Bidirectional “Ping-Pong” Energy Transfer and 3000-Fold Lifetime Enhancement in a Re(I) Charge Transfer Complex

The synthesis and photophysics of a new Re(I)-carbonyl diimine complex, Re(PNI-phen)(CO)3Cl, where the PNI-phen is N-(1,10-phenanthroline)-4-(1-piperidinyl)naphthalene-1,8-dicarboximide is reported. The metal-to-ligand charge transfer (MLCT) emission lifetime was increased approximately 3000-fold at...

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Veröffentlicht in:	Inorganic chemistry 2011-08, Vol.50 (16), p.7820-7830
Hauptverfasser:	Yarnell, James E, Deaton, Joseph C, McCusker, Catherine E, Castellano, Felix N
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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