Fabrication of superhydrophobic polymer films with hierarchical silver microbowl array structures

Superhydrophobic films with hierarchical silver bowl array structures were prepared by thermally evaporating silver on monolayer templates of self-assembled PS spheres. [Display omitted] ► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The p...

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Veröffentlicht in:Journal of colloid and interface science 2011-08, Vol.360 (1), p.300-304
Hauptverfasser: Xu, Miaojun, Lu, Nan, Qi, Dianpeng, Xu, Hongbo, Wang, Yandong, Shi, Shoulei, Chi, Lifeng
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container_end_page 304
container_issue 1
container_start_page 300
container_title Journal of colloid and interface science
container_volume 360
creator Xu, Miaojun
Lu, Nan
Qi, Dianpeng
Xu, Hongbo
Wang, Yandong
Shi, Shoulei
Chi, Lifeng
description Superhydrophobic films with hierarchical silver bowl array structures were prepared by thermally evaporating silver on monolayer templates of self-assembled PS spheres. [Display omitted] ► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The prepared superhydrophobic films show excellent stability after bending strongly the surfaces. ► The synthesized films exhibit uniform wettability over the whole surface. ► The superhydrophobic films could find applications as self-cleaning curved surfaces. Flexible superhydrophobic polyvinyl alcohol (PVA) films with silver bowl-like array structure are fabricated based on the thermal evaporation with sphere monolayer as templates and the modification of 1H, 1H, 2H, 2H-perfluorodecanethiol on silver surface. The silver microbowl arrays were composed of silver nanoparticles with an average diameter size of ca. 10nm. The polymer films exhibit excellent stability and remarkable superhydrophobicity with a high water contact angle (CA) of about 163° and a low sliding angle (SA) of less than 3°.
doi_str_mv 10.1016/j.jcis.2011.04.048
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[Display omitted] ► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The prepared superhydrophobic films show excellent stability after bending strongly the surfaces. ► The synthesized films exhibit uniform wettability over the whole surface. ► The superhydrophobic films could find applications as self-cleaning curved surfaces. Flexible superhydrophobic polyvinyl alcohol (PVA) films with silver bowl-like array structure are fabricated based on the thermal evaporation with sphere monolayer as templates and the modification of 1H, 1H, 2H, 2H-perfluorodecanethiol on silver surface. The silver microbowl arrays were composed of silver nanoparticles with an average diameter size of ca. 10nm. 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[Display omitted] ► The present fabrication method for flexible superhydrophobic films allows for a large area fabrication. ► The prepared superhydrophobic films show excellent stability after bending strongly the surfaces. ► The synthesized films exhibit uniform wettability over the whole surface. ► The superhydrophobic films could find applications as self-cleaning curved surfaces. Flexible superhydrophobic polyvinyl alcohol (PVA) films with silver bowl-like array structure are fabricated based on the thermal evaporation with sphere monolayer as templates and the modification of 1H, 1H, 2H, 2H-perfluorodecanethiol on silver surface. The silver microbowl arrays were composed of silver nanoparticles with an average diameter size of ca. 10nm. 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source Elsevier ScienceDirect Journals
subjects Arrays
Chemistry
Colloidal state and disperse state
contact angle
Evaporation
Exact sciences and technology
Flexible superhydrophobic film
General and physical chemistry
Hierarchical structure
hydrophobicity
Microorganisms
Monolayers
nanosilver
Physical and chemical studies. Granulometry. Electrokinetic phenomena
Polymeric films
polyvinyl alcohol
Polyvinyl alcohols
Silver
Silver microbowl array
Silver nanoparticles
Solid-liquid interface
Stability
Surface physical chemistry
Template
title Fabrication of superhydrophobic polymer films with hierarchical silver microbowl array structures
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