From Micelle Supramolecular Assemblies in Selective Solvents to Isoporous Membranes
The supramolecular assembly of PS-b-P4VP copolymer micelles induced by selective solvent mixtures was used to manufacture isoporous membranes. Micelle order in solution was confirmed by cryo-scanning electron microscopy in casting solutions, leading to ordered pore morphology. When dioxane, a solven...
Gespeichert in:
| Veröffentlicht in: | Langmuir 2011-08, Vol.27 (16), p.10184-10190 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 10190 |
|---|---|
| container_issue | 16 |
| container_start_page | 10184 |
| container_title | Langmuir |
| container_volume | 27 |
| creator | Nunes, Suzana P Karunakaran, Madhavan Pradeep, Neelakanda Behzad, Ali Reza Hooghan, Bobby Sougrat, Rachid He, Haoze Peinemann, Klaus-Viktor |
| description | The supramolecular assembly of PS-b-P4VP copolymer micelles induced by selective solvent mixtures was used to manufacture isoporous membranes. Micelle order in solution was confirmed by cryo-scanning electron microscopy in casting solutions, leading to ordered pore morphology. When dioxane, a solvent that interacts poorly with the micelle corona, was added to the solution, polymer–polymer segment contact was preferential, increasing the intermicelle contact. Immersion in water gave rise to asymmetric porous membranes with exceptional pore uniformity and high porosity. The introduction of a small number of carbon nanotubes to the casting solution improved the membrane stability and the reversibility of the gate response in the presence of different pH values. |
| doi_str_mv | 10.1021/la201439p |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_882089230</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>882089230</sourcerecordid><originalsourceid>FETCH-LOGICAL-a344t-9a331a532dcfc19a299a91c0c68132c0b558f5cd4e60bed676df3bea23d14ef33</originalsourceid><addsrcrecordid>eNpt0E1LwzAYB_AgipvTg19AehHxUM1rmxxlOB1seJieS5qm0JEuNU878NubsbldPD3w8ON5-SN0S_ATwZQ8O00x4Ux1Z2hMBMWpkDQ_R2Occ5bmPGMjdAWwxhgrxtUlGlGSE6xkPkarWfBtsmyMdc4mq6ELuvXOmsHpkLwA2LZ0jYWk2SQrG_t9s43Mu63d9JD0PpmD73zwAyTLaIPeWLhGF7V2YG8OdYK-Zq-f0_d08fE2n74sUs0471OlGSNaMFqZ2hClqVJaEYNNJgmjBpdCyFqYitsMl7bK8qyqWWk1ZRXhtmZsgh72c7vgvwcLfdE2sHskHhEPKqSkWCrKcJSPe2mCBwi2LrrQtDr8FAQXuwiLY4TR3h2mDmVrq6P8yyyC-wPQYLSr48-mgZPjnAop1MlpA8XaD2ETw_hn4S_Bj4Vy</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>882089230</pqid></control><display><type>article</type><title>From Micelle Supramolecular Assemblies in Selective Solvents to Isoporous Membranes</title><source>MEDLINE</source><source>American Chemical Society Journals</source><creator>Nunes, Suzana P ; Karunakaran, Madhavan ; Pradeep, Neelakanda ; Behzad, Ali Reza ; Hooghan, Bobby ; Sougrat, Rachid ; He, Haoze ; Peinemann, Klaus-Viktor</creator><creatorcontrib>Nunes, Suzana P ; Karunakaran, Madhavan ; Pradeep, Neelakanda ; Behzad, Ali Reza ; Hooghan, Bobby ; Sougrat, Rachid ; He, Haoze ; Peinemann, Klaus-Viktor</creatorcontrib><description>The supramolecular assembly of PS-b-P4VP copolymer micelles induced by selective solvent mixtures was used to manufacture isoporous membranes. Micelle order in solution was confirmed by cryo-scanning electron microscopy in casting solutions, leading to ordered pore morphology. When dioxane, a solvent that interacts poorly with the micelle corona, was added to the solution, polymer–polymer segment contact was preferential, increasing the intermicelle contact. Immersion in water gave rise to asymmetric porous membranes with exceptional pore uniformity and high porosity. The introduction of a small number of carbon nanotubes to the casting solution improved the membrane stability and the reversibility of the gate response in the presence of different pH values.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la201439p</identifier><identifier>PMID: 21710987</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Colloidal state and disperse state ; Dioxanes - chemistry ; Exact sciences and technology ; General and physical chemistry ; Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites ; Membranes ; Micelles ; Micelles. Thin films ; Nanotubes, Carbon - chemistry ; Polymers - chemistry ; Porosity ; Porous materials ; Solvents - chemistry</subject><ispartof>Langmuir, 2011-08, Vol.27 (16), p.10184-10190</ispartof><rights>Copyright © 2011 American Chemical Society</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a344t-9a331a532dcfc19a299a91c0c68132c0b558f5cd4e60bed676df3bea23d14ef33</citedby><cites>FETCH-LOGICAL-a344t-9a331a532dcfc19a299a91c0c68132c0b558f5cd4e60bed676df3bea23d14ef33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/la201439p$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/la201439p$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24425859$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21710987$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nunes, Suzana P</creatorcontrib><creatorcontrib>Karunakaran, Madhavan</creatorcontrib><creatorcontrib>Pradeep, Neelakanda</creatorcontrib><creatorcontrib>Behzad, Ali Reza</creatorcontrib><creatorcontrib>Hooghan, Bobby</creatorcontrib><creatorcontrib>Sougrat, Rachid</creatorcontrib><creatorcontrib>He, Haoze</creatorcontrib><creatorcontrib>Peinemann, Klaus-Viktor</creatorcontrib><title>From Micelle Supramolecular Assemblies in Selective Solvents to Isoporous Membranes</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>The supramolecular assembly of PS-b-P4VP copolymer micelles induced by selective solvent mixtures was used to manufacture isoporous membranes. Micelle order in solution was confirmed by cryo-scanning electron microscopy in casting solutions, leading to ordered pore morphology. When dioxane, a solvent that interacts poorly with the micelle corona, was added to the solution, polymer–polymer segment contact was preferential, increasing the intermicelle contact. Immersion in water gave rise to asymmetric porous membranes with exceptional pore uniformity and high porosity. The introduction of a small number of carbon nanotubes to the casting solution improved the membrane stability and the reversibility of the gate response in the presence of different pH values.</description><subject>Chemistry</subject><subject>Colloidal state and disperse state</subject><subject>Dioxanes - chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites</subject><subject>Membranes</subject><subject>Micelles</subject><subject>Micelles. Thin films</subject><subject>Nanotubes, Carbon - chemistry</subject><subject>Polymers - chemistry</subject><subject>Porosity</subject><subject>Porous materials</subject><subject>Solvents - chemistry</subject><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0E1LwzAYB_AgipvTg19AehHxUM1rmxxlOB1seJieS5qm0JEuNU878NubsbldPD3w8ON5-SN0S_ATwZQ8O00x4Ux1Z2hMBMWpkDQ_R2Occ5bmPGMjdAWwxhgrxtUlGlGSE6xkPkarWfBtsmyMdc4mq6ELuvXOmsHpkLwA2LZ0jYWk2SQrG_t9s43Mu63d9JD0PpmD73zwAyTLaIPeWLhGF7V2YG8OdYK-Zq-f0_d08fE2n74sUs0471OlGSNaMFqZ2hClqVJaEYNNJgmjBpdCyFqYitsMl7bK8qyqWWk1ZRXhtmZsgh72c7vgvwcLfdE2sHskHhEPKqSkWCrKcJSPe2mCBwi2LrrQtDr8FAQXuwiLY4TR3h2mDmVrq6P8yyyC-wPQYLSr48-mgZPjnAop1MlpA8XaD2ETw_hn4S_Bj4Vy</recordid><startdate>20110816</startdate><enddate>20110816</enddate><creator>Nunes, Suzana P</creator><creator>Karunakaran, Madhavan</creator><creator>Pradeep, Neelakanda</creator><creator>Behzad, Ali Reza</creator><creator>Hooghan, Bobby</creator><creator>Sougrat, Rachid</creator><creator>He, Haoze</creator><creator>Peinemann, Klaus-Viktor</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20110816</creationdate><title>From Micelle Supramolecular Assemblies in Selective Solvents to Isoporous Membranes</title><author>Nunes, Suzana P ; Karunakaran, Madhavan ; Pradeep, Neelakanda ; Behzad, Ali Reza ; Hooghan, Bobby ; Sougrat, Rachid ; He, Haoze ; Peinemann, Klaus-Viktor</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a344t-9a331a532dcfc19a299a91c0c68132c0b558f5cd4e60bed676df3bea23d14ef33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemistry</topic><topic>Colloidal state and disperse state</topic><topic>Dioxanes - chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites</topic><topic>Membranes</topic><topic>Micelles</topic><topic>Micelles. Thin films</topic><topic>Nanotubes, Carbon - chemistry</topic><topic>Polymers - chemistry</topic><topic>Porosity</topic><topic>Porous materials</topic><topic>Solvents - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nunes, Suzana P</creatorcontrib><creatorcontrib>Karunakaran, Madhavan</creatorcontrib><creatorcontrib>Pradeep, Neelakanda</creatorcontrib><creatorcontrib>Behzad, Ali Reza</creatorcontrib><creatorcontrib>Hooghan, Bobby</creatorcontrib><creatorcontrib>Sougrat, Rachid</creatorcontrib><creatorcontrib>He, Haoze</creatorcontrib><creatorcontrib>Peinemann, Klaus-Viktor</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nunes, Suzana P</au><au>Karunakaran, Madhavan</au><au>Pradeep, Neelakanda</au><au>Behzad, Ali Reza</au><au>Hooghan, Bobby</au><au>Sougrat, Rachid</au><au>He, Haoze</au><au>Peinemann, Klaus-Viktor</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>From Micelle Supramolecular Assemblies in Selective Solvents to Isoporous Membranes</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2011-08-16</date><risdate>2011</risdate><volume>27</volume><issue>16</issue><spage>10184</spage><epage>10190</epage><pages>10184-10190</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>The supramolecular assembly of PS-b-P4VP copolymer micelles induced by selective solvent mixtures was used to manufacture isoporous membranes. Micelle order in solution was confirmed by cryo-scanning electron microscopy in casting solutions, leading to ordered pore morphology. When dioxane, a solvent that interacts poorly with the micelle corona, was added to the solution, polymer–polymer segment contact was preferential, increasing the intermicelle contact. Immersion in water gave rise to asymmetric porous membranes with exceptional pore uniformity and high porosity. The introduction of a small number of carbon nanotubes to the casting solution improved the membrane stability and the reversibility of the gate response in the presence of different pH values.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>21710987</pmid><doi>10.1021/la201439p</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0743-7463 |
| ispartof | Langmuir, 2011-08, Vol.27 (16), p.10184-10190 |
| issn | 0743-7463 1520-5827 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_882089230 |
| source | MEDLINE; American Chemical Society Journals |
| subjects | Chemistry Colloidal state and disperse state Dioxanes - chemistry Exact sciences and technology General and physical chemistry Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites Membranes Micelles Micelles. Thin films Nanotubes, Carbon - chemistry Polymers - chemistry Porosity Porous materials Solvents - chemistry |
| title | From Micelle Supramolecular Assemblies in Selective Solvents to Isoporous Membranes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-18T18%3A07%3A36IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=From%20Micelle%20Supramolecular%20Assemblies%20in%20Selective%20Solvents%20to%20Isoporous%20Membranes&rft.jtitle=Langmuir&rft.au=Nunes,%20Suzana%20P&rft.date=2011-08-16&rft.volume=27&rft.issue=16&rft.spage=10184&rft.epage=10190&rft.pages=10184-10190&rft.issn=0743-7463&rft.eissn=1520-5827&rft.coden=LANGD5&rft_id=info:doi/10.1021/la201439p&rft_dat=%3Cproquest_cross%3E882089230%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=882089230&rft_id=info:pmid/21710987&rfr_iscdi=true |