The role of the atomic charges on the ligands and platinum(II) in affecting the cis and trans influences in [PtXL(PPh3)2]+ complexes (X = NO3, Cl, Br, I; L = 4-substituted pyridines, amines, PPh3). A 31P NMR and DFT investigation

One bond Pt-P coupling constants (1)J(PtP) of a series of cationic complexes [PtXL(PPh(3))(2)](+) (X = NO(3), Cl, Br, I; L = 4-Z-pyridines, Z = electron withdrawing or releasing groups, 4a-k; or X = Cl, L = NH(3), PhCH(2)NH(2) and (i)PrNH(2), 5a-c) have been used to establish the trans and cis influ...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2011-01, Vol.40 (39), p.10162-10173
Hauptverfasser:	Rigamonti, Luca, Rusconi, Michele, Forni, Alessandra, Pasini, Alessandro
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Cationic Charge Chemical bonds Ligands Nitrogen atoms Platinum Pyridines
Online-Zugang:	Volltext
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