Plasma-Modified PTFE for Biological Applications: Correlation between Protein-Resistant Properties and Surface Characteristics

PTFE samples were treated by low‐pressure O2 RF plasmas. The adsorption of BSA was used as a probe for the protein‐resistant properties. Exposure of PTFE to an O2 plasma leads to an increase in chamber pressure. OES reveals the presence of CO, CO2 and F in the gas phase, indicating a strong etching...

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Veröffentlicht in:Plasma processes and polymers 2008-09, Vol.5 (7), p.661-671
Hauptverfasser: Vandencasteele, Nicolas, Nisol, Bernard, Viville, Pascal, Lazzaroni, Roberto, Castner, David G., Reniers, François
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container_end_page 671
container_issue 7
container_start_page 661
container_title Plasma processes and polymers
container_volume 5
creator Vandencasteele, Nicolas
Nisol, Bernard
Viville, Pascal
Lazzaroni, Roberto
Castner, David G.
Reniers, François
description PTFE samples were treated by low‐pressure O2 RF plasmas. The adsorption of BSA was used as a probe for the protein‐resistant properties. Exposure of PTFE to an O2 plasma leads to an increase in chamber pressure. OES reveals the presence of CO, CO2 and F in the gas phase, indicating a strong etching of the PTFE surface by the plasma. Furthermore, the high‐resolution C1s spectra show CF3, CF and CCF components. WCA as high as 160° were observed, indicating a super‐hydrophobic behavior. AFM images of surfaces treated at high plasma power showed an increase in roughness. Lower amounts of BSA adsorption were detected on high power, O2 plasma‐modified PTFE samples compared to low power, oxygen plasma‐modified ones.
doi_str_mv 10.1002/ppap.200700143
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source Wiley Journals
subjects Adsorption
Applied sciences
biocompatibility
Carbon dioxide
Carbon monoxide
Chambers
Coating, metallization, dyeing
Exact sciences and technology
Machinery and processing
plasma treatment
Plastics
poly(tetrafluoroethylene) (PTFE)
Polymer industry, paints, wood
polymer modification
Polytetrafluoroethylenes
protein adsorption
Spectra
Surface chemistry
Technology of polymers
title Plasma-Modified PTFE for Biological Applications: Correlation between Protein-Resistant Properties and Surface Characteristics
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