Photosensitizing catalysis of the B12 complex without an additional photosensitizer

A cobalamin derivative, heptamethyl cobyrinate perchlorate, was activated by UV light irradiation to form a Co(I) species in the presence of triethanolamine and used for a dechlorination reaction, and this photochemical reaction was accelerated in an ionic liquid.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (39), p.10921-10923
Hauptverfasser: Shimakoshi, Hisashi, Li, Li, Nishi, Masashi, Hisaeda, Yoshio
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container_end_page 10923
container_issue 39
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container_title Chemical communications (Cambridge, England)
container_volume 47
creator Shimakoshi, Hisashi
Li, Li
Nishi, Masashi
Hisaeda, Yoshio
description A cobalamin derivative, heptamethyl cobyrinate perchlorate, was activated by UV light irradiation to form a Co(I) species in the presence of triethanolamine and used for a dechlorination reaction, and this photochemical reaction was accelerated in an ionic liquid.
doi_str_mv 10.1039/c1cc12482j
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source MEDLINE; Royal Society of Chemistry Journals Gold Package; Alma/SFX Local Collection
subjects Activated
Catalysis
Dechlorination
Derivatives
Ionic liquids
Ionic Liquids - chemistry
Light irradiation
Photochemical Processes
Photochemical reactions
Photosensitizing Agents - chemistry
Triethanolamine
Ultraviolet Rays
Vitamin B 12 - analogs & derivatives
Vitamin B 12 - chemistry
title Photosensitizing catalysis of the B12 complex without an additional photosensitizer
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