Olefin–Borane “van der Waals Complexes”: Intermediates in Frustrated Lewis Pair Addition Reactions

The nature of the borane–olefin interactions that take place prior to frustrated Lewis pair addition reactions has been probed employing a Lewis acidic borane tethered to a vinyl group through an alkyl chain. 1H{19F} HOESY spectral data obtained at −50 °C demonstrated the spatial proximity of the bo...

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Veröffentlicht in:	Journal of the American Chemical Society 2011-08, Vol.133 (32), p.12448-12450
Hauptverfasser:	Zhao, Xiaoxi, Stephan, Douglas W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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