Growth of nanocrystalline TiO2 films by pulsed-laser-induced liquid-deposition method and preliminary applications for dye-sensitized solar cells

A novel technique, the pulsed-laser-induced liquid-deposition (PLLD) method, has been employed to grow nanocrystalline TiO 2 films on fluorine-doped tin-oxide-coated (FTO) glass substrates at room temperature. The PLLD method was implemented by directing a pulsed laser into a liquid precursor and de...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2010-09, Vol.100 (4), p.1169-1176
Hauptverfasser: Wang, Guo-Bing, Fu, Min-Gong, Lu, Bin, Du, Guo-Ping, Li, Li, Qin, Xiao-Mei, Shi, Wang-Zhou
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container_title Applied physics. A, Materials science & processing
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creator Wang, Guo-Bing
Fu, Min-Gong
Lu, Bin
Du, Guo-Ping
Li, Li
Qin, Xiao-Mei
Shi, Wang-Zhou
description A novel technique, the pulsed-laser-induced liquid-deposition (PLLD) method, has been employed to grow nanocrystalline TiO 2 films on fluorine-doped tin-oxide-coated (FTO) glass substrates at room temperature. The PLLD method was implemented by directing a pulsed laser into a liquid precursor and depositing the photosynthesized nanocrystalline TiO 2 on an FTO glass substrate immersed in the liquid precursor. The as-grown nanocrystalline TiO 2 films were found to have a rutile crystal structure and consist of a number of flower-like TiO 2 crystal units arrayed together on the FTO glass substrate. Each of the flower-like TiO 2 crystal units was composed of many nanostructured TiO 2 whiskers, and their building blocks were found to be bundles of TiO 2 nanorods with diameter of about 5 nm. The growth of these TiO 2 nanorods is highly anisotropic, with the preferential growth direction along [001]. As-grown nanocrystalline TiO 2 films were annealed at 450°C in air for 30 min for the applications of dye-sensitized solar cells, and the nanostructured characteristics with good porosity were preserved after annealing. A preliminary dye-sensitized solar cell was built based on the annealed nanocrystalline TiO 2 film. The results suggest that the PLLD method is a promising technique for growing nanocrystalline TiO 2 films for photovoltaic applications.
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The PLLD method was implemented by directing a pulsed laser into a liquid precursor and depositing the photosynthesized nanocrystalline TiO 2 on an FTO glass substrate immersed in the liquid precursor. The as-grown nanocrystalline TiO 2 films were found to have a rutile crystal structure and consist of a number of flower-like TiO 2 crystal units arrayed together on the FTO glass substrate. Each of the flower-like TiO 2 crystal units was composed of many nanostructured TiO 2 whiskers, and their building blocks were found to be bundles of TiO 2 nanorods with diameter of about 5 nm. The growth of these TiO 2 nanorods is highly anisotropic, with the preferential growth direction along [001]. As-grown nanocrystalline TiO 2 films were annealed at 450°C in air for 30 min for the applications of dye-sensitized solar cells, and the nanostructured characteristics with good porosity were preserved after annealing. 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A, Materials science &amp; processing</title><addtitle>Appl. Phys. A</addtitle><description>A novel technique, the pulsed-laser-induced liquid-deposition (PLLD) method, has been employed to grow nanocrystalline TiO 2 films on fluorine-doped tin-oxide-coated (FTO) glass substrates at room temperature. The PLLD method was implemented by directing a pulsed laser into a liquid precursor and depositing the photosynthesized nanocrystalline TiO 2 on an FTO glass substrate immersed in the liquid precursor. The as-grown nanocrystalline TiO 2 films were found to have a rutile crystal structure and consist of a number of flower-like TiO 2 crystal units arrayed together on the FTO glass substrate. Each of the flower-like TiO 2 crystal units was composed of many nanostructured TiO 2 whiskers, and their building blocks were found to be bundles of TiO 2 nanorods with diameter of about 5 nm. The growth of these TiO 2 nanorods is highly anisotropic, with the preferential growth direction along [001]. 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Each of the flower-like TiO 2 crystal units was composed of many nanostructured TiO 2 whiskers, and their building blocks were found to be bundles of TiO 2 nanorods with diameter of about 5 nm. The growth of these TiO 2 nanorods is highly anisotropic, with the preferential growth direction along [001]. As-grown nanocrystalline TiO 2 films were annealed at 450°C in air for 30 min for the applications of dye-sensitized solar cells, and the nanostructured characteristics with good porosity were preserved after annealing. A preliminary dye-sensitized solar cell was built based on the annealed nanocrystalline TiO 2 film. The results suggest that the PLLD method is a promising technique for growing nanocrystalline TiO 2 films for photovoltaic applications.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><doi>10.1007/s00339-010-5731-z</doi><tpages>8</tpages></addata></record>
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subjects Annealing
Applied sciences
Characterization and Evaluation of Materials
Condensed Matter Physics
Cross-disciplinary physics: materials science
rheology
Dyes
Energy
Exact sciences and technology
Glass
Laser-assisted deposition
Machines
Manufacturing
Materials science
Methods of nanofabrication
Nanocrystalline materials
Nanocrystals
Nanorods
Nanoscale materials and structures: fabrication and characterization
Nanotechnology
Natural energy
Optical and Electronic Materials
Photovoltaic cells
Photovoltaic conversion
Physics
Physics and Astronomy
Processes
Solar cells
Solar cells. Photoelectrochemical cells
Solar energy
Surfaces and Interfaces
Thin Films
Titanium dioxide
title Growth of nanocrystalline TiO2 films by pulsed-laser-induced liquid-deposition method and preliminary applications for dye-sensitized solar cells
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