Nanocrystalline 3C-SiC Electrode for Biosensing Applications
Silicon carbide has been proved as a candidate for power and high-frequency devices. In this paper, we show the application of nanocrystalline 3C-SiC as an electrochemical electrode and its electrochemical functionalization for biosensing applications. SiC electrodes show a wider potential window an...
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Veröffentlicht in: | Analytical chemistry (Washington) 2011-08, Vol.83 (15), p.5827-5830 |
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creator | Yang, Nianjun Zhuang, Hao Hoffmann, René Smirnov, Waldemar Hees, Jakob Jiang, Xin Nebel, Christoph E |
description | Silicon carbide has been proved as a candidate for power and high-frequency devices. In this paper, we show the application of nanocrystalline 3C-SiC as an electrochemical electrode and its electrochemical functionalization for biosensing applications. SiC electrodes show a wider potential window and lower background current than glassy carbon electrodes. The surface can be electrochemically functionalized with diazonium salts, as confirmed by electrochemical techniques and X-ray photoelectron spectroscopy. The nitrophenyl film is used as linker layer to bond DNA molecule to SiC. These results show that 3C-SiC can be an interesting transducer material for applications in electro- and bioelectrochemical applications. |
doi_str_mv | 10.1021/ac201315q |
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In this paper, we show the application of nanocrystalline 3C-SiC as an electrochemical electrode and its electrochemical functionalization for biosensing applications. SiC electrodes show a wider potential window and lower background current than glassy carbon electrodes. The surface can be electrochemically functionalized with diazonium salts, as confirmed by electrochemical techniques and X-ray photoelectron spectroscopy. The nitrophenyl film is used as linker layer to bond DNA molecule to SiC. These results show that 3C-SiC can be an interesting transducer material for applications in electro- and bioelectrochemical applications.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac201315q</identifier><identifier>PMID: 21702486</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Analytical chemistry ; Biological and medical sciences ; Biosensing Techniques - methods ; Biosensors ; Biotechnology ; Carbon Compounds, Inorganic - chemistry ; Chemistry ; Diazonium Compounds - chemistry ; DNA - chemistry ; Electrochemical methods ; Electrochemical Techniques - methods ; Electrodes ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; General, instrumentation ; Methods. Procedures. 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Chem</addtitle><description>Silicon carbide has been proved as a candidate for power and high-frequency devices. In this paper, we show the application of nanocrystalline 3C-SiC as an electrochemical electrode and its electrochemical functionalization for biosensing applications. SiC electrodes show a wider potential window and lower background current than glassy carbon electrodes. The surface can be electrochemically functionalized with diazonium salts, as confirmed by electrochemical techniques and X-ray photoelectron spectroscopy. The nitrophenyl film is used as linker layer to bond DNA molecule to SiC. 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Technologies</subject><subject>Nanocrystals</subject><subject>Nanoparticles - chemistry</subject><subject>Photoelectron Spectroscopy</subject><subject>Silicon carbide</subject><subject>Silicon Compounds - chemistry</subject><subject>Spectrometric and optical methods</subject><subject>Surface Properties</subject><subject>Various methods and equipments</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqF0ctqGzEUBmARUmLH7aIvEIZAabqY9hzdRoJsUuNcIKSLtutBo9EEmfHIkcaLvH0V7MTQQLISgo__HOkn5DPCdwSKP4ylgAzFwwGZoqBQSqXoIZkCACtpBTAhxyktARAB5RGZUKyAciWn5PzODMHGxzSavveDK9i8_O3nxaJ3doyhdUUXYvHTh-SG5If74mK97r01ow9D-kg-dKZP7tPunJG_l4s_8-vy9tfVzfzitjQC2FhWXDJpGFfKcCuM0C2nvOOyaTsnHVe6k0ZLECi0FNjmO0PaaS0b3gDIhs3I123uOoaHjUtjvfLJur43gwubVCuluWAANMuzNyVSisioBv4-Bc04z7-nMj39jy7DJg75yXk0R67y5hl92yIbQ0rRdfU6-pWJjzmpfqqpfqkp25Nd4KZZufZFPveSwZcdMMmavotmsD7tHWdaVKraO2PTfqnXA_8BEhShew</recordid><startdate>20110801</startdate><enddate>20110801</enddate><creator>Yang, Nianjun</creator><creator>Zhuang, Hao</creator><creator>Hoffmann, René</creator><creator>Smirnov, Waldemar</creator><creator>Hees, Jakob</creator><creator>Jiang, Xin</creator><creator>Nebel, Christoph E</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7U5</scope><scope>7U7</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20110801</creationdate><title>Nanocrystalline 3C-SiC Electrode for Biosensing Applications</title><author>Yang, Nianjun ; Zhuang, Hao ; Hoffmann, René ; Smirnov, Waldemar ; Hees, Jakob ; Jiang, Xin ; Nebel, Christoph E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a503t-74636a3488a4c5a59d424f46bdfe6e489f6a9605159651d89f312f996b4b006b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Analytical chemistry</topic><topic>Biological and medical sciences</topic><topic>Biosensing Techniques - methods</topic><topic>Biosensors</topic><topic>Biotechnology</topic><topic>Carbon Compounds, Inorganic - chemistry</topic><topic>Chemistry</topic><topic>Diazonium Compounds - chemistry</topic><topic>DNA - chemistry</topic><topic>Electrochemical methods</topic><topic>Electrochemical Techniques - methods</topic><topic>Electrodes</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. 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Chem</addtitle><date>2011-08-01</date><risdate>2011</risdate><volume>83</volume><issue>15</issue><spage>5827</spage><epage>5830</epage><pages>5827-5830</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>Silicon carbide has been proved as a candidate for power and high-frequency devices. In this paper, we show the application of nanocrystalline 3C-SiC as an electrochemical electrode and its electrochemical functionalization for biosensing applications. SiC electrodes show a wider potential window and lower background current than glassy carbon electrodes. The surface can be electrochemically functionalized with diazonium salts, as confirmed by electrochemical techniques and X-ray photoelectron spectroscopy. The nitrophenyl film is used as linker layer to bond DNA molecule to SiC. These results show that 3C-SiC can be an interesting transducer material for applications in electro- and bioelectrochemical applications.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>21702486</pmid><doi>10.1021/ac201315q</doi><tpages>4</tpages></addata></record> |
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subjects | Analytical chemistry Biological and medical sciences Biosensing Techniques - methods Biosensors Biotechnology Carbon Compounds, Inorganic - chemistry Chemistry Diazonium Compounds - chemistry DNA - chemistry Electrochemical methods Electrochemical Techniques - methods Electrodes Exact sciences and technology Fundamental and applied biological sciences. Psychology General, instrumentation Methods. Procedures. Technologies Nanocrystals Nanoparticles - chemistry Photoelectron Spectroscopy Silicon carbide Silicon Compounds - chemistry Spectrometric and optical methods Surface Properties Various methods and equipments |
title | Nanocrystalline 3C-SiC Electrode for Biosensing Applications |
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