The effects of LiBOB additive for stable SEI formation of PP13TFSI-organic mixed electrolyte in lithium ion batteries

► LiBOB as the additive of SEI formation. ► LiBOB containing mixed electrolyte shows well thermal stability and safety. ► LiBOB improves the electrochemical performance of PP13TFSI-organic mixture. A safe electrolyte system is prepared from N-methyl- N-propylpiperidinium bis (trifluoromethanesulfony...

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Veröffentlicht in:Electrochimica acta 2011-05, Vol.56 (13), p.4841-4848
Hauptverfasser: An, Yongxin, Zuo, Pengjian, Cheng, Xinqun, Liao, Lixia, Yin, Geping
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container_end_page 4848
container_issue 13
container_start_page 4841
container_title Electrochimica acta
container_volume 56
creator An, Yongxin
Zuo, Pengjian
Cheng, Xinqun
Liao, Lixia
Yin, Geping
description ► LiBOB as the additive of SEI formation. ► LiBOB containing mixed electrolyte shows well thermal stability and safety. ► LiBOB improves the electrochemical performance of PP13TFSI-organic mixture. A safe electrolyte system is prepared from N-methyl- N-propylpiperidinium bis (trifluoromethanesulfonyl) imide (PP13TFSI), organic electrolyte (1 mol L −1 LiPF 6/EC-DEC) and lithium bis (oxalato) borate (LiBOB). The additive of LiBOB enhances the stability of interface between electrolyte and anode. The LiBOB-containing mixed electrolytes show non-flammability and good compatibility with active materials. The performance of anode for lithium ion battery is successfully improved by LiBOB-containing mixed electrolytes, which shows 200 mA h g −1 reversible capacities at 0.3 C rate. The ionic conductivity and the lithium ion transference number in LiBOB-containing mixed electrolytes system also suits to application for lithium ion battery.
doi_str_mv 10.1016/j.electacta.2011.01.125
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A safe electrolyte system is prepared from N-methyl- N-propylpiperidinium bis (trifluoromethanesulfonyl) imide (PP13TFSI), organic electrolyte (1 mol L −1 LiPF 6/EC-DEC) and lithium bis (oxalato) borate (LiBOB). The additive of LiBOB enhances the stability of interface between electrolyte and anode. The LiBOB-containing mixed electrolytes show non-flammability and good compatibility with active materials. The performance of anode for lithium ion battery is successfully improved by LiBOB-containing mixed electrolytes, which shows 200 mA h g −1 reversible capacities at 0.3 C rate. The ionic conductivity and the lithium ion transference number in LiBOB-containing mixed electrolytes system also suits to application for lithium ion battery.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2011.01.125</doi><tpages>8</tpages></addata></record>
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subjects Additives
Anodes
Applied sciences
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Electrolyte
Electrolytes
Exact sciences and technology
Imides
Interface stability
Ionic conductivity
Ionic liquid
Li-ion battery
Lithium
Lithium-ion batteries
Safety
Solid electrolyte interphase
title The effects of LiBOB additive for stable SEI formation of PP13TFSI-organic mixed electrolyte in lithium ion batteries
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