Dinuclear Silylium-enolate Bifunctional Active Species: Remarkable Activity and Stereoselectivity toward Polymerization of Methacrylate and Renewable Methylene Butyrolactone Monomers

Novel dinuclear silylium-enolate active species, consisting of an electrophilic silylium catalyst site and a nucleophilic silicon enolate initiating site that are covalently linked as single molecules, and their unique polymerization characteristics and kinetics are reported. Such unimolecular, bifu...

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Veröffentlicht in:	Journal of the American Chemical Society 2011-08, Vol.133 (34), p.13674-13684
Hauptverfasser:	Zhang, Yuetao, Gustafson, Laura O, Chen, Eugene Y.-X
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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