Biocatalytic ester synthesis in ionic liquid media
Ionic liquids have shown potential as green reaction media compared with organic solvents, mainly due to their lack of vapour pressure. In non-aqueous enzymology, ionic liquids are opening up new fields. The advantages of using ionic liquids over the use of organic solvents as reaction medium for bi...
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| Veröffentlicht in: | Journal of chemical technology and biotechnology (1986) 2010-11, Vol.85 (11), p.1423-1435 |
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| container_issue | 11 |
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| container_title | Journal of chemical technology and biotechnology (1986) |
| container_volume | 85 |
| creator | Hernández-Fernández, Francisco J de los Ríos, Antonia P Lozano-Blanco, Luis J Godínez, Carlos |
| description | Ionic liquids have shown potential as green reaction media compared with organic solvents, mainly due to their lack of vapour pressure. In non-aqueous enzymology, ionic liquids are opening up new fields. The advantages of using ionic liquids over the use of organic solvents as reaction medium for biocatalysis include enhancement of enzyme activity, stability and selectivity.In this work, the enzymatic synthesis of esters in ionic liquids has been extensively reviewed. Numerous examples of the application of ionic liquids as reaction medium for the enzymatic production of esters have been included. The effect of the nature of the ionic liquid on activity, selectivity and stability of enzymes which catalyze esters synthesis has been carefully analysed. Innovative reaction methodologies for the biosynthesis of esters, including ionic liquid/supercritical carbon dioxide biphasic systems and the integrated reaction/separation processes using supported liquid membranes based on ionic liquids have been revised. Copyright |
| doi_str_mv | 10.1002/jctb.2453 |
| format | Article |
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In non-aqueous enzymology, ionic liquids are opening up new fields. The advantages of using ionic liquids over the use of organic solvents as reaction medium for biocatalysis include enhancement of enzyme activity, stability and selectivity.In this work, the enzymatic synthesis of esters in ionic liquids has been extensively reviewed. Numerous examples of the application of ionic liquids as reaction medium for the enzymatic production of esters have been included. The effect of the nature of the ionic liquid on activity, selectivity and stability of enzymes which catalyze esters synthesis has been carefully analysed. Innovative reaction methodologies for the biosynthesis of esters, including ionic liquid/supercritical carbon dioxide biphasic systems and the integrated reaction/separation processes using supported liquid membranes based on ionic liquids have been revised. 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Chem. Technol. Biotechnol</addtitle><description>Ionic liquids have shown potential as green reaction media compared with organic solvents, mainly due to their lack of vapour pressure. In non-aqueous enzymology, ionic liquids are opening up new fields. The advantages of using ionic liquids over the use of organic solvents as reaction medium for biocatalysis include enhancement of enzyme activity, stability and selectivity.In this work, the enzymatic synthesis of esters in ionic liquids has been extensively reviewed. Numerous examples of the application of ionic liquids as reaction medium for the enzymatic production of esters have been included. The effect of the nature of the ionic liquid on activity, selectivity and stability of enzymes which catalyze esters synthesis has been carefully analysed. Innovative reaction methodologies for the biosynthesis of esters, including ionic liquid/supercritical carbon dioxide biphasic systems and the integrated reaction/separation processes using supported liquid membranes based on ionic liquids have been revised. Copyright</description><subject>Applied sciences</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>Chemical engineering</subject><subject>enzyme</subject><subject>ester synthesis</subject><subject>Esters</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>green chemistry</subject><subject>ionic liquid</subject><subject>Ionic liquids</subject><subject>Media</subject><subject>Membrane separation (reverse osmosis, dialysis...)</subject><subject>Methods. Procedures. 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Technologies</topic><topic>Others</topic><topic>Selectivity</topic><topic>Solvents</topic><topic>Stability</topic><topic>Synthesis</topic><topic>Vapor pressure</topic><topic>Various methods and equipments</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hernández-Fernández, Francisco J</creatorcontrib><creatorcontrib>de los Ríos, Antonia P</creatorcontrib><creatorcontrib>Lozano-Blanco, Luis J</creatorcontrib><creatorcontrib>Godínez, Carlos</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology Research Abstracts</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of chemical technology and biotechnology (1986)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hernández-Fernández, Francisco J</au><au>de los Ríos, Antonia P</au><au>Lozano-Blanco, Luis J</au><au>Godínez, Carlos</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biocatalytic ester synthesis in ionic liquid media</atitle><jtitle>Journal of chemical technology and biotechnology (1986)</jtitle><addtitle>J. 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| identifier | ISSN: 0268-2575 |
| ispartof | Journal of chemical technology and biotechnology (1986), 2010-11, Vol.85 (11), p.1423-1435 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences Biological and medical sciences Biotechnology Chemical engineering enzyme ester synthesis Esters Exact sciences and technology Fundamental and applied biological sciences. Psychology green chemistry ionic liquid Ionic liquids Media Membrane separation (reverse osmosis, dialysis...) Methods. Procedures. Technologies Others Selectivity Solvents Stability Synthesis Vapor pressure Various methods and equipments |
| title | Biocatalytic ester synthesis in ionic liquid media |
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