Facile synthesis of unusual glycosyl carbamates and amino acid glycosides from propargyl 1,2-orthoesters as glycosyl donors

Propargyl 1,2-O-orthoesters are exploited for the synthesis of 1,2-trans O-glycosides of protected amino acids. N-Fmoc- and N-Cbz protected serine/threonine - benzyl/methyl esters reacted well with glucosyl-, galactosyl-, mannosyl- and lactosyl- derived propargyl 1,2-orthoesters affording respective...

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Veröffentlicht in:	Organic & biomolecular chemistry 2011-09, Vol.9 (17), p.5951-5959
Hauptverfasser:	Shaikh, Ashif Y, Sureshkumar, Gopalsamy, Pati, Debasish, Sen Gupta, Sayam, Hotha, Srinivas
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino Acids - chemical synthesis Amino Acids - chemistry Carbamates - chemical synthesis Carbamates - chemistry Esters - chemical synthesis Esters - chemistry Glycosides - chemical synthesis Glycosides - chemistry
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