Conformation-Specific Spectroscopy and Populations of Diastereomers of a Model Monolignol Derivative: Chiral Effects in a Triol Chain

Single-conformation spectroscopy of two diastereomers of 1-(4-hydroxy-3-methoxyphenyl)propane-1,2,3-triol (HMPPT) has been carried out under isolated, jet-cooled conditions. HMPPT is a close analog of coniferyl alcohol, one of the three monomers that make up lignin, the aromatic biopolymer that give...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2011-08, Vol.115 (30), p.8464-8478
Hauptverfasser: Dean, Jacob C, Buchanan, Evan G, James, William H, Gutberlet, Anna, Biswas, Bidyut, Ramachandran, P. Veeraraghavan, Zwier, Timothy S
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Sprache:eng
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