Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?
A plethora of methods have been developed over the years so that carbon dioxide can be used as a reactant in organic synthesis. Given the abundance of this compound, its utilization in synthetic chemistry, particularly on an industrial scale, is still at a rather low level. In the last 35 years, con...
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| creator | Cokoja, Mirza Bruckmeier, Christian Rieger, Bernhard Herrmann, Wolfgang A. Kühn, Fritz E. |
| description | A plethora of methods have been developed over the years so that carbon dioxide can be used as a reactant in organic synthesis. Given the abundance of this compound, its utilization in synthetic chemistry, particularly on an industrial scale, is still at a rather low level. In the last 35 years, considerable research has been performed to find catalytic routes to transform CO2 into carboxylic acids, esters, lactones, and polymers in an economic way. This Review presents an overview of the available homogeneous catalytic routes that use carbon dioxide as a C1 carbon source for the synthesis of industrial products as well as fine chemicals.
Renewable carbon resources, such as carbon dioxide, are of enormous interest as an entry into industrially relevant chemicals, such as formic or salicylic acids, urea, and (poly)carbonates. This Review highlights the use of CO2 as a C1 feedstock as well as its transformation with homogeneous molecular transition‐metal catalysts. |
| doi_str_mv | 10.1002/anie.201102010 |
| format | Article |
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Renewable carbon resources, such as carbon dioxide, are of enormous interest as an entry into industrially relevant chemicals, such as formic or salicylic acids, urea, and (poly)carbonates. This Review highlights the use of CO2 as a C1 feedstock as well as its transformation with homogeneous molecular transition‐metal catalysts.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201102010</identifier><identifier>PMID: 21887758</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Carbon dioxide ; Carbon Dioxide - chemistry ; Carboxylic Acids - chemical synthesis ; Carboxylic Acids - chemistry ; Catalysis ; Chemical bonds ; Conservation of Natural Resources ; Esters - chemical synthesis ; Esters - chemistry ; homogeneous catalysis ; Lactones - chemical synthesis ; Lactones - chemistry ; organometallic catalysts ; Polymers - chemical synthesis ; Polymers - chemistry ; renewable resources ; sustainable chemistry ; Transition Elements - chemistry</subject><ispartof>Angewandte Chemie International Edition, 2011-09, Vol.50 (37), p.8510-8537</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4470-83da5533e3cdefd210960760dcc402914b0f7b12b0734ec4e6a566805da819e33</citedby><cites>FETCH-LOGICAL-c4470-83da5533e3cdefd210960760dcc402914b0f7b12b0734ec4e6a566805da819e33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201102010$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201102010$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,782,786,1419,27933,27934,45583,45584</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21887758$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cokoja, Mirza</creatorcontrib><creatorcontrib>Bruckmeier, Christian</creatorcontrib><creatorcontrib>Rieger, Bernhard</creatorcontrib><creatorcontrib>Herrmann, Wolfgang A.</creatorcontrib><creatorcontrib>Kühn, Fritz E.</creatorcontrib><title>Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>A plethora of methods have been developed over the years so that carbon dioxide can be used as a reactant in organic synthesis. Given the abundance of this compound, its utilization in synthetic chemistry, particularly on an industrial scale, is still at a rather low level. In the last 35 years, considerable research has been performed to find catalytic routes to transform CO2 into carboxylic acids, esters, lactones, and polymers in an economic way. This Review presents an overview of the available homogeneous catalytic routes that use carbon dioxide as a C1 carbon source for the synthesis of industrial products as well as fine chemicals.
Renewable carbon resources, such as carbon dioxide, are of enormous interest as an entry into industrially relevant chemicals, such as formic or salicylic acids, urea, and (poly)carbonates. This Review highlights the use of CO2 as a C1 feedstock as well as its transformation with homogeneous molecular transition‐metal catalysts.</description><subject>Carbon dioxide</subject><subject>Carbon Dioxide - chemistry</subject><subject>Carboxylic Acids - chemical synthesis</subject><subject>Carboxylic Acids - chemistry</subject><subject>Catalysis</subject><subject>Chemical bonds</subject><subject>Conservation of Natural Resources</subject><subject>Esters - chemical synthesis</subject><subject>Esters - chemistry</subject><subject>homogeneous catalysis</subject><subject>Lactones - chemical synthesis</subject><subject>Lactones - chemistry</subject><subject>organometallic catalysts</subject><subject>Polymers - chemical synthesis</subject><subject>Polymers - chemistry</subject><subject>renewable resources</subject><subject>sustainable chemistry</subject><subject>Transition Elements - chemistry</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU1P3DAURaOqqFDotsvKUhddZbDj-CPdVKOUDkiQCkHVpeUkL2DqxGAngvn3ODMwqrrp5vktzrmyfZPkI8ELgnF2rAcDiwwTguPAb5IDwjKSUiHo27jnlKZCMrKfvA_hLvJSYv4u2c-IlEIweZCsr70eQud8r0fjBuQ6VGpfx-27cU-mBfRoxlt06np3AwO4KaCNYWY6vYBR2yjEuQ5j-IqW6MJZaCarPbpydtpkjg5ptLKuntlbbS0MN_DtKNnrtA3w4eU8TH79OLkuT9Pzn6uzcnmeNnkucCppqxmjFGjTQtdmBBccC47bpslxVpC8xp2oSVZjQXNocuCacS4xa7UkBVB6mHzZ5t579zBBGFVvQgPW6s1zVPwJhrkUMpKf_yHv3OSHeDlFGOGcclzM1GJLNd6F4KFT99702q8VwWruRM2dqF0nUfj0EjvVPbQ7_LWECBRb4NFYWP8nTi2rs5O_w9Ota8IITztX-z-KCyqY-l2tVJnLy7K6rFRFnwHGbKdE</recordid><startdate>20110905</startdate><enddate>20110905</enddate><creator>Cokoja, Mirza</creator><creator>Bruckmeier, Christian</creator><creator>Rieger, Bernhard</creator><creator>Herrmann, Wolfgang A.</creator><creator>Kühn, Fritz E.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20110905</creationdate><title>Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?</title><author>Cokoja, Mirza ; Bruckmeier, Christian ; Rieger, Bernhard ; Herrmann, Wolfgang A. ; Kühn, Fritz E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4470-83da5533e3cdefd210960760dcc402914b0f7b12b0734ec4e6a566805da819e33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Carbon dioxide</topic><topic>Carbon Dioxide - chemistry</topic><topic>Carboxylic Acids - chemical synthesis</topic><topic>Carboxylic Acids - chemistry</topic><topic>Catalysis</topic><topic>Chemical bonds</topic><topic>Conservation of Natural Resources</topic><topic>Esters - chemical synthesis</topic><topic>Esters - chemistry</topic><topic>homogeneous catalysis</topic><topic>Lactones - chemical synthesis</topic><topic>Lactones - chemistry</topic><topic>organometallic catalysts</topic><topic>Polymers - chemical synthesis</topic><topic>Polymers - chemistry</topic><topic>renewable resources</topic><topic>sustainable chemistry</topic><topic>Transition Elements - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cokoja, Mirza</creatorcontrib><creatorcontrib>Bruckmeier, Christian</creatorcontrib><creatorcontrib>Rieger, Bernhard</creatorcontrib><creatorcontrib>Herrmann, Wolfgang A.</creatorcontrib><creatorcontrib>Kühn, Fritz E.</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cokoja, Mirza</au><au>Bruckmeier, Christian</au><au>Rieger, Bernhard</au><au>Herrmann, Wolfgang A.</au><au>Kühn, Fritz E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. 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Renewable carbon resources, such as carbon dioxide, are of enormous interest as an entry into industrially relevant chemicals, such as formic or salicylic acids, urea, and (poly)carbonates. This Review highlights the use of CO2 as a C1 feedstock as well as its transformation with homogeneous molecular transition‐metal catalysts.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>21887758</pmid><doi>10.1002/anie.201102010</doi><tpages>28</tpages><edition>International ed. in English</edition></addata></record> |
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| subjects | Carbon dioxide Carbon Dioxide - chemistry Carboxylic Acids - chemical synthesis Carboxylic Acids - chemistry Catalysis Chemical bonds Conservation of Natural Resources Esters - chemical synthesis Esters - chemistry homogeneous catalysis Lactones - chemical synthesis Lactones - chemistry organometallic catalysts Polymers - chemical synthesis Polymers - chemistry renewable resources sustainable chemistry Transition Elements - chemistry |
| title | Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge? |
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