Detection of early stage precursor during formation of plastic crystal ethanol from the supercooled liquid state: a simultaneous dielectric spectroscopy with neutron diffraction study
Transformation of deuterated ethanol from supercooled liquid into a plastic crystal or rotator phase is investigated by means of a particular experimental setup combining simultaneously dielectric spectroscopy with neutron diffraction techniques. We demonstrate that, previous to the growth of the bc...
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| Veröffentlicht in: | Physical review letters 2011-07, Vol.107 (2), p.025502-025502, Article 025502 |
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| container_title | Physical review letters |
| container_volume | 107 |
| creator | Sanz, Alejandro Nogales, Aurora Puente-Orench, Inés Jiménez-Ruiz, Mónica Ezquerra, Tiberio A |
| description | Transformation of deuterated ethanol from supercooled liquid into a plastic crystal or rotator phase is investigated by means of a particular experimental setup combining simultaneously dielectric spectroscopy with neutron diffraction techniques. We demonstrate that, previous to the growth of the bcc lattice of the plastic crystal phase, the formation of a precursor or intermediate phase through a liquid-liquid phase separation takes place. Once this precursor phase is formed, subsequent (plastic) crystalline nucleation and growth is expected to develop. |
| doi_str_mv | 10.1103/PhysRevLett.107.025502 |
| format | Article |
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| ispartof | Physical review letters, 2011-07, Vol.107 (2), p.025502-025502, Article 025502 |
| issn | 0031-9007 1079-7114 |
| language | eng |
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| source | American Physical Society Journals |
| title | Detection of early stage precursor during formation of plastic crystal ethanol from the supercooled liquid state: a simultaneous dielectric spectroscopy with neutron diffraction study |
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