Optimization of transesterification for methyl ester production from chicken fat
In this study, low cost feedstock chicken fat was used to produce methyl ester. After reducing the free fatty acid level of the chicken fat less than 1%, the transesterification reaction was completed with alkaline catalyst. Potassium hydroxide, sodium hydroxide, potassium methoxide and sodium metho...
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Veröffentlicht in: | Fuel (Guildford) 2011-08, Vol.90 (8), p.2630-2638 |
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creator | Alptekin, Ertan Canakci, Mustafa |
description | In this study, low cost feedstock chicken fat was used to produce methyl ester. After reducing the free fatty acid level of the chicken fat less than 1%, the transesterification reaction was completed with alkaline catalyst. Potassium hydroxide, sodium hydroxide, potassium methoxide and sodium methoxide were used as catalyst and methanol was used as alcohol for transesterification reactions. The effects of catalyst type, reaction temperature and reaction time on the fuel properties of methyl esters were investigated. The produced chicken fat methyl esters were characterized by determining their viscosity, density, pour point, flash point, acid value, methanol content, heat of combustion value, total-free glycerin, mono-di-tri glycerides, copper strip corrosion and ester yield values. The measured fuel properties of the chicken fat methyl ester met EN 14214 and ASTM D6751 biodiesel specifications when using potassium hydroxide and sodium hydroxide catalysts with high ester yield. |
doi_str_mv | 10.1016/j.fuel.2011.03.042 |
format | Article |
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After reducing the free fatty acid level of the chicken fat less than 1%, the transesterification reaction was completed with alkaline catalyst. Potassium hydroxide, sodium hydroxide, potassium methoxide and sodium methoxide were used as catalyst and methanol was used as alcohol for transesterification reactions. The effects of catalyst type, reaction temperature and reaction time on the fuel properties of methyl esters were investigated. The produced chicken fat methyl esters were characterized by determining their viscosity, density, pour point, flash point, acid value, methanol content, heat of combustion value, total-free glycerin, mono-di-tri glycerides, copper strip corrosion and ester yield values. The measured fuel properties of the chicken fat methyl ester met EN 14214 and ASTM D6751 biodiesel specifications when using potassium hydroxide and sodium hydroxide catalysts with high ester yield.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2011.03.042</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Alkaline catalyst ; Applied sciences ; Biodiesel ; Catalysts ; Chicken fat ; Chickens ; Density ; Energy ; Energy. 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After reducing the free fatty acid level of the chicken fat less than 1%, the transesterification reaction was completed with alkaline catalyst. Potassium hydroxide, sodium hydroxide, potassium methoxide and sodium methoxide were used as catalyst and methanol was used as alcohol for transesterification reactions. The effects of catalyst type, reaction temperature and reaction time on the fuel properties of methyl esters were investigated. The produced chicken fat methyl esters were characterized by determining their viscosity, density, pour point, flash point, acid value, methanol content, heat of combustion value, total-free glycerin, mono-di-tri glycerides, copper strip corrosion and ester yield values. The measured fuel properties of the chicken fat methyl ester met EN 14214 and ASTM D6751 biodiesel specifications when using potassium hydroxide and sodium hydroxide catalysts with high ester yield.</description><subject>Alkaline catalyst</subject><subject>Applied sciences</subject><subject>Biodiesel</subject><subject>Catalysts</subject><subject>Chicken fat</subject><subject>Chickens</subject><subject>Density</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Esters</subject><subject>Exact sciences and technology</subject><subject>Fuels</subject><subject>Methyl alcohol</subject><subject>Potassium hydroxides</subject><subject>Pretreatment</subject><subject>Transesterification</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKxDAUhoMoOI6-gKtuRDetJ2napOBGxBsIutB1yCQnmLGdjkkr6NObsYPLWYWT_zsXPkJOKRQUaH25LNyIbcGA0gLKAjjbIzMqRZkLWpX7ZAaJyllZ00NyFOMSAISs-Iy8PK8H3_kfPfh-lfUuG4JeRYwDBu-8mb5dH7IOh_fvNvtLsnXo7WimLPRdZt69-cBU6OGYHDjdRjzZvnPydnf7evOQPz3fP95cP-WG13TIK4ELzZ01Ao2VDUorgaWEg2D1QlPQkrNKInfMggXNoWqobkxTG9ssyqack_Npbrrlc0xnqc5Hg22rV9iPUUnZpFmc1om82ElSIQRlaW2VUDahJvQxBnRqHXynw7eioDai1VJtRKuNaAWlSqJT09l2vo5Gty4JND7-d7KEVKKUibuaOExavjwGFY3HlUHrA5pB2d7vWvMLNUCUcA</recordid><startdate>20110801</startdate><enddate>20110801</enddate><creator>Alptekin, Ertan</creator><creator>Canakci, Mustafa</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope><scope>7ST</scope><scope>SOI</scope></search><sort><creationdate>20110801</creationdate><title>Optimization of transesterification for methyl ester production from chicken fat</title><author>Alptekin, Ertan ; Canakci, Mustafa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c461t-57eba4fdc7ecd89e8d80246140726ba10a84258e4f2d0d0a40591a9c96cd9b393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Alkaline catalyst</topic><topic>Applied sciences</topic><topic>Biodiesel</topic><topic>Catalysts</topic><topic>Chicken fat</topic><topic>Chickens</topic><topic>Density</topic><topic>Energy</topic><topic>Energy. 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After reducing the free fatty acid level of the chicken fat less than 1%, the transesterification reaction was completed with alkaline catalyst. Potassium hydroxide, sodium hydroxide, potassium methoxide and sodium methoxide were used as catalyst and methanol was used as alcohol for transesterification reactions. The effects of catalyst type, reaction temperature and reaction time on the fuel properties of methyl esters were investigated. The produced chicken fat methyl esters were characterized by determining their viscosity, density, pour point, flash point, acid value, methanol content, heat of combustion value, total-free glycerin, mono-di-tri glycerides, copper strip corrosion and ester yield values. 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subjects | Alkaline catalyst Applied sciences Biodiesel Catalysts Chicken fat Chickens Density Energy Energy. Thermal use of fuels Esters Exact sciences and technology Fuels Methyl alcohol Potassium hydroxides Pretreatment Transesterification |
title | Optimization of transesterification for methyl ester production from chicken fat |
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