Water Oxidation by a Mononuclear Ruthenium Catalyst: Characterization of the Intermediates

A detailed characterization of intermediates in water oxidation catalyzed by a mononuclear Ru polypyridyl complex [Ru II–OH2]2+ (Ru = Ru complex with one 4-t-butyl-2,6-di-(1′,8′-naphthyrid-2′-yl)-pyridine ligand and two 4-picoline ligands) has been carried out using electrochemistry, UV–vis and reso...

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Veröffentlicht in:Journal of the American Chemical Society 2011-09, Vol.133 (37), p.14649-14665
Hauptverfasser: Polyansky, Dmitry E, Muckerman, James T, Rochford, Jonathan, Zong, Ruifa, Thummel, Randolph P, Fujita, Etsuko
Format: Artikel
Sprache:eng
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