Fabrication of superhydrophobic polymer films with hierarchical silver microbowl array structures
Superhydrophobic films with hierarchical silver bowl array structures were prepared by thermally evaporating silver on monolayer templates of self-assembled PS spheres. [Display omitted] ► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The p...
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Veröffentlicht in: | Journal of colloid and interface science 2011-08, Vol.360 (1), p.300-304 |
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creator | Xu, Miaojun Lu, Nan Qi, Dianpeng Xu, Hongbo Wang, Yandong Shi, Shoulei Chi, Lifeng |
description | Superhydrophobic films with hierarchical silver bowl array structures were prepared by thermally evaporating silver on monolayer templates of self-assembled PS spheres. [Display omitted]
► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The prepared superhydrophobic films show excellent stability after bending strongly the surfaces. ► The synthesized films exhibit uniform wettability over the whole surface. ► The superhydrophobic films could find applications as self-cleaning curved surfaces.
Flexible superhydrophobic polyvinyl alcohol (PVA) films with silver bowl-like array structure are fabricated based on the thermal evaporation with sphere monolayer as templates and the modification of 1H, 1H, 2H, 2H-perfluorodecanethiol on silver surface. The silver microbowl arrays were composed of silver nanoparticles with an average diameter size of ca. 10nm. The polymer films exhibit excellent stability and remarkable superhydrophobicity with a high water contact angle (CA) of about 163° and a low sliding angle (SA) of less than 3°. |
doi_str_mv | 10.1016/j.jcis.2011.04.048 |
format | Article |
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► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The prepared superhydrophobic films show excellent stability after bending strongly the surfaces. ► The synthesized films exhibit uniform wettability over the whole surface. ► The superhydrophobic films could find applications as self-cleaning curved surfaces.
Flexible superhydrophobic polyvinyl alcohol (PVA) films with silver bowl-like array structure are fabricated based on the thermal evaporation with sphere monolayer as templates and the modification of 1H, 1H, 2H, 2H-perfluorodecanethiol on silver surface. The silver microbowl arrays were composed of silver nanoparticles with an average diameter size of ca. 10nm. The polymer films exhibit excellent stability and remarkable superhydrophobicity with a high water contact angle (CA) of about 163° and a low sliding angle (SA) of less than 3°.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2011.04.048</identifier><identifier>PMID: 21549389</identifier><identifier>CODEN: JCISA5</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>Arrays ; Chemistry ; Colloidal state and disperse state ; contact angle ; Evaporation ; Exact sciences and technology ; Flexible superhydrophobic film ; General and physical chemistry ; Hierarchical structure ; hydrophobicity ; Microorganisms ; Monolayers ; nanosilver ; Physical and chemical studies. Granulometry. Electrokinetic phenomena ; Polymeric films ; polyvinyl alcohol ; Polyvinyl alcohols ; Silver ; Silver microbowl array ; Silver nanoparticles ; Solid-liquid interface ; Stability ; Surface physical chemistry ; Template</subject><ispartof>Journal of colloid and interface science, 2011-08, Vol.360 (1), p.300-304</ispartof><rights>2011 Elsevier Inc.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2011 Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c478t-1ea8ec9154c52bf190c4c86bcceb86fe3820558249a6eb73aca9b3896b49a813</citedby><cites>FETCH-LOGICAL-c478t-1ea8ec9154c52bf190c4c86bcceb86fe3820558249a6eb73aca9b3896b49a813</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0021979711004784$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24335620$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21549389$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Miaojun</creatorcontrib><creatorcontrib>Lu, Nan</creatorcontrib><creatorcontrib>Qi, Dianpeng</creatorcontrib><creatorcontrib>Xu, Hongbo</creatorcontrib><creatorcontrib>Wang, Yandong</creatorcontrib><creatorcontrib>Shi, Shoulei</creatorcontrib><creatorcontrib>Chi, Lifeng</creatorcontrib><title>Fabrication of superhydrophobic polymer films with hierarchical silver microbowl array structures</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>Superhydrophobic films with hierarchical silver bowl array structures were prepared by thermally evaporating silver on monolayer templates of self-assembled PS spheres. [Display omitted]
► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The prepared superhydrophobic films show excellent stability after bending strongly the surfaces. ► The synthesized films exhibit uniform wettability over the whole surface. ► The superhydrophobic films could find applications as self-cleaning curved surfaces.
Flexible superhydrophobic polyvinyl alcohol (PVA) films with silver bowl-like array structure are fabricated based on the thermal evaporation with sphere monolayer as templates and the modification of 1H, 1H, 2H, 2H-perfluorodecanethiol on silver surface. The silver microbowl arrays were composed of silver nanoparticles with an average diameter size of ca. 10nm. The polymer films exhibit excellent stability and remarkable superhydrophobicity with a high water contact angle (CA) of about 163° and a low sliding angle (SA) of less than 3°.</description><subject>Arrays</subject><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>contact angle</subject><subject>Evaporation</subject><subject>Exact sciences and technology</subject><subject>Flexible superhydrophobic film</subject><subject>General and physical chemistry</subject><subject>Hierarchical structure</subject><subject>hydrophobicity</subject><subject>Microorganisms</subject><subject>Monolayers</subject><subject>nanosilver</subject><subject>Physical and chemical studies. Granulometry. Electrokinetic phenomena</subject><subject>Polymeric films</subject><subject>polyvinyl alcohol</subject><subject>Polyvinyl alcohols</subject><subject>Silver</subject><subject>Silver microbowl array</subject><subject>Silver nanoparticles</subject><subject>Solid-liquid interface</subject><subject>Stability</subject><subject>Surface physical chemistry</subject><subject>Template</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkU9v1DAQxS0EotvCF-AAviBOWcZO4j8SF1TRglSJA-Vs2d4J8SpZBztptd8eR7v0CNJIluzfG8-8R8gbBlsGTHzcb_c-5C0HxrbQlFLPyIaBbivJoH5ONgCcVVpqeUEuc95DAdtWvyQXnLWNrpXeEHtjXQreziEeaOxoXiZM_XGX4tRHFzyd4nAcMdEuDGOmj2HuaR8w2eT7IhtoDsNDeR6DT9HFx4HalOyR5jktfl4S5lfkRWeHjK_P5xW5v_lyf_21uvt---36813lG6nmiqFV6HUZzLfcdUyDb7wSznt0SnRYKw5tq3ijrUAna-utdmUF4cqNYvUV-XBqO6X4e8E8mzFkj8NgDxiXbJTSDecC6v-TEtpGSrWS_ESW3XJO2JkphdGmo2Fg1gjM3qwRmDUCA00pVURvz-0XN-LuSfLX8wK8PwM2Fwe7ZA9rjyeuqetWcCjcuxPX2Wjsr1SYnz_KTwIAhBK1LMSnE4HF14eSisk-4MHjLiT0s9nF8K9J_wBrl6_j</recordid><startdate>20110801</startdate><enddate>20110801</enddate><creator>Xu, Miaojun</creator><creator>Lu, Nan</creator><creator>Qi, Dianpeng</creator><creator>Xu, Hongbo</creator><creator>Wang, Yandong</creator><creator>Shi, Shoulei</creator><creator>Chi, Lifeng</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20110801</creationdate><title>Fabrication of superhydrophobic polymer films with hierarchical silver microbowl array structures</title><author>Xu, Miaojun ; Lu, Nan ; Qi, Dianpeng ; Xu, Hongbo ; Wang, Yandong ; Shi, Shoulei ; Chi, Lifeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c478t-1ea8ec9154c52bf190c4c86bcceb86fe3820558249a6eb73aca9b3896b49a813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Arrays</topic><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>contact angle</topic><topic>Evaporation</topic><topic>Exact sciences and technology</topic><topic>Flexible superhydrophobic film</topic><topic>General and physical chemistry</topic><topic>Hierarchical structure</topic><topic>hydrophobicity</topic><topic>Microorganisms</topic><topic>Monolayers</topic><topic>nanosilver</topic><topic>Physical and chemical studies. Granulometry. Electrokinetic phenomena</topic><topic>Polymeric films</topic><topic>polyvinyl alcohol</topic><topic>Polyvinyl alcohols</topic><topic>Silver</topic><topic>Silver microbowl array</topic><topic>Silver nanoparticles</topic><topic>Solid-liquid interface</topic><topic>Stability</topic><topic>Surface physical chemistry</topic><topic>Template</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Miaojun</creatorcontrib><creatorcontrib>Lu, Nan</creatorcontrib><creatorcontrib>Qi, Dianpeng</creatorcontrib><creatorcontrib>Xu, Hongbo</creatorcontrib><creatorcontrib>Wang, Yandong</creatorcontrib><creatorcontrib>Shi, Shoulei</creatorcontrib><creatorcontrib>Chi, Lifeng</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Miaojun</au><au>Lu, Nan</au><au>Qi, Dianpeng</au><au>Xu, Hongbo</au><au>Wang, Yandong</au><au>Shi, Shoulei</au><au>Chi, Lifeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of superhydrophobic polymer films with hierarchical silver microbowl array structures</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2011-08-01</date><risdate>2011</risdate><volume>360</volume><issue>1</issue><spage>300</spage><epage>304</epage><pages>300-304</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><coden>JCISA5</coden><abstract>Superhydrophobic films with hierarchical silver bowl array structures were prepared by thermally evaporating silver on monolayer templates of self-assembled PS spheres. [Display omitted]
► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The prepared superhydrophobic films show excellent stability after bending strongly the surfaces. ► The synthesized films exhibit uniform wettability over the whole surface. ► The superhydrophobic films could find applications as self-cleaning curved surfaces.
Flexible superhydrophobic polyvinyl alcohol (PVA) films with silver bowl-like array structure are fabricated based on the thermal evaporation with sphere monolayer as templates and the modification of 1H, 1H, 2H, 2H-perfluorodecanethiol on silver surface. The silver microbowl arrays were composed of silver nanoparticles with an average diameter size of ca. 10nm. The polymer films exhibit excellent stability and remarkable superhydrophobicity with a high water contact angle (CA) of about 163° and a low sliding angle (SA) of less than 3°.</abstract><cop>Amsterdam</cop><pub>Elsevier Inc</pub><pmid>21549389</pmid><doi>10.1016/j.jcis.2011.04.048</doi><tpages>5</tpages></addata></record> |
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subjects | Arrays Chemistry Colloidal state and disperse state contact angle Evaporation Exact sciences and technology Flexible superhydrophobic film General and physical chemistry Hierarchical structure hydrophobicity Microorganisms Monolayers nanosilver Physical and chemical studies. Granulometry. Electrokinetic phenomena Polymeric films polyvinyl alcohol Polyvinyl alcohols Silver Silver microbowl array Silver nanoparticles Solid-liquid interface Stability Surface physical chemistry Template |
title | Fabrication of superhydrophobic polymer films with hierarchical silver microbowl array structures |
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