Bottom-up realization of a porous metal-organic nanotubular assembly
Nanotubes are generally prepared from their constituent elements at high temperatures, and thus it is difficult to control their size, shape and electronic states. One useful approach for synthesizing well-defined nanostructures involves the use of building blocks such as metal ions and organic mole...
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| Veröffentlicht in: | Nature materials 2011-04, Vol.10 (4), p.291-295 |
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| container_title | Nature materials |
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| creator | Otsubo, Kazuya Kitagawa, Hiroshi Wakabayashi, Yusuke Ohara, Jun Yamamoto, Shoji Matsuzaki, Hiroyuki Okamoto, Hiroshi Nitta, Kiyofumi Uruga, Tomoya |
| description | Nanotubes are generally prepared from their constituent elements at high temperatures, and thus it is difficult to control their size, shape and electronic states. One useful approach for synthesizing well-defined nanostructures involves the use of building blocks such as metal ions and organic molecules. Here, we show the successful creation of an assembly of infinite square prism-shaped metal-organic nanotubes obtained from the simple polymerization of a square-shaped metal-organic frame. The constituent nanotube has a one-dimensional (1D) channel with a window size of 5.9×5.9 Å2, and can adsorb water (H2O) and alcohol vapours, whereas N2 and CO2 do not adhere. It consists of four 1D covalent chains that constitute a unique electronic structure of 'charge-density wave (CDW) quartets' on crystallization. Moreover, exchanging structural components and guest molecules enables us to control its semiconductive bandgap. These findings demonstrate the possibility of bottom-up construction of new porous nanotubes, where their degrees of freedom in both pore space and framework can be used. |
| doi_str_mv | 10.1038/nmat2963 |
| format | Article |
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One useful approach for synthesizing well-defined nanostructures involves the use of building blocks such as metal ions and organic molecules. Here, we show the successful creation of an assembly of infinite square prism-shaped metal-organic nanotubes obtained from the simple polymerization of a square-shaped metal-organic frame. The constituent nanotube has a one-dimensional (1D) channel with a window size of 5.9×5.9 Å2, and can adsorb water (H2O) and alcohol vapours, whereas N2 and CO2 do not adhere. It consists of four 1D covalent chains that constitute a unique electronic structure of 'charge-density wave (CDW) quartets' on crystallization. Moreover, exchanging structural components and guest molecules enables us to control its semiconductive bandgap. These findings demonstrate the possibility of bottom-up construction of new porous nanotubes, where their degrees of freedom in both pore space and framework can be used.</description><identifier>ISSN: 1476-1122</identifier><identifier>EISSN: 1476-4660</identifier><identifier>DOI: 10.1038/nmat2963</identifier><identifier>PMID: 21358649</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301/1034/1038 ; 639/301/299/1013 ; 639/301/357 ; Assembly ; Biomaterials ; Carbon dioxide ; Channels ; Chemical elements ; Chemistry and Materials Science ; Condensed Matter Physics ; Constituents ; Crystallization ; High temperature ; letter ; Materials Science ; Metal ions ; Nanocomposites ; Nanomaterials ; Nanostructure ; Nanotechnology ; Nanotubes ; Optical and Electronic Materials ; Polymerization ; Porous materials</subject><ispartof>Nature materials, 2011-04, Vol.10 (4), p.291-295</ispartof><rights>Springer Nature Limited 2011</rights><rights>Copyright Nature Publishing Group Apr 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c464t-f698af3e83c7670004a1aadef97e3e64eb2d39e3119a8966f3521e38eaaa33663</citedby><cites>FETCH-LOGICAL-c464t-f698af3e83c7670004a1aadef97e3e64eb2d39e3119a8966f3521e38eaaa33663</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,2727,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21358649$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Otsubo, Kazuya</creatorcontrib><creatorcontrib>Kitagawa, Hiroshi</creatorcontrib><creatorcontrib>Wakabayashi, Yusuke</creatorcontrib><creatorcontrib>Ohara, Jun</creatorcontrib><creatorcontrib>Yamamoto, Shoji</creatorcontrib><creatorcontrib>Matsuzaki, Hiroyuki</creatorcontrib><creatorcontrib>Okamoto, Hiroshi</creatorcontrib><creatorcontrib>Nitta, Kiyofumi</creatorcontrib><creatorcontrib>Uruga, Tomoya</creatorcontrib><title>Bottom-up realization of a porous metal-organic nanotubular assembly</title><title>Nature materials</title><addtitle>Nature Mater</addtitle><addtitle>Nat Mater</addtitle><description>Nanotubes are generally prepared from their constituent elements at high temperatures, and thus it is difficult to control their size, shape and electronic states. One useful approach for synthesizing well-defined nanostructures involves the use of building blocks such as metal ions and organic molecules. Here, we show the successful creation of an assembly of infinite square prism-shaped metal-organic nanotubes obtained from the simple polymerization of a square-shaped metal-organic frame. The constituent nanotube has a one-dimensional (1D) channel with a window size of 5.9×5.9 Å2, and can adsorb water (H2O) and alcohol vapours, whereas N2 and CO2 do not adhere. It consists of four 1D covalent chains that constitute a unique electronic structure of 'charge-density wave (CDW) quartets' on crystallization. Moreover, exchanging structural components and guest molecules enables us to control its semiconductive bandgap. 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One useful approach for synthesizing well-defined nanostructures involves the use of building blocks such as metal ions and organic molecules. Here, we show the successful creation of an assembly of infinite square prism-shaped metal-organic nanotubes obtained from the simple polymerization of a square-shaped metal-organic frame. The constituent nanotube has a one-dimensional (1D) channel with a window size of 5.9×5.9 Å2, and can adsorb water (H2O) and alcohol vapours, whereas N2 and CO2 do not adhere. It consists of four 1D covalent chains that constitute a unique electronic structure of 'charge-density wave (CDW) quartets' on crystallization. Moreover, exchanging structural components and guest molecules enables us to control its semiconductive bandgap. 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| subjects | 639/301/1034/1038 639/301/299/1013 639/301/357 Assembly Biomaterials Carbon dioxide Channels Chemical elements Chemistry and Materials Science Condensed Matter Physics Constituents Crystallization High temperature letter Materials Science Metal ions Nanocomposites Nanomaterials Nanostructure Nanotechnology Nanotubes Optical and Electronic Materials Polymerization Porous materials |
| title | Bottom-up realization of a porous metal-organic nanotubular assembly |
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