Estimation of kinetic parameters of the passive state of carbon steel in mildly alkaline solutions from electrochemical impedance spectroscopic and X-ray photoelectron spectroscopic data

► The passive state of carbon steel is described using the Mixed-Conduction Model for oxide films. ► Kinetic parameters are estimated by comparison of the model to EIS and XPS data. ► The passive film is intermediate between magnetite and maghemite. ► Relevance of film growth and dissolution reactio...

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Veröffentlicht in:	Electrochimica acta 2011-07, Vol.56 (17), p.5910-5918
Hauptverfasser:	Zhang, X., Wren, J.C., Betova, I., Bojinov, M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Adjustable Applied sciences Carbon steel Carbon steels Corrosion Corrosion mechanisms Electrochemical impedance spectroscopy Estimates Exact sciences and technology Kinetic model Mathematical models Metals. Metallurgy Passivity Photoelectrons Spectroscopy X-ray photoelectron spectroscopy X-rays
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