Multifunctional polymethylsilsesquioxane (PMSQ) surfaces prepared by electrospinning at the sol–gel transition: Superhydrophobicity, excellent solvent resistance, thermal stability and enhanced sound absorption property
Superhydrophobic PMSQ surfaces with excellent solvent resistance and thermal stability were prepared. Modifying sponge with PMSQ not only endows ultra water repellency, but also enhances acoustic performance by 12%. [Display omitted] ► Superhydrophobic PMSQ surfaces were prepared by electrospinning...
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| Veröffentlicht in: | Journal of colloid and interface science 2011-07, Vol.359 (1), p.296-303 |
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| creator | Xiang, Haifan Zhang, Liang Wang, Zhen Yu, Xiaolan Long, Yuhua Zhang, Xiaoli Zhao, Ning Xu, Jian |
| description | Superhydrophobic PMSQ surfaces with excellent solvent resistance and thermal stability were prepared. Modifying sponge with PMSQ not only endows ultra water repellency, but also enhances acoustic performance by 12%. [Display omitted]
► Superhydrophobic PMSQ surfaces were prepared by electrospinning at sol–gel transition. ► Superhydrophobic PMSQ surfaces show excellent resistance to solvents. ► Superhydrophobic PMSQ surfaces show thermal stability as high as 300°C. ► Superior acoustical performance was obtained when the sponge decorated with PMSQ.
Multifunctional superhydrophobic polymethylsilsesquioxane (PMSQ) surfaces with excellent solvent resistance, thermal stability and enhanced sound absorption property were manufactured by electrospinning. The surfaces with various hierarchical morphologies and hydrophobicity were obtained by electrospinning at the different stages of sol–gel transition of PMSQ prepolymer solution. At the stage with a proper viscosity the superhydrophobic PMSQ surface with a contact angle as high as 151° and a sliding angle as low as 8° was prepared. Due to the excellent thermal stability and solvent resistance properties of the cured PMSQ, the resultant surfaces remain superhydrophobicity after thermal treatment at 300°C and immersion into many solvents. Additionally, an enhanced acoustical performance and ultra water repellency were obtained simultaneously when the traditional acoustical sponge was decorated with the electrospun PMSQ superhydrophobic surface. The robust superhydrophobic PMSQ surfaces may promise practical applications in many fields. |
| doi_str_mv | 10.1016/j.jcis.2011.03.076 |
| format | Article |
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► Superhydrophobic PMSQ surfaces were prepared by electrospinning at sol–gel transition. ► Superhydrophobic PMSQ surfaces show excellent resistance to solvents. ► Superhydrophobic PMSQ surfaces show thermal stability as high as 300°C. ► Superior acoustical performance was obtained when the sponge decorated with PMSQ.
Multifunctional superhydrophobic polymethylsilsesquioxane (PMSQ) surfaces with excellent solvent resistance, thermal stability and enhanced sound absorption property were manufactured by electrospinning. The surfaces with various hierarchical morphologies and hydrophobicity were obtained by electrospinning at the different stages of sol–gel transition of PMSQ prepolymer solution. At the stage with a proper viscosity the superhydrophobic PMSQ surface with a contact angle as high as 151° and a sliding angle as low as 8° was prepared. Due to the excellent thermal stability and solvent resistance properties of the cured PMSQ, the resultant surfaces remain superhydrophobicity after thermal treatment at 300°C and immersion into many solvents. Additionally, an enhanced acoustical performance and ultra water repellency were obtained simultaneously when the traditional acoustical sponge was decorated with the electrospun PMSQ superhydrophobic surface. The robust superhydrophobic PMSQ surfaces may promise practical applications in many fields.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2011.03.076</identifier><identifier>PMID: 21492863</identifier><identifier>CODEN: JCISA5</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>absorption ; Acoustics ; Chemistry ; Colloidal gels. Colloidal sols ; Colloidal state and disperse state ; Contact angle ; Corrosion resistance ; Electrospinning ; Exact sciences and technology ; Gels - chemistry ; General and physical chemistry ; heat treatment ; Hydrophobic and Hydrophilic Interactions ; hydrophobicity ; Organosilicon Compounds - chemistry ; Particle Size ; Polymers - chemistry ; Polymethylsilsesquioxane ; Sol gel process ; Solid-liquid interface ; solvents ; Solvents - chemistry ; Sol–gel transition ; Sound ; Sound absorption ; Superhydrophobicity ; Surface chemistry ; Surface physical chemistry ; Surface Properties ; Temperature ; Thermal stability ; viscosity</subject><ispartof>Journal of colloid and interface science, 2011-07, Vol.359 (1), p.296-303</ispartof><rights>2011 Elsevier Inc.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2011 Elsevier Inc. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c441t-b0537cd3aa492ebccfdbac225b34b585c5872897c5e0fe188a4994350bb153763</citedby><cites>FETCH-LOGICAL-c441t-b0537cd3aa492ebccfdbac225b34b585c5872897c5e0fe188a4994350bb153763</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jcis.2011.03.076$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27911,27912,45982</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24158054$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21492863$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xiang, Haifan</creatorcontrib><creatorcontrib>Zhang, Liang</creatorcontrib><creatorcontrib>Wang, Zhen</creatorcontrib><creatorcontrib>Yu, Xiaolan</creatorcontrib><creatorcontrib>Long, Yuhua</creatorcontrib><creatorcontrib>Zhang, Xiaoli</creatorcontrib><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Xu, Jian</creatorcontrib><title>Multifunctional polymethylsilsesquioxane (PMSQ) surfaces prepared by electrospinning at the sol–gel transition: Superhydrophobicity, excellent solvent resistance, thermal stability and enhanced sound absorption property</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>Superhydrophobic PMSQ surfaces with excellent solvent resistance and thermal stability were prepared. Modifying sponge with PMSQ not only endows ultra water repellency, but also enhances acoustic performance by 12%. [Display omitted]
► Superhydrophobic PMSQ surfaces were prepared by electrospinning at sol–gel transition. ► Superhydrophobic PMSQ surfaces show excellent resistance to solvents. ► Superhydrophobic PMSQ surfaces show thermal stability as high as 300°C. ► Superior acoustical performance was obtained when the sponge decorated with PMSQ.
Multifunctional superhydrophobic polymethylsilsesquioxane (PMSQ) surfaces with excellent solvent resistance, thermal stability and enhanced sound absorption property were manufactured by electrospinning. The surfaces with various hierarchical morphologies and hydrophobicity were obtained by electrospinning at the different stages of sol–gel transition of PMSQ prepolymer solution. At the stage with a proper viscosity the superhydrophobic PMSQ surface with a contact angle as high as 151° and a sliding angle as low as 8° was prepared. Due to the excellent thermal stability and solvent resistance properties of the cured PMSQ, the resultant surfaces remain superhydrophobicity after thermal treatment at 300°C and immersion into many solvents. Additionally, an enhanced acoustical performance and ultra water repellency were obtained simultaneously when the traditional acoustical sponge was decorated with the electrospun PMSQ superhydrophobic surface. The robust superhydrophobic PMSQ surfaces may promise practical applications in many fields.</description><subject>absorption</subject><subject>Acoustics</subject><subject>Chemistry</subject><subject>Colloidal gels. Colloidal sols</subject><subject>Colloidal state and disperse state</subject><subject>Contact angle</subject><subject>Corrosion resistance</subject><subject>Electrospinning</subject><subject>Exact sciences and technology</subject><subject>Gels - chemistry</subject><subject>General and physical chemistry</subject><subject>heat treatment</subject><subject>Hydrophobic and Hydrophilic Interactions</subject><subject>hydrophobicity</subject><subject>Organosilicon Compounds - chemistry</subject><subject>Particle Size</subject><subject>Polymers - chemistry</subject><subject>Polymethylsilsesquioxane</subject><subject>Sol gel process</subject><subject>Solid-liquid interface</subject><subject>solvents</subject><subject>Solvents - chemistry</subject><subject>Sol–gel transition</subject><subject>Sound</subject><subject>Sound absorption</subject><subject>Superhydrophobicity</subject><subject>Surface chemistry</subject><subject>Surface physical chemistry</subject><subject>Surface Properties</subject><subject>Temperature</subject><subject>Thermal stability</subject><subject>viscosity</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFks1u1DAUhSMEokPhBViANxUgdQY7ifOD2KCKP6kVoNK1ZTs3Mx554tR2qmbHO_B8bHgSrjulS1hZlr9zz733OMueMrpilFWvt6utNmGVU8ZWtFjRurqXLRht-bJmtLifLSjN2bKt2_ogexTCliLIefswO8hZ2eZNVSyyX2eTjaafBh2NG6Qlo7PzDuJmtsHYAOFyMu5aDkBefj07__aKhMn3UkMgo4dReuiImglY0NG7MJphMMOayEjiBkhw9vePn2uwJHo5BJMs3pDzaQS_mTvvxo1TRps4HxO41mAtDDGJrtLpIZgQ5aDhOBXzO2wO78pYFBA5dASGTXruUDLhVarg_Jg8sDeHHnF-nD3oJU7x5PY8zC4-vP9-8ml5-uXj55N3p0tdliwuFeVFrbtCSlwLKK37Tkmd51wVpeIN17yp86atNQfaA2sa5Nqy4FQphsqqOMxe7Oui8eUEIYqdCWkgXJybgmiatmQVrZr_k1VZNxUrCyTzPalxscFDL0ZvdtLPglGR8hdbkfIXKX9BC0FvGnl2W35SO-juJH8DR-DoFpBBS9tjLqnGHVcy3lBeIvd8z_XSCbn2yFyco1NFKY7BbyZ5uycAF3tlwIugDaQ8jMffIDpn_tXpH8N74JM</recordid><startdate>20110701</startdate><enddate>20110701</enddate><creator>Xiang, Haifan</creator><creator>Zhang, Liang</creator><creator>Wang, Zhen</creator><creator>Yu, Xiaolan</creator><creator>Long, Yuhua</creator><creator>Zhang, Xiaoli</creator><creator>Zhao, Ning</creator><creator>Xu, Jian</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SE</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110701</creationdate><title>Multifunctional polymethylsilsesquioxane (PMSQ) surfaces prepared by electrospinning at the sol–gel transition: Superhydrophobicity, excellent solvent resistance, thermal stability and enhanced sound absorption property</title><author>Xiang, Haifan ; Zhang, Liang ; Wang, Zhen ; Yu, Xiaolan ; Long, Yuhua ; Zhang, Xiaoli ; Zhao, Ning ; Xu, Jian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c441t-b0537cd3aa492ebccfdbac225b34b585c5872897c5e0fe188a4994350bb153763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>absorption</topic><topic>Acoustics</topic><topic>Chemistry</topic><topic>Colloidal gels. Colloidal sols</topic><topic>Colloidal state and disperse state</topic><topic>Contact angle</topic><topic>Corrosion resistance</topic><topic>Electrospinning</topic><topic>Exact sciences and technology</topic><topic>Gels - chemistry</topic><topic>General and physical chemistry</topic><topic>heat treatment</topic><topic>Hydrophobic and Hydrophilic Interactions</topic><topic>hydrophobicity</topic><topic>Organosilicon Compounds - chemistry</topic><topic>Particle Size</topic><topic>Polymers - chemistry</topic><topic>Polymethylsilsesquioxane</topic><topic>Sol gel process</topic><topic>Solid-liquid interface</topic><topic>solvents</topic><topic>Solvents - chemistry</topic><topic>Sol–gel transition</topic><topic>Sound</topic><topic>Sound absorption</topic><topic>Superhydrophobicity</topic><topic>Surface chemistry</topic><topic>Surface physical chemistry</topic><topic>Surface Properties</topic><topic>Temperature</topic><topic>Thermal stability</topic><topic>viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiang, Haifan</creatorcontrib><creatorcontrib>Zhang, Liang</creatorcontrib><creatorcontrib>Wang, Zhen</creatorcontrib><creatorcontrib>Yu, Xiaolan</creatorcontrib><creatorcontrib>Long, Yuhua</creatorcontrib><creatorcontrib>Zhang, Xiaoli</creatorcontrib><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Xu, Jian</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Corrosion Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiang, Haifan</au><au>Zhang, Liang</au><au>Wang, Zhen</au><au>Yu, Xiaolan</au><au>Long, Yuhua</au><au>Zhang, Xiaoli</au><au>Zhao, Ning</au><au>Xu, Jian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multifunctional polymethylsilsesquioxane (PMSQ) surfaces prepared by electrospinning at the sol–gel transition: Superhydrophobicity, excellent solvent resistance, thermal stability and enhanced sound absorption property</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2011-07-01</date><risdate>2011</risdate><volume>359</volume><issue>1</issue><spage>296</spage><epage>303</epage><pages>296-303</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><coden>JCISA5</coden><abstract>Superhydrophobic PMSQ surfaces with excellent solvent resistance and thermal stability were prepared. Modifying sponge with PMSQ not only endows ultra water repellency, but also enhances acoustic performance by 12%. [Display omitted]
► Superhydrophobic PMSQ surfaces were prepared by electrospinning at sol–gel transition. ► Superhydrophobic PMSQ surfaces show excellent resistance to solvents. ► Superhydrophobic PMSQ surfaces show thermal stability as high as 300°C. ► Superior acoustical performance was obtained when the sponge decorated with PMSQ.
Multifunctional superhydrophobic polymethylsilsesquioxane (PMSQ) surfaces with excellent solvent resistance, thermal stability and enhanced sound absorption property were manufactured by electrospinning. The surfaces with various hierarchical morphologies and hydrophobicity were obtained by electrospinning at the different stages of sol–gel transition of PMSQ prepolymer solution. At the stage with a proper viscosity the superhydrophobic PMSQ surface with a contact angle as high as 151° and a sliding angle as low as 8° was prepared. Due to the excellent thermal stability and solvent resistance properties of the cured PMSQ, the resultant surfaces remain superhydrophobicity after thermal treatment at 300°C and immersion into many solvents. Additionally, an enhanced acoustical performance and ultra water repellency were obtained simultaneously when the traditional acoustical sponge was decorated with the electrospun PMSQ superhydrophobic surface. The robust superhydrophobic PMSQ surfaces may promise practical applications in many fields.</abstract><cop>Amsterdam</cop><pub>Elsevier Inc</pub><pmid>21492863</pmid><doi>10.1016/j.jcis.2011.03.076</doi><tpages>8</tpages></addata></record> |
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| source | MEDLINE; ScienceDirect Journals (5 years ago - present) |
| subjects | absorption Acoustics Chemistry Colloidal gels. Colloidal sols Colloidal state and disperse state Contact angle Corrosion resistance Electrospinning Exact sciences and technology Gels - chemistry General and physical chemistry heat treatment Hydrophobic and Hydrophilic Interactions hydrophobicity Organosilicon Compounds - chemistry Particle Size Polymers - chemistry Polymethylsilsesquioxane Sol gel process Solid-liquid interface solvents Solvents - chemistry Sol–gel transition Sound Sound absorption Superhydrophobicity Surface chemistry Surface physical chemistry Surface Properties Temperature Thermal stability viscosity |
| title | Multifunctional polymethylsilsesquioxane (PMSQ) surfaces prepared by electrospinning at the sol–gel transition: Superhydrophobicity, excellent solvent resistance, thermal stability and enhanced sound absorption property |
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