Approaching polymetallic 'assemblies of assemblies' using ligands with multiple functionality--novel Mn10M2 (M = alkali metal) chains with 'ionophoric' end cavities

Approaching polymetallic 'assemblies of assemblies' using ligands with multiple functionality--novel Mn10M2 (M = alkali metal) chains with 'ionophoric' end cavities

A tri-functional ligand with hydrazone, oxime and o-vanillin subunits uses separate encoded coordination instructions to create a novel extended spin-coupled cluster where the hydazone oxygen and oxime groups of three ligands combine to create bridges linking ten Mn ions together, leaving organized...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2011-08, Vol.40 (32), p.8079-8082
Hauptverfasser: Anwar, Muhammad Usman, Dawe, Louise Nicole, Thompson, Laurence Kenneth
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Anwar, Muhammad Usman
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description A tri-functional ligand with hydrazone, oxime and o-vanillin subunits uses separate encoded coordination instructions to create a novel extended spin-coupled cluster where the hydazone oxygen and oxime groups of three ligands combine to create bridges linking ten Mn ions together, leaving organized O(6) end cavities capable of coordinating oxo-philic cations.
doi_str_mv 10.1039/c1dt11067e
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Approaching polymetallic 'assemblies of assemblies' using ligands with multiple functionality--novel Mn10M2 (M = alkali metal) chains with 'ionophoric' end cavities
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