Plasma-Modified PTFE for Biological Applications: Correlation between Protein-Resistant Properties and Surface Characteristics
PTFE samples were treated by low‐pressure O2 RF plasmas. The adsorption of BSA was used as a probe for the protein‐resistant properties. Exposure of PTFE to an O2 plasma leads to an increase in chamber pressure. OES reveals the presence of CO, CO2 and F in the gas phase, indicating a strong etching...
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Veröffentlicht in: | Plasma processes and polymers 2008-09, Vol.5 (7), p.661-671 |
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creator | Vandencasteele, Nicolas Nisol, Bernard Viville, Pascal Lazzaroni, Roberto Castner, David G. Reniers, François |
description | PTFE samples were treated by low‐pressure O2 RF plasmas. The adsorption of BSA was used as a probe for the protein‐resistant properties. Exposure of PTFE to an O2 plasma leads to an increase in chamber pressure. OES reveals the presence of CO, CO2 and F in the gas phase, indicating a strong etching of the PTFE surface by the plasma. Furthermore, the high‐resolution C1s spectra show CF3, CF and CCF components. WCA as high as 160° were observed, indicating a super‐hydrophobic behavior. AFM images of surfaces treated at high plasma power showed an increase in roughness. Lower amounts of BSA adsorption were detected on high power, O2 plasma‐modified PTFE samples compared to low power, oxygen plasma‐modified ones. |
doi_str_mv | 10.1002/ppap.200700143 |
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The adsorption of BSA was used as a probe for the protein‐resistant properties. Exposure of PTFE to an O2 plasma leads to an increase in chamber pressure. OES reveals the presence of CO, CO2 and F in the gas phase, indicating a strong etching of the PTFE surface by the plasma. Furthermore, the high‐resolution C1s spectra show CF3, CF and CCF components. WCA as high as 160° were observed, indicating a super‐hydrophobic behavior. AFM images of surfaces treated at high plasma power showed an increase in roughness. Lower amounts of BSA adsorption were detected on high power, O2 plasma‐modified PTFE samples compared to low power, oxygen plasma‐modified ones.</description><subject>Adsorption</subject><subject>Applied sciences</subject><subject>biocompatibility</subject><subject>Carbon dioxide</subject><subject>Carbon monoxide</subject><subject>Chambers</subject><subject>Coating, metallization, dyeing</subject><subject>Exact sciences and technology</subject><subject>Machinery and processing</subject><subject>plasma treatment</subject><subject>Plastics</subject><subject>poly(tetrafluoroethylene) (PTFE)</subject><subject>Polymer industry, paints, wood</subject><subject>polymer modification</subject><subject>Polytetrafluoroethylenes</subject><subject>protein adsorption</subject><subject>Spectra</subject><subject>Surface chemistry</subject><subject>Technology of polymers</subject><issn>1612-8850</issn><issn>1612-8869</issn><issn>1612-8869</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkcFvFCEUxifGJtbaq2cu6mm2D1gYxtu6adcmbR1rjUdCmYei7DDCbGov_u1l3WbjSU88eL_vI_m-qnpJYUYB2Mk4mnHGABoAOudPqkMqKauVku3T_SzgWfU85-8AHISCw-p3F0xem_oy9t557El3c3ZKXEzknY8hfvXWBLIYx1CGycchvyXLmBKGPzdyi9Md4kC6FCf0Q32N2efJDNP2ZcQ0eczEDD35tEnOWCTLbyYZO2EqmLf5RXXgTMh4_HgeVZ_PTm-W7-uLD6vz5eKitoJJXlPbCt66llmQaNxtPwcqoexsz7niknI3F9T2TijHeI8gGqMoQydV2UjGj6o3O98xxZ8bzJNe-2wxBDNg3GStFEgJtGkK-fqfJBclXSrnBZztQJtizgmdHpNfm3SvKehtIXpbiN4XUgSvHp1NLqm6ZAbr817FQPJiqwrX7rg7H_D-P6666xbd33_UO22JF3_ttSb90LLhjdBfrlb6o7pcXQtGteQPZ3Sspg</recordid><startdate>20080915</startdate><enddate>20080915</enddate><creator>Vandencasteele, Nicolas</creator><creator>Nisol, Bernard</creator><creator>Viville, Pascal</creator><creator>Lazzaroni, Roberto</creator><creator>Castner, David G.</creator><creator>Reniers, François</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20080915</creationdate><title>Plasma-Modified PTFE for Biological Applications: Correlation between Protein-Resistant Properties and Surface Characteristics</title><author>Vandencasteele, Nicolas ; Nisol, Bernard ; Viville, Pascal ; Lazzaroni, Roberto ; Castner, David G. ; Reniers, François</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5263-1c9539f92c06eafbd40160c52cd3383613f451cdf58f23de057a812ef683f4623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Adsorption</topic><topic>Applied sciences</topic><topic>biocompatibility</topic><topic>Carbon dioxide</topic><topic>Carbon monoxide</topic><topic>Chambers</topic><topic>Coating, metallization, dyeing</topic><topic>Exact sciences and technology</topic><topic>Machinery and processing</topic><topic>plasma treatment</topic><topic>Plastics</topic><topic>poly(tetrafluoroethylene) (PTFE)</topic><topic>Polymer industry, paints, wood</topic><topic>polymer modification</topic><topic>Polytetrafluoroethylenes</topic><topic>protein adsorption</topic><topic>Spectra</topic><topic>Surface chemistry</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vandencasteele, Nicolas</creatorcontrib><creatorcontrib>Nisol, Bernard</creatorcontrib><creatorcontrib>Viville, Pascal</creatorcontrib><creatorcontrib>Lazzaroni, Roberto</creatorcontrib><creatorcontrib>Castner, David G.</creatorcontrib><creatorcontrib>Reniers, François</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Plasma processes and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vandencasteele, Nicolas</au><au>Nisol, Bernard</au><au>Viville, Pascal</au><au>Lazzaroni, Roberto</au><au>Castner, David G.</au><au>Reniers, François</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Plasma-Modified PTFE for Biological Applications: Correlation between Protein-Resistant Properties and Surface Characteristics</atitle><jtitle>Plasma processes and polymers</jtitle><addtitle>Plasma Processes Polym</addtitle><date>2008-09-15</date><risdate>2008</risdate><volume>5</volume><issue>7</issue><spage>661</spage><epage>671</epage><pages>661-671</pages><issn>1612-8850</issn><issn>1612-8869</issn><eissn>1612-8869</eissn><abstract>PTFE samples were treated by low‐pressure O2 RF plasmas. 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subjects | Adsorption Applied sciences biocompatibility Carbon dioxide Carbon monoxide Chambers Coating, metallization, dyeing Exact sciences and technology Machinery and processing plasma treatment Plastics poly(tetrafluoroethylene) (PTFE) Polymer industry, paints, wood polymer modification Polytetrafluoroethylenes protein adsorption Spectra Surface chemistry Technology of polymers |
title | Plasma-Modified PTFE for Biological Applications: Correlation between Protein-Resistant Properties and Surface Characteristics |
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