Assessment of the generation of chlorinated byproducts upon Fenton-like oxidation of chlorophenols at different conditions

► The possibility of working under substoichiometric conditions is seriously limited. ► PCB's, dioxins and diphenyl ethers were formed. ► A carbonaceous solid residue containing Cl and Fe was formed. ► An increase of ecotoxicity was observed. Homogeneous Fenton-like (H 2O 2/Fe 3+) oxidation pro...

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Veröffentlicht in:	Journal of hazardous materials 2011-06, Vol.190 (1), p.993-1000
Hauptverfasser:	Munoz, Macarena, de Pedro, Zahara M., Casas, Jose A., Rodriguez, Juan J.
Format:	Artikel
Sprache:	eng
Schlagworte:	acids Advanced oxidation Applied sciences Assessments Byproducts Carbon carbon dioxide Chemical engineering Chlorination chlorine Chlorophenols Chlorophenols - chemistry condensation Condensation byproducts Dioxins Ethers Exact sciences and technology Fenton-like process General purification processes Halogenation hydrogen peroxide Hydrogen Peroxide - chemistry Industrial Waste - prevention & control Iron Iron - chemistry Oxidation Oxidation-Reduction oxygen Pollution Polychlorinated Biphenyls Reactors toxicity Waste water wastewater Wastewaters Water Pollutants, Chemical - chemical synthesis Water Pollutants, Chemical - toxicity Water treatment and pollution
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