Substituent Effects on the Reversibility of Furan–Maleimide Cycloadditions

The effects of furan and maleimide substitution on the dynamic reversibility of their Diels–Alder reactivity have been investigated computationally and by 1H NMR spectroscopy. Furan and furan derivatives bearing methoxy, methyl, or formyl groups at their 2- or 3-positions were investigated with male...

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Veröffentlicht in:	Journal of organic chemistry 2011-10, Vol.76 (19), p.7994-8002
Hauptverfasser:	Boutelle, Robert C, Northrop, Brian H
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical reactivity Chemistry Electrons Exact sciences and technology Furans - chemistry Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Heterocyclic compounds with only one n hetero atom and condensed derivatives Magnetic Resonance Spectroscopy Maleimides - chemistry Organic chemistry Preparations and properties Reactivity and mechanisms Stereoisomerism Thermodynamics
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