The effects of LiBOB additive for stable SEI formation of PP13TFSI-organic mixed electrolyte in lithium ion batteries
► LiBOB as the additive of SEI formation. ► LiBOB containing mixed electrolyte shows well thermal stability and safety. ► LiBOB improves the electrochemical performance of PP13TFSI-organic mixture. A safe electrolyte system is prepared from N-methyl- N-propylpiperidinium bis (trifluoromethanesulfony...
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| Veröffentlicht in: | Electrochimica acta 2011-05, Vol.56 (13), p.4841-4848 |
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| container_issue | 13 |
| container_start_page | 4841 |
| container_title | Electrochimica acta |
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| creator | An, Yongxin Zuo, Pengjian Cheng, Xinqun Liao, Lixia Yin, Geping |
| description | ► LiBOB as the additive of SEI formation. ► LiBOB containing mixed electrolyte shows well thermal stability and safety. ► LiBOB improves the electrochemical performance of PP13TFSI-organic mixture.
A safe electrolyte system is prepared from
N-methyl-
N-propylpiperidinium bis (trifluoromethanesulfonyl) imide (PP13TFSI), organic electrolyte (1
mol
L
−1 LiPF
6/EC-DEC) and lithium bis (oxalato) borate (LiBOB). The additive of LiBOB enhances the stability of interface between electrolyte and anode. The LiBOB-containing mixed electrolytes show non-flammability and good compatibility with active materials. The performance of anode for lithium ion battery is successfully improved by LiBOB-containing mixed electrolytes, which shows 200
mA
h
g
−1 reversible capacities at 0.3
C rate. The ionic conductivity and the lithium ion transference number in LiBOB-containing mixed electrolytes system also suits to application for lithium ion battery. |
| doi_str_mv | 10.1016/j.electacta.2011.01.125 |
| format | Article |
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A safe electrolyte system is prepared from
N-methyl-
N-propylpiperidinium bis (trifluoromethanesulfonyl) imide (PP13TFSI), organic electrolyte (1
mol
L
−1 LiPF
6/EC-DEC) and lithium bis (oxalato) borate (LiBOB). The additive of LiBOB enhances the stability of interface between electrolyte and anode. The LiBOB-containing mixed electrolytes show non-flammability and good compatibility with active materials. The performance of anode for lithium ion battery is successfully improved by LiBOB-containing mixed electrolytes, which shows 200
mA
h
g
−1 reversible capacities at 0.3
C rate. The ionic conductivity and the lithium ion transference number in LiBOB-containing mixed electrolytes system also suits to application for lithium ion battery.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2011.01.125</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Additives ; Anodes ; Applied sciences ; Direct energy conversion and energy accumulation ; Electrical engineering. Electrical power engineering ; Electrical power engineering ; Electrochemical conversion: primary and secondary batteries, fuel cells ; Electrolyte ; Electrolytes ; Exact sciences and technology ; Imides ; Interface stability ; Ionic conductivity ; Ionic liquid ; Li-ion battery ; Lithium ; Lithium-ion batteries ; Safety ; Solid electrolyte interphase</subject><ispartof>Electrochimica acta, 2011-05, Vol.56 (13), p.4841-4848</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-af61c6095d332862aad4e5d14ecd0c07227b62c46c8bcef7119b8317dc96a5b53</citedby><cites>FETCH-LOGICAL-c377t-af61c6095d332862aad4e5d14ecd0c07227b62c46c8bcef7119b8317dc96a5b53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.electacta.2011.01.125$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,782,786,3552,27931,27932,46002</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24196154$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>An, Yongxin</creatorcontrib><creatorcontrib>Zuo, Pengjian</creatorcontrib><creatorcontrib>Cheng, Xinqun</creatorcontrib><creatorcontrib>Liao, Lixia</creatorcontrib><creatorcontrib>Yin, Geping</creatorcontrib><title>The effects of LiBOB additive for stable SEI formation of PP13TFSI-organic mixed electrolyte in lithium ion batteries</title><title>Electrochimica acta</title><description>► LiBOB as the additive of SEI formation. ► LiBOB containing mixed electrolyte shows well thermal stability and safety. ► LiBOB improves the electrochemical performance of PP13TFSI-organic mixture.
A safe electrolyte system is prepared from
N-methyl-
N-propylpiperidinium bis (trifluoromethanesulfonyl) imide (PP13TFSI), organic electrolyte (1
mol
L
−1 LiPF
6/EC-DEC) and lithium bis (oxalato) borate (LiBOB). The additive of LiBOB enhances the stability of interface between electrolyte and anode. The LiBOB-containing mixed electrolytes show non-flammability and good compatibility with active materials. The performance of anode for lithium ion battery is successfully improved by LiBOB-containing mixed electrolytes, which shows 200
mA
h
g
−1 reversible capacities at 0.3
C rate. The ionic conductivity and the lithium ion transference number in LiBOB-containing mixed electrolytes system also suits to application for lithium ion battery.</description><subject>Additives</subject><subject>Anodes</subject><subject>Applied sciences</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrical power engineering</subject><subject>Electrochemical conversion: primary and secondary batteries, fuel cells</subject><subject>Electrolyte</subject><subject>Electrolytes</subject><subject>Exact sciences and technology</subject><subject>Imides</subject><subject>Interface stability</subject><subject>Ionic conductivity</subject><subject>Ionic liquid</subject><subject>Li-ion battery</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Safety</subject><subject>Solid electrolyte interphase</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkEFr3DAQhUVpodu0v6G6lJ7saiRbso9JSNqFhQSyPQtZGjVabCuVtCH597WzIdfCwDDwvTczj5CvwGpgIH8cahzRFrNUzRlAzaAG3r4jG-iUqETX9u_JhjEQVSM7-ZF8yvnAGFNSsQ057u-RoveLQ6bR0124uLmgxrlQwiNSHxPNxQwj0rur7TpOpoQ4r-jtLYj99d22iumPmYOlU3hCR1-uSXF8LkjDTMdQ7sNxoqtoMKVgCpg_kw_ejBm_vPYz8vv6an_5q9rd_Nxenu8qK5QqlfESrGR964TgneTGuAZbBw1axyxTnKtBcttI2w0WvQLoh06AcraXph1acUa-n3wfUvx7xFz0FLLFcTQzxmPWXccU63u-kupE2hRzTuj1QwqTSc8amF5z1gf9lrNec9YMNLwov73uMNma0Scz25Df5LyBXkLbLNz5icPl4ceASWcbcLboQlp8tYvhv7v-AbFQl9s</recordid><startdate>20110501</startdate><enddate>20110501</enddate><creator>An, Yongxin</creator><creator>Zuo, Pengjian</creator><creator>Cheng, Xinqun</creator><creator>Liao, Lixia</creator><creator>Yin, Geping</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110501</creationdate><title>The effects of LiBOB additive for stable SEI formation of PP13TFSI-organic mixed electrolyte in lithium ion batteries</title><author>An, Yongxin ; Zuo, Pengjian ; Cheng, Xinqun ; Liao, Lixia ; Yin, Geping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-af61c6095d332862aad4e5d14ecd0c07227b62c46c8bcef7119b8317dc96a5b53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Additives</topic><topic>Anodes</topic><topic>Applied sciences</topic><topic>Direct energy conversion and energy accumulation</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrical power engineering</topic><topic>Electrochemical conversion: primary and secondary batteries, fuel cells</topic><topic>Electrolyte</topic><topic>Electrolytes</topic><topic>Exact sciences and technology</topic><topic>Imides</topic><topic>Interface stability</topic><topic>Ionic conductivity</topic><topic>Ionic liquid</topic><topic>Li-ion battery</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Safety</topic><topic>Solid electrolyte interphase</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>An, Yongxin</creatorcontrib><creatorcontrib>Zuo, Pengjian</creatorcontrib><creatorcontrib>Cheng, Xinqun</creatorcontrib><creatorcontrib>Liao, Lixia</creatorcontrib><creatorcontrib>Yin, Geping</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>An, Yongxin</au><au>Zuo, Pengjian</au><au>Cheng, Xinqun</au><au>Liao, Lixia</au><au>Yin, Geping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effects of LiBOB additive for stable SEI formation of PP13TFSI-organic mixed electrolyte in lithium ion batteries</atitle><jtitle>Electrochimica acta</jtitle><date>2011-05-01</date><risdate>2011</risdate><volume>56</volume><issue>13</issue><spage>4841</spage><epage>4848</epage><pages>4841-4848</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><coden>ELCAAV</coden><abstract>► LiBOB as the additive of SEI formation. ► LiBOB containing mixed electrolyte shows well thermal stability and safety. ► LiBOB improves the electrochemical performance of PP13TFSI-organic mixture.
A safe electrolyte system is prepared from
N-methyl-
N-propylpiperidinium bis (trifluoromethanesulfonyl) imide (PP13TFSI), organic electrolyte (1
mol
L
−1 LiPF
6/EC-DEC) and lithium bis (oxalato) borate (LiBOB). The additive of LiBOB enhances the stability of interface between electrolyte and anode. The LiBOB-containing mixed electrolytes show non-flammability and good compatibility with active materials. The performance of anode for lithium ion battery is successfully improved by LiBOB-containing mixed electrolytes, which shows 200
mA
h
g
−1 reversible capacities at 0.3
C rate. The ionic conductivity and the lithium ion transference number in LiBOB-containing mixed electrolytes system also suits to application for lithium ion battery.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2011.01.125</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 2011-05, Vol.56 (13), p.4841-4848 |
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| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Additives Anodes Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrolyte Electrolytes Exact sciences and technology Imides Interface stability Ionic conductivity Ionic liquid Li-ion battery Lithium Lithium-ion batteries Safety Solid electrolyte interphase |
| title | The effects of LiBOB additive for stable SEI formation of PP13TFSI-organic mixed electrolyte in lithium ion batteries |
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