Communication: probable scenario of the liquid-liquid phase transition of SnI4

Communication: probable scenario of the liquid-liquid phase transition of SnI4

We have shown from in situ synchrotron x-ray diffraction measurements that there are two thermodynamically stable liquid forms of SnI(4), depending on the pressure. Based on the liquid-liquid critical point scenario, our recent measurements suggest that the second critical point, if it exists, may b...

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Veröffentlicht in:The Journal of chemical physics 2011-09, Vol.135 (9), p.091101-091101
Hauptverfasser: Fuchizaki, Kazuhiro, Hamaya, Nozomu, Hase, Takaki, Katayama, Yoshinori
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container_end_page 091101
container_issue 9
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container_title The Journal of chemical physics
container_volume 135
creator Fuchizaki, Kazuhiro
Hamaya, Nozomu
Hase, Takaki
Katayama, Yoshinori
description We have shown from in situ synchrotron x-ray diffraction measurements that there are two thermodynamically stable liquid forms of SnI(4), depending on the pressure. Based on the liquid-liquid critical point scenario, our recent measurements suggest that the second critical point, if it exists, may be located in a region close to the point at which the melting curve of the crystalline phase abruptly breaks. This region is, unlike that of water, experimentally accessible with relative ease.
doi_str_mv 10.1063/1.3637038
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title Communication: probable scenario of the liquid-liquid phase transition of SnI4
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