Transition metal-catalysed cross-coupling reactions of P-activated enols

Transition metal-catalysed cross-coupling reactions of P-activated enols

Transition metal catalysed cross-coupling reactions are ubiquitous in organic chemistry providing an impressive technique for C-C bond formation. Whilst many electrophilic partners have been described for these reactions, aryl and vinyl phosphates, phosphonates and phosphonites can offer advantages...

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Veröffentlicht in:Chemical Society reviews 2011-01, Vol.40 (10), p.5170-5180
Hauptverfasser: Sellars, Jonathan D, Steel, Patrick G
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
Carbon-carbon composites
Organic chemistry
Phosphates
Phosphonates
Stability
Transition metals
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Steel, Patrick G
description Transition metal catalysed cross-coupling reactions are ubiquitous in organic chemistry providing an impressive technique for C-C bond formation. Whilst many electrophilic partners have been described for these reactions, aryl and vinyl phosphates, phosphonates and phosphonites can offer advantages in terms of preparation, stability and reactivity profile. This critical review summarises the advances made to date utilising P-activated enols in metal-catalysed cross-coupling reactions (97 references).
doi_str_mv 10.1039/c1cs15100b
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Aromatic compounds
Carbon-carbon composites
Organic chemistry
Phosphates
Phosphonates
Stability
Transition metals
title Transition metal-catalysed cross-coupling reactions of P-activated enols
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