_LGQyz4_iWek1_XVz8vv3d3P77dXH6961CoqXbo1IhOT3KCEaQG7ZQYPBMSB_BDQ4RrhefTbjtIcIIPYuRe7wZlPe44k-fk4_PdQ05NbKlmDsVijLCsyo2eFFej1rqRH15IKBaiz7DYUMwhhxnyyYit0IOWsnFfnjlssv8FzKasr7LoQkZbjUvBcGZWY8zeNGPMaoxh0rSOfASOq4MH</recordid><startdate>20110610</startdate><enddate>20110610</enddate><creator>Wang, Xu</creator><creator>Shao, Shuang</creator><creator>Guo, Yuhua</creator><creator>Lin, Ruisen</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110610</creationdate><title>Enthalpic interaction coefficients of N, N-dimethylformamide in aqueous ethylene glycol and glycerol solutions at 298.15 K</title><author>Wang, Xu ; Shao, Shuang ; Guo, Yuhua ; Lin, Ruisen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e269t-ed67ed8939a7a38a8d625f023e5af52692d023f19b453ad215271f8b56cfeb103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Dilution enthalpy</topic><topic>Enthalpic pair interaction coefficients</topic><topic>Enthalpy</topic><topic>Ethylene Glycol</topic><topic>Exact sciences and technology</topic><topic>Formalism</topic><topic>General and physical chemistry</topic><topic>Glycerol</topic><topic>Glycerols</topic><topic>Mixtures</topic><topic>N, N-Dimethylformamide</topic><topic>Thermodynamic properties</topic><topic>Virial coefficients</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xu</creatorcontrib><creatorcontrib>Shao, Shuang</creatorcontrib><creatorcontrib>Guo, Yuhua</creatorcontrib><creatorcontrib>Lin, Ruisen</creatorcontrib><collection>Pascal-Francis</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Thermochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xu</au><au>Shao, Shuang</au><au>Guo, Yuhua</au><au>Lin, Ruisen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enthalpic interaction coefficients of N, N-dimethylformamide in aqueous ethylene glycol and glycerol solutions at 298.15 K</atitle><jtitle>Thermochimica acta</jtitle><date>2011-06-10</date><risdate>2011</risdate><volume>520</volume><issue>1</issue><spage>61</spage><epage>66</epage><pages>61-66</pages><issn>0040-6031</issn><eissn>1872-762X</eissn><coden>THACAS</coden><abstract>The dilution enthalpies of
N,
N-dimethylformamide (DMF) in aqueous ethylene glycol and glycerol solutions have been determined using a CSC-4400 isothermal calorimeter at 298.15
K. The experimental data have been analyzed in terms of McMillan–Mayer formalism to obtain the enthalpic virial coefficients for heterotactic interaction. The results have been interpreted from the point of view of solute–solute interactions and solute–solvent interactions.</abstract><cop>Oxford</cop><pub>Elsevier B.V</pub><doi>10.1016/j.tca.2011.03.016</doi><tpages>6</tpages></addata></record> |
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| ispartof | Thermochimica acta, 2011-06, Vol.520 (1), p.61-66 |
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| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Chemical thermodynamics Chemistry Dilution enthalpy Enthalpic pair interaction coefficients Enthalpy Ethylene Glycol Exact sciences and technology Formalism General and physical chemistry Glycerol Glycerols Mixtures N, N-Dimethylformamide Thermodynamic properties Virial coefficients |
| title | Enthalpic interaction coefficients of N, N-dimethylformamide in aqueous ethylene glycol and glycerol solutions at 298.15 K |
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