A comparative study of nanocrystalline Cu film deposited using anodic vacuum arc and dc magnetron sputtering

A comparative study of structural, electrical and thermoelectric properties of nanocrystalline copper thin films deposited using anodic vacuum arc plasma deposition technique and dc-magnetron sputtering is presented. The crystallographic texture and structural evolution of these films are investigat...

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Veröffentlicht in:Surface & coatings technology 2011-06, Vol.205 (19), p.4582-4595
Hauptverfasser: Mukherjee, S.K., Joshi, L., Barhai, P.K.
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container_title Surface & coatings technology
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creator Mukherjee, S.K.
Joshi, L.
Barhai, P.K.
description A comparative study of structural, electrical and thermoelectric properties of nanocrystalline copper thin films deposited using anodic vacuum arc plasma deposition technique and dc-magnetron sputtering is presented. The crystallographic texture and structural evolution of these films are investigated as a function of thickness within a range of 30 to 230nm using XRD and SEM. AVA deposited Cu films possess smaller grains with a lesser degree of crystallinity than dc-sputtered ones. Electrical resistivity, temperature coefficient of resistance and thermoelectric power of both as-deposited and annealed Cu films of AVA and dc-magnetron sputtering is measured and their dependence on the film thickness is investigated. AVA deposited Cu films having thickness less than 100nm show much higher resistivity than dc-sputtered ones. AVA deposited Cu films possess lower temperature coefficient of resistance values than dc-sputtered ones. The observed thickness dependence of thermoelectric power is larger in AVA deposited Cu films than in dc-sputtered ones. These electrical measurements reveal that AVA deposited Cu films possess more vacancies than dc-sputtered ones. ► AVA deposition rate is much higher than that of sputter deposition. ► AVA-deposited Cu films possess smaller crystallites than dc-sputtered ones. ► AVA deposited films having thickness less than 100 nm are more resistive. ► AVA deposited Cu films show lower temperature coefficient of resistance. ► The change in thermoelectric power w.r.t. Cu bulk is higher in AVA deposited films.
doi_str_mv 10.1016/j.surfcoat.2011.03.119
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These electrical measurements reveal that AVA deposited Cu films possess more vacancies than dc-sputtered ones. ► AVA deposition rate is much higher than that of sputter deposition. ► AVA-deposited Cu films possess smaller crystallites than dc-sputtered ones. ► AVA deposited films having thickness less than 100 nm are more resistive. ► AVA deposited Cu films show lower temperature coefficient of resistance. ► The change in thermoelectric power w.r.t. Cu bulk is higher in AVA deposited films.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.surfcoat.2011.03.119</doi><tpages>14</tpages></addata></record>
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subjects ANODES
Anodic vacuum arc
Applied sciences
Arc deposition
ARCS
Coefficients
Copper
Cross-disciplinary physics: materials science
rheology
CRYSTAL STRUCTURE
DEPOSITION
Electric power generation
ELECTRICAL CONDUCTIVITY
Electrical resistivity
ELECTRICITY
Exact sciences and technology
Magnetron sputtering
Materials science
Metals. Metallurgy
Nanocrystalline
Physics
Production techniques
Resistivity
SPUTTERING
Surface treatment
Surface treatments
Texture
TEXTURES
Thermoelectricity
XRD
title A comparative study of nanocrystalline Cu film deposited using anodic vacuum arc and dc magnetron sputtering
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