Controlling the Transmission of Stereochemical Information through Space in Terphenyl-Edged Fe4L6 Cages

A series of terphenyl-edged Fe4L6 cages were synthesized from substituted 4,4′′-diamino-p-terphenyls, 2-formylpyridine, and iron(II). For the parent diaminoterphenyl, all three possible diastereomers, with T, S 4, and C 3 point symmetries, were formed in nearly equal amounts, as determined by 1H and...

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Veröffentlicht in:Journal of the American Chemical Society 2011-08, Vol.133 (34), p.13652-13660
Hauptverfasser: Meng, Wenjing, Clegg, Jack K, Thoburn, John D, Nitschke, Jonathan R
Format: Artikel
Sprache:eng
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