Countercations Direct One- or Two-Electron Oxidation of an Al(III) Complex and Al(III)–Oxo Intermediates Activate C–H Bonds
Hydrogen abstraction by aluminum(III)–oxo intermediates via reaction pathways reminiscent of late transition metal chemistry has been observed. Oxidation of M+[(IP2–)2Al]− (IP = iminopyridine, M = Na, Bu4N) yielded [Na(THF)(DME)][(IP–)(IP2–)Al(OH)] (3) or [(IP–)2Al(OH)] (4), via O-atom transfer and...
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| Veröffentlicht in: | Journal of the American Chemical Society 2011-08, Vol.133 (31), p.11865-11867 |
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| container_end_page | 11867 |
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| container_issue | 31 |
| container_start_page | 11865 |
| container_title | Journal of the American Chemical Society |
| container_volume | 133 |
| creator | Myers, Thomas W Berben, Louise A |
| description | Hydrogen abstraction by aluminum(III)–oxo intermediates via reaction pathways reminiscent of late transition metal chemistry has been observed. Oxidation of M+[(IP2–)2Al]− (IP = iminopyridine, M = Na, Bu4N) yielded [Na(THF)(DME)][(IP–)(IP2–)Al(OH)] (3) or [(IP–)2Al(OH)] (4), via O-atom transfer and subsequent C–H activation or proton abstraction, respectively. |
| doi_str_mv | 10.1021/ja203842s |
| format | Article |
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| title | Countercations Direct One- or Two-Electron Oxidation of an Al(III) Complex and Al(III)–Oxo Intermediates Activate C–H Bonds |
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