Enhancing the stability of power generation of single-chamber microbial fuel cells using an anion exchange membrane

BACKGROUD: A decreased power density could be observed in a single-chamber microbial fuel cell (MFC) with a cation exchange membrane (CEM), as a result of pH-associated problem and a precipitated salt-associated problem, due to the transport of cations other than protons through the membrane to the...

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Veröffentlicht in:Journal of chemical technology and biotechnology (1986) 2009-12, Vol.84 (12), p.1767-1772
Hauptverfasser: Mo, Yinghui, Liang, Peng, Huang, Xia, Wang, Huiyong, Cao, Xiaoxin
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container_end_page 1772
container_issue 12
container_start_page 1767
container_title Journal of chemical technology and biotechnology (1986)
container_volume 84
creator Mo, Yinghui
Liang, Peng
Huang, Xia
Wang, Huiyong
Cao, Xiaoxin
description BACKGROUD: A decreased power density could be observed in a single-chamber microbial fuel cell (MFC) with a cation exchange membrane (CEM), as a result of pH-associated problem and a precipitated salt-associated problem, due to the transport of cations other than protons through the membrane to the cathode. To inhibit cation transport and enhance the stability of power generation, an anion exchange membranes (AEM) was applied in a single-chamber MFC.RESULTS: After 70 days' operation, the power density dropped 29% in the MFC with an AEM (AMFC), smaller than 48% in the MFC with a cation exchange membrane (CMFC). The reason for this difference lay in internal resistance development. Membrane resistance in the AMFC remained the same but that in the CMFC was increased by 67 Ω, and the cathode resistance increase in the AMFC was 54 Ω, while that in the CMFC was 123 Ω. The precipitated cations on the cathode catalyst surface in the CMFC, which accounted for the resistance increase, were up to 84 times larger than that in the AMFC.CONCLUSION: Because of its capacity for inhibiting cations, the AMFC possessed more stable membrane and cathode resistances; thus an enhanced power generation was obtained. Copyright
doi_str_mv 10.1002/jctb.2242
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To inhibit cation transport and enhance the stability of power generation, an anion exchange membranes (AEM) was applied in a single-chamber MFC.RESULTS: After 70 days' operation, the power density dropped 29% in the MFC with an AEM (AMFC), smaller than 48% in the MFC with a cation exchange membrane (CMFC). The reason for this difference lay in internal resistance development. Membrane resistance in the AMFC remained the same but that in the CMFC was increased by 67 Ω, and the cathode resistance increase in the AMFC was 54 Ω, while that in the CMFC was 123 Ω. The precipitated cations on the cathode catalyst surface in the CMFC, which accounted for the resistance increase, were up to 84 times larger than that in the AMFC.CONCLUSION: Because of its capacity for inhibiting cations, the AMFC possessed more stable membrane and cathode resistances; thus an enhanced power generation was obtained. Copyright</description><identifier>ISSN: 0268-2575</identifier><identifier>ISSN: 1097-4660</identifier><identifier>EISSN: 1097-4660</identifier><identifier>DOI: 10.1002/jctb.2242</identifier><identifier>CODEN: JCTBDC</identifier><language>eng</language><publisher>Chichester, UK: John Wiley &amp; Sons, Ltd</publisher><subject>anion exchange membrane ; Anion exchanging ; Applied sciences ; Biochemical fuel cells ; Catalysis ; Catalytic reactions ; Cathodes ; Cation exchanging ; cation precipitation ; Chemical engineering ; Chemistry ; Density ; Energy ; Energy. Thermal use of fuels ; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc ; Exact sciences and technology ; Fuel cells ; General and physical chemistry ; Ion exchange ; Membranes ; Microorganisms ; Power generation ; Reactors ; single-chamber microbial fuel cell ; Theory of reactions, general kinetics. Catalysis. 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Chem. Technol. Biotechnol</addtitle><description>BACKGROUD: A decreased power density could be observed in a single-chamber microbial fuel cell (MFC) with a cation exchange membrane (CEM), as a result of pH-associated problem and a precipitated salt-associated problem, due to the transport of cations other than protons through the membrane to the cathode. To inhibit cation transport and enhance the stability of power generation, an anion exchange membranes (AEM) was applied in a single-chamber MFC.RESULTS: After 70 days' operation, the power density dropped 29% in the MFC with an AEM (AMFC), smaller than 48% in the MFC with a cation exchange membrane (CMFC). The reason for this difference lay in internal resistance development. Membrane resistance in the AMFC remained the same but that in the CMFC was increased by 67 Ω, and the cathode resistance increase in the AMFC was 54 Ω, while that in the CMFC was 123 Ω. 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Chem. Technol. Biotechnol</addtitle><date>2009-12</date><risdate>2009</risdate><volume>84</volume><issue>12</issue><spage>1767</spage><epage>1772</epage><pages>1767-1772</pages><issn>0268-2575</issn><issn>1097-4660</issn><eissn>1097-4660</eissn><coden>JCTBDC</coden><abstract>BACKGROUD: A decreased power density could be observed in a single-chamber microbial fuel cell (MFC) with a cation exchange membrane (CEM), as a result of pH-associated problem and a precipitated salt-associated problem, due to the transport of cations other than protons through the membrane to the cathode. To inhibit cation transport and enhance the stability of power generation, an anion exchange membranes (AEM) was applied in a single-chamber MFC.RESULTS: After 70 days' operation, the power density dropped 29% in the MFC with an AEM (AMFC), smaller than 48% in the MFC with a cation exchange membrane (CMFC). The reason for this difference lay in internal resistance development. 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source Wiley Online Library Journals Frontfile Complete
subjects anion exchange membrane
Anion exchanging
Applied sciences
Biochemical fuel cells
Catalysis
Catalytic reactions
Cathodes
Cation exchanging
cation precipitation
Chemical engineering
Chemistry
Density
Energy
Energy. Thermal use of fuels
Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc
Exact sciences and technology
Fuel cells
General and physical chemistry
Ion exchange
Membranes
Microorganisms
Power generation
Reactors
single-chamber microbial fuel cell
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Transport
title Enhancing the stability of power generation of single-chamber microbial fuel cells using an anion exchange membrane
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