Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures

Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures

Mixed matrix membranes (MMMs) composed of a glassy polymer (polysulfone) and the flexible metal organic framework NH(2)-MIL-53(Al) exhibit excellent separation properties. In contrast to most reported membranes, CO(2)/CH(4) separation selectivity increases with pressure, related to the flexibility o...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2011-09, Vol.47 (33), p.9522-9524
Hauptverfasser: Zornoza, Beatriz, Martinez-Joaristi, Alberto, Serra-Crespo, Pablo, Tellez, Carlos, Coronas, Joaquin, Gascon, Jorge, Kapteijn, Freek
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container_end_page 9524
container_issue 33
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container_title Chemical communications (Cambridge, England)
container_volume 47
creator Zornoza, Beatriz
Martinez-Joaristi, Alberto
Serra-Crespo, Pablo
Tellez, Carlos
Coronas, Joaquin
Gascon, Jorge
Kapteijn, Freek
description Mixed matrix membranes (MMMs) composed of a glassy polymer (polysulfone) and the flexible metal organic framework NH(2)-MIL-53(Al) exhibit excellent separation properties. In contrast to most reported membranes, CO(2)/CH(4) separation selectivity increases with pressure, related to the flexibility of the filler.
doi_str_mv 10.1039/c1cc13431k
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title Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures
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